Abstract
A possibility to use pyridoxal as an alkylating agent in the reactions of electrophilic mono-, di-, and trisubstitution in the aromatic core of various phenols and polyphenols was demonstrated for the first time. New types of hydroxyl-containing aromatic aldehydes containing vitamin B6 fragment were obtained, and the conditions for their synthesis were optimized.
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Dedicated to the 110th anniversary of M.I. Kabachnik’s birth
Original Russian Text © L.K. Kibardina, A.V. Trifonov, A.R. Burilov, A.S. Gazizov, M.A. Pudovik, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 9, pp. 1486–1492.
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Kibardina, L.K., Trifonov, A.V., Burilov, A.R. et al. Pyridoxal: A New Alkylating Agent in Reactions with Phenols and Polyphenols. Russ J Gen Chem 88, 1832–1837 (2018). https://doi.org/10.1134/S1070363218090116
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DOI: https://doi.org/10.1134/S1070363218090116