Abstract
A new polyfunctional monomer, 2-chloromethyl-1-(p-vinylphenyl)cyclopropane, was synthesized, and its radical copolymerization with styrene was performed. The copolymerization constants were determined, and the Alfrey–Price Q–e parameters were calculated. The photochemical cross-linking of the synthesized copolymer containing photosensitive groups (cyclopropane ring, chlorinated organic moiety) was studied. The copolymer exhibits relatively high photosensitivity (54 cm2 J–1) and can be used as a photosensitive base of negative photoresists.
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Mizoguchi, K. and Hasegawa, E., Polym. Adv. Technol., 1996, vol. 7, nos. 5–6, pp. 471–477.
Reichmanis, E., Nalamasu, O., Houhihan, F.M., and Novembre, A.E., Polym. Int., 1999, vol. 48, no. 10, pp. 053–1059.
Ohe, Y., Ito, H., Watanabe, N., and Ichimura, K., J. Appl. Polym. Sci., 2000, vol. 77, pp. 2189–2200.
Fonstad, C.G., Microelectronic Devices and Circuit,. 2006, Electronic ed. (http://www2.units.it/carrato/didatt/doc/Fonstad_MicroelecDevCkt_2006EEd.pdf).
Galaktionov, D., Plastiks, 2007, nos. 7–8, p. 53.
Guliyev, K.G., Aliyeva, A.M., Mamedli, S.B., et al., Eur. Chem. Bull., 2016, vol. 5, pp. 108–112.
Vainer, A.Ya., Dyumaev, K.M., Likhachev, I.A., et al., Dokl. Phys. Chem., 2004, vol. 396, part 1, pp. 115–118.
Hou, H., Jiang, J., and Ding, M., Eur. Polym. J., 1999, vol. 35, no. 11, p. 1993.
Guliev, K.G., Ponomareva, G.Z., and Guliev, A.M., Russ. J. Appl. Chem., 2006, vol. 79, no. 3, pp. 488–491.
Guliev, K.G., Ponomareva, G.Z., and Guliev, A.M., Polym. Sci., Ser. B, 2007, vol. 49, nos. 7–8, pp. 196–199.
Guliyev, K.G., Ponomareva, G.Z., and Mamedli, S.B., Prots. Neftekhim. Neftepererab., 2009, vol. 10, no. 2, pp. 183–186.
Subramanian, K., Ramai Reddy, A.V., and Krishnasamy, V., Macromol. Chem. Rapid Commun., 1991, vol. 12, pp. 211–214.
Rehab, A. and Salahuddin, N., Polymer, 1999, vol. 40, pp. 2197–2207.
Guliev, K.G., Ponomareva, G.Z., and Mamedli, S.B., J. Struct. Chem., 2009, vol. 50, no. 4, pp. 720–722.
Guliyev, K.G., Aliyeva, A.M., Ponomaryova, G.Z., et al., Am. J. Appl. Chem., 2015, vol. 3, no. 1, pp. 21–24.
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Original Russian Text © K.G. Guliyev, A.I. Sadygova, G.Z. Ponomareva, A.M. Aliyeva, Ts.D. Gulverdashvili, D.B. Tagiyev, 2018, published in Zhurnal Prikladnoi Khimii, 2018, Vol. 91, No. 2, pp. 257−262.
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Guliyev, K.G., Sadygova, A.I., Ponomareva, G.Z. et al. Synthesis of 2-Chloromethyl-1-(p-vinylphenyl)cyclopropane and Its Copolymerization with Styrene. Russ J Appl Chem 91, 304–309 (2018). https://doi.org/10.1134/S1070427218020209
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DOI: https://doi.org/10.1134/S1070427218020209