Abstract
This review summarizes the experimental kinetic data on the polymerization of various monomers mediated by reversible addition-fragmentation chain-transfer agents of various classes and the results of model experiments illustrating the conditions under which the products of termination of radical intermediates may be formed. The contributions of these reactions to the overall kinetics of the process are considered. An approach to the study of reversibility of termination reactions of intermediates is advanced.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
J. Chiefari, Y. K. Chong, F. Ercole, J. Krstina, J. Jeffery, T. P. T. Le, R. T. A. Mayadunne, G. F. Meijs, C. L. Moad, G. Moad, E. Rizzardo, S. H. Thang, Macromolecules 31, 5559 (1998).
C. Barner-Kowollik, M. Buback, B. Charleux, M. L. Coote, M. Drache, T. Fukuda, A. Goto, B. Klumperman, A. B. Lowe, J. B. Mcleary, G. Moad, M. J. Monteiro, R. D. Sanderson, M. P. Tonge, and P. Vana, J. Polym. Sci., Part A: Polym. Chem. 44, 5809 (2006).
G. Moad, E. Rizzardo, and S. H. Thang, Polymer 49(5), 1079 (2008).
Handbook of RAFT Polymerization, Ed. by C. Barner-Kowollik (Wiley-VCH, Weinheim, 2008).
G. Moad, E. Rizzardo, and S. H. Thang, Aust. J. Chem. 65, 985 (2012).
G. Moad, Macromol. Chem. Phys. 215, 9 (2014).
M. Buback, W. Meiser, and P. Vana, Aust. J. Chem. 62, 1484 (2009).
W. Meiser, J. Barth, M. Buback, H. Kattner, P. Vana, Macromolecules 44, 2474 (2011).
D. Konkolewicz, B. S. Hawkett, A. Gray-Weale, and S. Perrier, Macromolecules 41, 6400 (2008).
D. Konkolewicz, B. S. Hawkett, A. Gray-Weale, and S. Perrier, J. Polym. Sci., Part A: Polym. Chem. 47, 3455 (2009).
E. Chernikova, V. Golubev, A. Filippov, C. Y. Lin, M. L. Coote, Polym. Chem. 1, 1437 (2010).
V. B. Golubev, A. N. Filippov, E. V. Chernikova, M. L. Coote, C. Y. Lin, G. Gryn’ova, Polym. Sci., Ser. C 53(1), 14 (2011).
E. Chernikova, A. Morozov, E. Leonova, E. Garina, V. Golubev, Ch. Bui, B. Charleux, Macromolecules 37(19), 6329 (2004).
E. T. A. van den Dungen, H. Matahwa, J. B. McLeary, R. D. Sanderson, B. Klumperman, J. Polym. Sci., Part A: Polym. Chem. 46, 2500 (2008).
J. Moad Gchiefari, Y. K. Chong, J. Krstina, R. T. A. Mayadunne, A. Postma, E. Rizzardo, S. H. Thang, Polym. Int. 49(9), 993 (2000).
F. Ganachaud, M. J. Monteiro, R. G. Gilbert, M.-A. Dourges, S. H. Thang, E. Rizzardo, Macromolecules 33(18), 6738 (2000).
E. V. Chernikova, A. V. Tarasenko, E. S. Garina, and V. B. Golubev, Polym. Sci., Ser. A 48(10), 1046 (2006).
A. D. Peklak, A. Butte, G. Storti, and M. Morbidelli, J. Polym. Sci., Part A: Polym. Chem. 44, 1071 (2006).
Y. K. Chong, J. Krstina, T. P. T. Le, G. Moad, A. Postma, E. Rizzardo, S. H. Thang, Macromolecules 36, 2256 (2003).
E. V. Chernikova, P. S. Terpugova, A. A. Baskakov, A. V. Plutalova, E. S. Garina, E. V. Sivtsov, Polymer Science 52(3–4), 119 (2010).
P. Vana, T. P. Davis, and C. Barner-Kowollik, Macromol. Theory Simul. 11, 823 (2002).
C. Barner-Kowollik, J. F. Quinn, D. R. Morsley, and T. P. Davis, J. Polym. Sci., Part A: Polym. Chem. 39, 1353 (2001).
C. Barner-Kowollik, M. L. Coote, T. P. Davis, L. Radom, P. Vana, J. Polym. Sci., Part A: Polym. Chem. 41, 2828 (2003).
F. M. Calitz, J. B. McLeary, J. M. McKenzie, M. P. Tonge, B. Klumperman, R. D. Sanderson, Macromolecules 36(26), 9687 (2003).
M. J. Monteiro and H. de Brouwer, Macromolecules 34, 349 (2001).
Y. Kwak, A. Goto, K. Komatsu, Y. Sugiura, T. Fukuda, Macromolecules 37, 4434 (2004).
E. V. Chernikova, P. S. Terpugova, E. S. Garina, and V. B. Golubev, Polym. Sci., Ser. A 49(1), 108 (2007).
J. Xu, J. He, D. Fan, W. Tang, Y. Yang, Macromolecules 39, 3753 (2006).
A. Feldermann, M. L. Coote, M. H. Stenzel, T. P. Davis, C. Barner-Kowollik, J. Am. Chem. Soc. 126, 15915 (2004).
S. Perrier, C. Barner-Kowollik, J. F. Quinn, P. Vana, T. P. Davis, Macromolecules 35(22), 8300 (2002).
T. Junkers, G. Delaittre, R. Chapman, F. Gunzler, E. Chernikova, C. Barner-Kowollik, Macromol. Rapid. Commun. 33, 984 (2012).
Y. Kwak, A. Goto, and T. Fukuda, Macromolecules 37(4), 1219 (2004).
R. Venkatesh, B. B. P. Staal, B. Klumperman, and M. J. Monteiro, Macromolecules 37(21), 7906 (2004).
E. V. Chernikova, P. S. Terpugova, A. N. Filippov, E. S. Garina, V. B. Golubev, A. I. Gostev, E. V. Sivtsov, Russ. J. Appl. Chem. 82(10), 1882 (2009).
E. V. Chernikova, V. V. Yulusov, K. O. Mineeva, V. B. Golubev, E. S. Garina, Polym. Sci., Ser. B 53(7–8), 437 (2011).
E. V. Chernikova, A. V. Tarasenko, E. S. Garina, and V. B. Golubev, Polym. Sci., Ser. A 50(4), 353 (2008).
Polymer Handbook, Ed. by J. Brandrup, E. H. Immergut, and E. A. Crulue (Wiley, New York, 1999).
K. Ohno, A. Goto, T. Fukuda, J. Xia, K. Matyjaszewski, Macromolecules 31, 2699 (1998).
T. Gruendling, S. Weidner, J. Falkenhagen, and C. Barner-Kowollik, Polym. Chem. 1, 599 (2010).
E. V. Chernikova, Doctoral Dissertation in Chemistry (MGU, Moscow, 2010).
D. G. Hawthorne, G. Moad, A. Postma, E. Rizzardo, S. H. Thang, Macromolecules 32(16), 5457 (1999).
M. Buback, M. Egorov, and A. Feldermann, Macromolecules 37, 1768 (2004).
T. Junkers, A. Theis, M. Buback, T. P. Davis, M. H. Stenzel, P. Vana, C. Barner-Kowollik, Macromolecules 38, 9497 (2005).
A. N. Filippov, Candidate’s Dissertation in Chemistry (MGU, Moscow, 2013).
V. E. Zubarev, Methods of Spin Trap (MGU, Moscow, 1984) [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © E.V. Chernikova, V.B. Golubev, A.N. Filippov, E.S. Garina, 2015, published in Vysokomolekulyarnye Soedineniya, Ser. C, 2015, Vol. 57, No. 1, pp. 106–122.
Rights and permissions
About this article
Cite this article
Chernikova, E.V., Golubev, V.B., Filippov, A.N. et al. The role of termination reactions of radical intermediates in reversible addition-fragmentation chain-transfer polymerization. Polym. Sci. Ser. C 57, 94–109 (2015). https://doi.org/10.1134/S1811238215010026
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1811238215010026