Abstract
The dependences of the initial reduced rate of radical homopolymerization on the initial concentration of the monomers were studied for toluene and dimethylformamide solutions of four amine-containing (meth)acrylic esters and amides, and also for N-(n-butyl)acrylamide and n-butyl methacrylate taken for comparison. The concentration effects are similar for all the methacrylic monomers and are specific in the case of acrylamides {N-(n-butyl)acrylamide and N-[3-(dimethylamino)propyl]acrylamide}, which is associated with the specific features of the structure of the prereaction monomeric associates.
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Original Russian Text © D.M. Kamorin, O.A. Kazantsev, S.I. Samodurova, A.P. Sivokhin, M.V. Savinova, 2015, published in Zhurnal Prikladnoi Khimii, 2015, Vol. 88, No. 6, pp. 937-944.
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Kamorin, D.M., Kazantsev, O.A., Samodurova, S.I. et al. Concentration effects in homopolymerization of amine- and amide-containing (meth)acrylic monomers in organic solvents. Russ J Appl Chem 88, 1033–1040 (2015). https://doi.org/10.1134/S1070427215060221
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DOI: https://doi.org/10.1134/S1070427215060221