Abstract
Reaction of elemental (white) phosphorus with proton-donor reagents has been studied. The following organophosphorus compounds containing P-O and P-S bonds have been synthesized: metal hypophosphites and phosphites, and ammonium salts of O,O′-diesters of dithiophosphoric, S,S′-diphenyldithiophosphoric, S,S′-dialkyltetrathiophosphoric, O,O′-alkylidenedithiophosphoric acids, and octathiotetraphosphetane. The reaction products include highly efficient inhibitors of steel corrosion with carbonic acid and hydrogen sulfide as well as compounds showing fungicide, anticancer, and anti-inflammatory activity.
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Original Russian Text © E.K. Badeeva, E.V. Platova, E.S. Batyeva, 2015, published in Zhurnal Obshchei Khimii, 2015, Vol. 85, No. 2, pp. 219–228.
To the 80th Anniversary of B.I. Ionin
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Badeeva, E.K., Platova, E.V. & Batyeva, E.S. Synthesis of organophosphorus compounds based on the reaction of elemental phosphorus with proton-donor reagents. Russ J Gen Chem 85, 392–401 (2015). https://doi.org/10.1134/S1070363215020085
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DOI: https://doi.org/10.1134/S1070363215020085