Abstract
The results of thermal and thermodynamic (phase diagram) property calculations of water–aliphatic alcohol (methanol, ethanol, n-propanol) systems in liquid and vapor phases, as well as supercritical fluid water–methanol systems have been presented. The calculations are based on the polynomial equation of state, represented by expansion of the compressibility factor into a power series of reduced density (ω = ρ/ρcr and reduced temperature (τ = T/T cr)
, which describes experimental p,ρ,T,x-dependencies with an average relative error of 1.2%.
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Original Russian Text © B.K. Karabekova, E.A. Bazaev, A.R. Bazaev, 2015, published in Sverkhkriticheskie Flyuidy: Teoriya i Praktika, 2015, Vol. 10, No. 1, pp. 35–60.
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Karabekova, B.K., Bazaev, E.A. & Bazaev, A.R. Thermodynamic properties of water–aliphatic alcohol systems in a wide range of parameters. Russ. J. Phys. Chem. B 9, 1162–1178 (2015). https://doi.org/10.1134/S1990793115080060
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DOI: https://doi.org/10.1134/S1990793115080060