Abstract
Additive nature of the combined effect of the structure (X, Y substituents) and temperature on the rate and free activation energy has been established for the reactions of phenyloxirane with Y-substituted N-aroylbenzenesulfonamides catalyzed by X-substituted pyridines. The cross reaction series is isoenthalpic with respect to the structural effects. The mechanism of the catalytic process has been discussed.
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Russian Text © The Author(s), 2019, published in Zhurnal Obshchei Khimii, 2019, Vol. 89, No. 12, pp. 1835–1841.
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Shpanko, I.V., Sadovaya, I.V. Isoenthalpy Catalytic Effects of Pyridines in Reactions of Phenyloxyrane with N-Aroylbenzenesulfonamides. Russ J Gen Chem 89, 2358–2363 (2019). https://doi.org/10.1134/S1070363219120053
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DOI: https://doi.org/10.1134/S1070363219120053