Abstract
The kinetics of the reaction of a series of α-amino acids with 4-nitrophenyl acetate, 4-nitrophenyl benzoate, and 2,4,6-trinitrophenyl benzoate in aqueous 1,4-dioxane medium has been studied. Kinetics of the reactions involving 4-nitrophenyl acetate and 2,4,6-trinitrophenyl benzoate has complied with the Brønsted dependence and revealed linear correlation between rate constant logarithm and the energy difference of the frontier orbitals of α-amino acids anions.
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Original Russian Text © L.B. Kochetova, T.P. Kustova, L.V. Kuritsyn, 2018, published in Zhurnal Obshchei Khimii, 2018, Vol. 88, No. 1, pp. 84–89.
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Kochetova, L.B., Kustova, T.P. & Kuritsyn, L.V. Reactivity of α-Amino Acids in the Reaction with Esters in Aqueous–1,4-Dioxane Media. Russ J Gen Chem 88, 80–85 (2018). https://doi.org/10.1134/S1070363218010127
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DOI: https://doi.org/10.1134/S1070363218010127