Abstract
Mesoporous diatomite platelets were employed to synthesize different polystyrene/diatomite composites by in situ polymerization of styrene via simultaneous reverse and normal techniques of atom transfer radical polymerization. Furrier transform infrared spectroscopy, thermogravimetric analysis, differential scanning calorimetry, scanning and transmission electron microscopy, gas and size exclusion chromatography were used to examine characteristics of polymer and composite. Addition of 3 wt% pristine mesoporous diatomite leads to increase of conversion from 79 to 93%, while control over molecular weight characteristics become worse.
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Khezri, K., Fazli, Y. Polystyrene/mesoporous diatomite composites by in situ simultaneous reverse and normal initiation technique for atom transfer radical polymerization. Polym. Sci. Ser. B 59, 109–116 (2017). https://doi.org/10.1134/S1560090417010092
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DOI: https://doi.org/10.1134/S1560090417010092