Abstract
The reactions of 1,1-dimethylhydrazine with 2,3,5-triphenyl-2Н-tetrazolium and 2,5-diphenyl-3-(4-nitrophenyl)-2Н-tetrazolium chlorides in a solution and on a cellulose carrier have been studied by means of spectrophotometry and chromato–mass spectrometry to develop new chromogenic indicators for detection of 1,1-dimethylhydrazine. 1,3,5-Triphenylformazan and 1,3-diphenyl-5-(4-nitrophenyl)formazan are formed in these reactions, respectively; deep red shifts have been observed. Other products of these reactions result from oligomerization and addition of short-living 1,1-dimethylhydrazyl and tetrazolium radicals.
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Original Russian Text © V.M. Ostrovskaya, D.O. Shchepilov, E.A. Kletter, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 7, pp. 1092–1097.
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Ostrovskaya, V.M., Shchepilov, D.O. & Kletter, E.A. Chromogenic Reaction of 1,1-Dimethylhydrazine with Aryltetrazolium Salts. Russ J Gen Chem 88, 1385–1389 (2018). https://doi.org/10.1134/S107036321807006X
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DOI: https://doi.org/10.1134/S107036321807006X