Abstract
Silica-supported perchloric acid (HClO4/SiO2) was used to catalyze the synthesis of tetraazamacrocyclic complexes of Co(II), Ni(II), Cu(II), and Zn(II) from the corresponding metal chlorides, nitrates, or acetates, isatin, and benzene-1,2-diamine in ethanol. The use of HClO4/SiO2 as catalyst allowed the reaction to be performed under stirring at room temperature instead of traditional reflux and completed in two hours. The synthesized complexes were characterized by molar conductance and magnetic susceptibility measurements, IR, electronic, 1H NMR, and mass spectra, and thermogravimetric and X-ray powder analyses. On the basis of these data, six-coordinate octahedral geometry was proposed for all complexes. The synthesized complexes were also tested for antimicrobial activity.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
Kalam, A., Tripathi, V., Srivastav, S., Pandey, Y., Kumar, A., Gupta, A., and Purohit, A., Turk. J. Chem., 2010, vol. 34, p.147.
Singh, D.P. and Kumar, R., Transition Met. Chem., 2006, vol. 31, p.970.
Singh, D.P. and Kumar, R., J. Serb. Chem. Soc., 2007, vol. 72, no. 11, p. 1069.
Rathi, P. and Singh, D.P., Pharma Chem., 2014, vol. 6, no. 5, p.203.
Singh, D.P., Malik, V., Kumar, R., and Kumar, K., Russ. J. Coord. Chem., 2010, vol. 36, no. 3, p.220.
Shakir, M. and Verkey, S.P., Polyhedron, 1995, vol. 14, p. 1117.
Singh, R.V. and Chaudhary, A., J. Inorg. Biochem., 2004, vol. 98, p. 1712.
Kamble, V.T. and Ibatte, S.N., Int. J. Chem. Sci., 2013, vol. 11, p. 1858.
Chandra, S. and Verma, S., Spectrochim. Acta, Part A, 2008, vol. 71, p.458.
Singh, D.P., Grover, V., Kumar, K., and Jain, K., J. Serb. Chem. Soc., 2011, vol. 76, no. 3, p.385.
Singh, D.P., Kumar, R., Kambhoj, M., Grover, V., and Jain, K., Russ. J. Coord. Chem., 2008, vol. 34, no. 3, p.233.
Nivasan, S.S. and Athappan, P.A., Transition Met. Chem., 2001, vol. 26, p.588.
Zeng, Q., Sun, J., Gou, S., Zhou, K., Fang, J., and Chen, H., Transition Met. Chem., 1998, vol. 23, p.371.
Casa, J.S., Castellano, E.E., and Tasande, M.S.G., Inorg. Chim. Acta, 2000, vol. 304, p.283.
Singh, A.K., Singh, R., and Saxena, P., Transition Met. Chem., 2004, vol. 29, p.867.
Dey, D.K., Bhandopadhya, D., Nandi, K., Paddan, S.N., and Mukhopadhay, S.G., Synth. React. Inorg. Met.-Org. Chem., 1992, vol. 22, p. 1111.
Mohamed, A.K., Islam, K.S., Hasan, S.S., and Shakir, M., Transition Met. Chem., 1999, vol. 24, p.198.
Loderio, C., Bastida, R., Bértolo, E., Macias, R., and Rodriguez, A., Transition Met. Chem., 2003, vol. 28, p.388.
Chandra, S. and Pundir, M., Spectrochim. Acta, Part A, 2007, vol. 68, p.883.
Rana, V.B., Singh, D.P., Singh, P., and Teotia, M.P., Transition Met. Chem., 1982, vol. 7, p.174.
Singh, S. and Gupta, L.K., Spectrochim. Acta, Part A, 2004, vol. 60, p. 2767.
Singh, D.P., Malik, V., Kumar, R., Kumar, K., and Dhiman, S.S., J. Serb. Chem. Soc., 2010, vol. 75, no. 10, p. 1369.
Rana, V.B., Singh, D.P., and Teotia, M.P., Transition Met. Chem., 1981, vol. 6, p.36.
Rana, V.B., Singh, D.P., and Teotia, M.P., Polyhedron, 1982, vol. 1, p.377.
Lever, A.B.P., Inorganic Electronic Spectroscopy, Amsterdam: Elsevier, 1968, 2nd ed.
Raman, N., Ravichandran, S., and Thangaraja, C., J. Chem. Sci., 2004, vol. 116, p.215.
El-Boraey, H.A., Emam, S.M., Tolan, D.A., and El-Nahas, A.M., Spectrochim. Acta, Part A, 2011, vol. 62, p.360.
Singh, D.P., Kumar, P., Surain, P., and Aneja, K.R., J. Inclusion Phenom. Macrocyclic Chem., 2014, vol. 78, p.363.
Geary, W.J., Coord. Chem. Rev., 1971, vol. 7, p.122.
Naik, A.D., Annigeri, S.M., Gangadharmath, U.B., Revankar, V.K., and Mahale, V.B., J. Inclusion Phenom. Macrocyclic Chem., 2002, vol. 43, p.291.
Nisari, M.S. and Amiri, A., Transition Met. Chem., 2006, vol. 31, p.157.
Khan, T.A. and Shagupta, M., Transition Met. Chem., 1999, vol. 24, p.669.
Kareem, A., Zafar, H., Sherwani, A., Mohammed, O., and Khan, T.A., J. Mol. Struct., 2014, vol. 1075, p.17.
Munde, A.S., Jagdale, A.N., Jadhav, S.M., and Chondhekar, T.K., J. Serb. Chem. Soc., 2010, vol. 75, no. 3, p.349.
Shaikh, R.A., Wani, M.Y., Shaikh, S., Khan, L.A., and Hasmi, A.A., Arabian J. Chem., 2012. DOI: 10.1016/j.arabjc.2011.08.003
Sadana, A.K., Mirza, Y., Aneja, K.R., and Prakash, O., Eur. J. Med. Chem., 2003, vol. 38, p.533.
Fahmi, N., Sharma, S., Kumar, R., and Singh, R.V., Chem. Sci. Rev. Lett., 2014, vol. 3, no. 11, p.488.
Shukla, P.K., Verma, A., and Pathak, P., Arch. Appl. Sci. Res., 2014, vol. 6, p.18.
Kantevari, S., Vuppalapati, S.V.N., Biradar, D.O., and Nagarapu, L., J. Mol. Catal., A: Chem., 2007, vol. 266, p.109.
Bauer, A.W., Kirby, W.M.M., Sherris, J.C., and Truck, M., Am. J. Clin. Pathol., 1966, vol. 45, p. 493.
Author information
Authors and Affiliations
Corresponding author
Additional information
The text was submitted by the authors in English.
Rights and permissions
About this article
Cite this article
Wankhede, D.S., Wagh, P.B. Silica-supported perchloric acid (HClO4/SiO2) as efficient catalyst for the synthesis of tetraazamacrocyclic complexes of transition metals. Russ J Gen Chem 86, 696–701 (2016). https://doi.org/10.1134/S1070363216030300
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070363216030300