Abstract
A unique one-stage synthesis of tetrakis(2-hydroxyethylammonium) salts, precursors of new hypervalent silicon compounds, has been developed. The vibration spectra of tetrakis(2-hydroxyethylammonium) chloride and its triethanolamine precursor and metabolite have been studied by IR spectroscopy and quantum chemistry. Analysis of alterations in the modes with increasing number of HOCH2CH2 groups has been performed.
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Original Russian Text © G.S. Buslaev, I.S. Ignat’ev, N.G. Tyurnina, T.A. Kochina, 2014, published in Zhurnal Obshchei Khimii, 2014, Vol. 84, No. 10, pp. 1624–1628.
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Buslaev, G.S., Ignat’ev, I.S., Tyurnina, N.G. et al. Synthesis, molecular structure, and vibrational spectra of tetrakis(2-hydroxyethylammonium) chloride and its triethanolamine precursor and metabolite. Russ J Gen Chem 84, 1904–1908 (2014). https://doi.org/10.1134/S1070363214100065
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DOI: https://doi.org/10.1134/S1070363214100065