Abstract
The synthesis, porosity and the capability for carbon dioxide gas-capture of functionalized thiophene- pyridine microporous imine-linked polymer synthesized via the Schiff base condensation reaction between (1,3,5-triformyl thienyl benzene) and 2,6-diaminopyridine is described. The structural formation of the polymer was successfully confirmed via 13C NMR (CP-MAS) and IR spectroscopy, and elemental analysis. The polymer has the good thermal stability up to 380°C, a non-defined aggregated particles morphology and amorphous nature. From the argon sorption isotherm at 87 K, the polymer revealed a moderate Brunauer–Emmett–Teller surface area (372 m2/g) and micro-size pores (~5 Å). The CO2 uptake was studied at 273 and 298 K to evaluate the polymer tendency for capturing CO2 from the surrounding atmosphere. At 298 K, the polymer has shown a reversible adsorption-desorption isotherm with significant uptake (11.4 wt %) at 1.0 atm. The binding energy of CO2 at zero gas coverage is 24 kJ/mol and decreased upon loading.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
S. Xu, B. Tan, and A. Parthiban, in Synthesis and Applications of Copolymers (Wiley, Hoboken, 2014), p. 125.
B. Li, Z. Guan, X. Yang, W. Wang, I. Hussain, K. Song, B. Tan, and T. Li, J. Mater. Chem. A 2, 11930 (2014).
R. Dawson, E. Stockel, R. Holst, D. Adams, and A. Cooper, Energy Environ. Sci. 4, 4239 (2011).
Z. Chang, D. Zhang, Q. Chen, and X. Bu, Phys. Chem. Chem. Phys. 15, 5430 (2013).
J. Chun, S. Kang, N, Park, E. Park, X. Jin, K. Kim, H. Seo, S. Lee, H. Kim, W. Kwon, Y. Park, J. Kim, Y. Kim, and S. Son, J. Am. Chem. Soc. 136, 6786 (2014).
L. Tan and B. Tan, Chem. Soc. Rev. 46, 3322 (2017).
C. Diercks and O. Yaghi, Science 3, 355 (2017).
D. Ramimoghadam, E. Gray, and C. Webb, Int. J. Hydrogen Energy 41, 16944 (2016).
C. Sun, P. Wang, H. Wang, and B. Han, Polym. Chem. 7, 5031 (2016).
A. Rengaraj, P. Puthiaraj, Y. Haldorai, N. Heo, S. Hwang, Y. Han, S. Kwon, W. Ahn, and Y. Huh, ACS Appl.Mater. Interfaces 8, 8947 (2016).
S. Altarawneh, S. Behera, P. Jena, and H. El-Kaderi, Chem. Commun. 50, 3571 (2014).
G. Zhu and H. Ren, in Porous Organic Frameworks: Design, Synthesis and Their Advanced Applications (Springer, Berlin; Heidelberg, 2015), p. 13.
M. Rabbani, T. Islamoglu, and H. El-Kaderi, J. Mater. Chem. A 5, 258 (2017).
W. D. Guerra, R. A. Rossi, A. B. Pierini, and S. M. Barolo, J. Org. Chem. 80, 928 (2015).
E. Wolkenberg, D. Wisnoski, H. Leister, Y. Wang, Z. Zhijian, and W. Lindsley, Org. Lett. 6, 1453 (2004).
N. Joshi, V. Saxena, A. Singh, S. P. Koiry, A. K. Debnath, M. M. Chehimi, D. K. Aswal, and S. K. Gupta, Sens. Actuators, B 200, 227 (2014).
S. Altarawneh, T. Jazzazi, T. Ababneh, T. Al Shboul, and I. Al Jaafreh, J. Appl. Polym. Sci. 134, 44331 (2017).
I. Aljaafreh, S. Altarawneh, M. Alomari, A. Almaabreh, and M. Al Amelat, Indones. J. Pure Appl. Chem. Res. 6, 34 (2017).
S. Altarawneh, T. Islamoglu, A. Sekizkardes, and H. El-Kaderi, Environ. Sci. Technol. 49, 4715 (2015).
J. Wang, I. Senkovska, M. Oschatz, M. Lohe, L. Borchardt, A. Heerwig, Q. Liu, and S. Kaskel, ACS Appl. Mater. Interfaces 5, 3160 (2013).
H. Sun, X. Zhao, P. Wang, H. Wang, and B. Han, Sci. China: Chem. 60, 1067 (2017).
D. Pyles, W. Crowe, L. Baldwin, and P. McGrier, ACS Macro Lett. 5, 1055 (2016).
J. J. P. Stewart, J. Mol. Model. 13, 1173 (2007).
J. Binkley, J. Pople, and W. Hehre, J. Am. Chem. Soc. 102, 939 (1980).
A. D. Becke, J. Chem. Phys. 98, 5648 (1993).
A. D. Becke, J. Chem. Phys. 104, 1040 (1996).
C. Lee, W. Yang, and R. G. Parr, Phys. Rev. B: Condens. Matter Mater. Phys. 37, 785 (1988).
G. A. Petersson, A. Bennett,T. G. Tensfeldt, M. A. Al-Laham, W. A. Shirley, and J. A. Mantzaris, J. Chem. Phys. 89, 2193 (1988).
G. A. Petersson, T. G. Tensfeldt, and J. A. Montgomery, Jr., J. Chem. Phys. 94, 6091 (1991).
Y. Zhao and D. G. Truhlar, Theor. Chem. Acc. 120, 215 (2006).
E. Reed, R. B. Weinstock, and F. J. Weinhold, J. Chem. Phys. 83, 735 (1985).
K. D. Vogiatzis, A. Mavrandonakis, W. Klopper, and G. E. Froudakis, ChemPhysChem 10, 374 (2009).
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Altarawneh, S.S., Ababneh, T.S., Al-Momani, L.A. et al. New Microporous Thiophene-Pyridine Functionalized Imine-Linked Polymer for Carbon-Dioxide Capture. Polym. Sci. Ser. B 60, 789–797 (2018). https://doi.org/10.1134/S1560090419010019
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1560090419010019