Abstract
Presented is a detailed characterization of the present state and pollution of soil cover in the influence area of the Dzhidinskii tungsten-molybdenum plant which takes into consideration the spatial geological inhomogeneity and the functional purpose of urban territories. As part of the investigation, we determined the content levels of heavy metals and metalloids in background soils, and the elements which are the main pollutants of urban soils in the zones of different functional purposes, ascertained the degree of technogenic geochemical transformation of soil cover in the city of Zakamensk, and identified the leading soiland landscape-geochemical factors for accumulation of heavy metals and metalloids in the urban topsoil (0−10 cm) horizons. An assessment was also made of the ecological hazard of soil pollution by a set of heavy metals and metalloids in the main functional zones of the city. A soil-geochemical survey was carried out, and the ICP-MS method was used to determine the total content levels of 14 heavy metals and metalloids of hazard classes I−III as well as Be, Sn, Cs and Bi. The elements were determined, which are the main pollutants of the soils in Zakamensk: W, Bi, Cd, Pb and Mo. The study revealed a need to take into account the metallogenic specific character and geological inhomogeneity of the area by using the local coefficients of concentration (EF l ) and dispersal (DF l ) which must be calculated not with respect to the average regional background but from the individual (for each parent material) background value in order to more accurately determine the degree of technogenic geochemical transformation of soils, and the ecological hazard of pollution. It is suggested that the ecological hazard should be assessed on the basis of the Integrated Pollution Index (IPI) which is calculated with respect to the world’s average concentrations of heavy metals and metalloids in soils and takes into account hazard classes of elements.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
Elpatyevskii, P.V., Geochemistry of Migratory Flows in Natural and Natural-Technogenic Geosystems, Moscow: Nauka, 1993 [in Russian].
Lizárraga-Mendiola, L., González-Sandoval, M.R., Durán-Domínguez, M.C., and Márquez-Herrera, C., Geochemical Behavior of Heavy Metals in Zn–Pb–Cu Mining Area in the State of Mexico (Central Mexico), Environ. Monit. Assess., 2009, vol. 155, issue 1–4, pp. 355–372.
Khanchuk, A.I., Krupskaya, L.T. and Zvereva, V.P., Ecological Problems of Tin Ore Resources in Primorie and Priamurie, Geogr. Nat. Resour., 2012, vol. 33, issue 1, pp. 45–49.
Rey, J., Martínez, J., Hidalgo, M.C., and Rojas, D., Heavy Metal Pollution in the Quaternery Garza Basin: A Multidisciplinary Study of the Environmental Risks Posed by Mining (Linares, Southern Spain), Catena, 2013, vol. 110, pp. 234–242.
Chernyaeva, L.E., Chernyaev, A.M. and Mogilenskikh, A.K., Chemical Composition of Atmospheric Precipitation (Ural and Priuralie), Leningrad: Gidrometeoizdat, 1978 [in Russian].
Serbula, S.M., Miljkovic, D.Dj., Kovacevic, R.M., and Ilic, A.A., Assessment of Airborne Heavy Metal Pollution Using Plant Parts and Topsoil, Ecotox. Environ. Safe., 2012, vol. 76, pp. 209–214.
Ladonin, D.V., Heavy Metal Compounds in Soils: Problems and Methods of Study, Euras. Soil Sci., vol. 35, issue 6, pp. 605–613.
Gedgafova, F.V. and Uligova, T.S., Heavy Metals in Natural and Technogenic Ecosystems of the Central Caucasus, Russ. J. Ecol., 2007, vol. 38, issue 4, pp. 295–298.
García-Sánchez, A., Alonso-Rojo, P. and Santos-Francés, F., Distribution and Mobility of Arsenic in Soils of a Mining Area (Western Spain), Sci. Tot. Environ., 2010, vol. 408,issue 19, pp. 4194–4201.
Candeias, C., Ferreira da Silva, E., Salgueiro, A.R., Pereira, H.G., Reis, A.P., Patinha, C., Matos, J.X., and Avila, P.H., Assessment of Soil Contamination by Potentially Toxic Elements in the Aljustrel Mining Area in Order to Implement Soil Reclamation Strategies, Land Degrad. Dev., 2011, vol. 22, issue 6, pp. 564–585.
Avessalamova, I.A., The Functioning and Dynamics of Mountain Landscapes, in Geography, Society, Environment, Vol. 2: The Functioning and Present State of Landscapes K.N. Dyakonov and E.P. Romanova, Eds., Moscow: Gorodets, 2004, pp. 154–170 [in Russian].
Makhinova, A.F., Makhinov, A.N., Kuptsova, V.A., Liu, S., and Ermoshin, V.V., Landscape–Geochemical Zoning of the Amur Basin (Russian Territory), Russ. J. Pac. Geol., 2014, vol. 8, issue 2, pp. 138–150.
Povilaitis, M.M., The Main Features of Mineralogy of the Dzhida Molybdenum-Tungsten Deposit, Moscow: Akad. Nauk SSSR, 1960 [in Russian].
Shagzhiev, K.Sh., Ral’din, B.B. and Radnaev, B.L., An Ecologo-Economic Characteristic of Problematic Areas, in Buryatia: Natural Resources, K.Sh. Shagzhiev, Ed., Ulan-Ude: Buryat. Univ., 1997, pp. 234–248 [in Russian].
Khodanovich, P.Yu., Yatsenko, R.I. and Smirnova, O.K., Technogenic Sands of Dzhida GOK as the Deposit of Complex Ores, Proc. Sci. Conf. “Zakamenka in the 21st Century” (September 25–26, 2002, Zakamenka), Ulan-Ude: Vost.-Sib. Technol. Univ., 2002, pp. 61–67 [in Russian].
Smirnova, O.K., Sarapulova, A.E. and Tsyrenova, A.A., Peculiarities of Heavy Metal Occurrence in Geotechnogenic Landscapes of Dzhida W-Mo Plant, Geoekologiya, 2010, no. 4, pp. 319–327 [in Russian].
Smirnova, O.K. and Plyusnin, A.M., The Dzhida Ore District (Problems of the State of Environment), Ulan-Ude: Izd-vo BNTs SORAN, 2013 [in Russian].
Ufimtsev, G.F., Mountain Belts of Continents, and Symmetry of the Relief of the Earth, N.A. Logachev, Ed., Novosibirsk: Nauka, 1991 [in Russian].
Zinovyeva, I.G., Sokolov, A.V., Fedorov, I.B., Shul’gina, L.I., Patrin, E.V., Mochalkina, T.T., Gordeeva, O.I., Gusev, Yu.P., Alsadaev, I.T., Chebunina, O.A., Katyukha, V.A., and Bagryantseva, T.M., The Second Phase of Measures for the Elimination of Ecological Consequences of the Operation of Dzhida W-Mo Plant in the Zakamenskii District of the Republic of Buryatia: Pre-Project Survey, Chita: Gidrospetsstroi, 2011 [in Russian].
Dobrovol’skii, V.V. and Urusevskaya, I.S., Geography of Soils, Moscow: Izd-vo Moscow Univ; Izd-vo KolosS, 2004 [in Russian].
Nogina, N.A., Soils of Transbaikalia, Moscow: Nauka, 1964 [in Russian].
Kabata-Pendias, A., Trace Elements in Soils and Plants, 4th Ed., Boca Raton: CRC Press, 2010.
GN 2.1.7.2041-06 “Maximum Allowable Concentrations (MAC) of Chemical Substances in Soil” as Approved by the Chief State Sanitary Physician of the RF G.G. Onishchenko on January 19, 2006. URL: shipov. net/c_ 4655_snip_110042.html. Accessed 03.7.2015 [in Russian].
GN 2.1.7.2042-06 “Tentatively Allowable Concentrations (TAC) of Chemical Substances in Soil as Approved by the Chief State Physician of the RF G.G. Onishchenko on January 19, 2006. URL: www.norm-load.ru/SNiAxData1/46/46590/index.htm. Accessed 03.7.2015 [in Russian].
Procedural Recommendations for Assessment of Urban Soil and Snow Cover Pollution by Heavy Metals, Compiled by V.A. Bol’shakov, Yu.N. Vodyanitskii, T.I. Borisochkina, Z.N. Kakhnovich, and V.V. Myasnikov, Moscow: V.V. Dokuchaev Soil Science Institute, 1999 [in Russian].
Environmental Geochemistry, Yu.E. Saet, B.A. Rrvich, E.P. Yanin, R.S. Smirnova, I.L. Basharkevich, T.L. Onishchenko, L.I. Pavlova, T.Ya. Trefilova, A.I. Achkasov, and S.Sh. Sarkisyan, Moscow: Nedra, 1990 [in Russian].
Kasimov, N.S., Bitiukova, V.R., Kislov, A.V., Kosheleva, N.E., Nikiforova, E.M., Malkhazova, S.M., and Shartova, N.V., Problems of Ecological Geochemistry of Big Cities, Okhrana i Razvedka Nedr, 2012, no. 7, pp. 8–13 [in Russian].
Novoselov, S.S., Investigation of Air Emissions of Boiler Oil Solid Combustion Products, and Development of Methods for Minimizing Them, Extended Abstract of Cand. Sci. (Techn.) Dissertation, Moscow, 1983 [in Russian].
Greenwood, N.N. and Earnshaw, A., Chemistry of the Elements, Second Ed., Oxford: Butterworth-Heinemann, 1997.
Udachin, V.N., Ecological Geochemistry of the Mining Technogenesis in Southern Ural, Extended Abstract of Dr. Sci. (Geol.-Mineral.) Dissertation, Miass, 2012 [in Russian].
Ivanov, V.V., Ecological Geochemistry of the Elements: Reference Book in 6 Books, Book 5: Rare d-Elements, Moscow: Ekologiya, 1997 [in Russian].
Procedural Instructions 2.1.7.730-99 “Sanitary Assessment of the Soil Quality of Settlements” as Approved by the Chief State Sanitary Physician of the RF on February 7, 1999. URL: snipov.net/c_4655_ snip_99446.html. Accessed 03.7.2015 [in Russian].
Prusakov, V.M., Prusakova, A.V., Basaraba, I.N., Anglyuster, M.V., Khodanovich, P.Yu., Smirnova, O.K., and Yatsenko, R.I., Assessment of Risk to health of the Child Population From the Impact of Sands of Technogenic Sands of tungsten-molybdenum GOK, Byulleten’ VSNTs SORAMN, 2005, no. 8, pp. 55–60 [in Russian].
Sinitsa, I.V., Development and Investigations of the Parameters of the Method for Consolidating Dust-Emitting Surfaces of Tailing Ponds, Extended Abstract of Cand. Sci. (Techn.) Dissertation, Belgorod, 2008 [in Russian].
Koptsik, G.N., Problems and Prospects Concerning Phytoremediation of Heavy Metal Polluted Soils: A Review, Euras. Soil. Sci, vol. 47, issue 9, pp. 923–939.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © I.V. Timofeev, N.S. Kasimov, N.E. Kosheleva, 2016, published in Geografiya i Prirodnye Resursy, 2016, Vol. 37, No. 3, pp. 49–61.
Rights and permissions
About this article
Cite this article
Timofeev, I.V., Kasimov, N.S. & Kosheleva, N.E. Soil cover geochemistry of mining landscapes in the South-East of Transbaikalia (City of Zakamensk). Geogr. Nat. Resour. 37, 200–211 (2016). https://doi.org/10.1134/S1875372816030033
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1875372816030033