Abstract
Three coordination complexes [Co(Imphtpy)2]Cl2 · CHCl3 · 3H2O (I), [Ni(Imphtpy)2]Cl2 · CHCl3 · C2H5OH (II) and [Zn(Imphtpy)]Cl2 (III) (Imphtpy = 4'-(4-(imidazol-1-yl)phenyl)2,2':6',2″-terpyridine) have been synthesized and characterized by IR, elemental analysis and X-ray single crystal diffraction (СIF files CCDC nos. 1012055 (I), 1011708 (II), 1011709 (III)). Complexes I and II are isomorphism except for some solvent molecules. In the crystal, both face-to-face interactions between pyridyl ring, imidazole rings and phenyl rings and hydrogen bonds facilitate the construction of 3D networks. There are no hydrogen bonds in III and the packing of discrete neutral molecules were ascribed to face-to-face interactions and van der Waals forces. The luminescence properties of three complexes have been investigated in the solid state at room temperature.
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Alcock, N.W., Barker, P.R., Haider, J.M., et al., Dalton Trans., 2000, vol. 29, p. 1447.
Lee, Y.H., Kubota, E., Fuyuhiro, A., et al., Dalton Trans., 2012, vol. 41, p. 10825.
Misra, P., Liao, C.-Y., Wei, H.-H., et al., Polyhedron, 2008, vol. 27, p. 1185.
Komatsu, Y., Kato, K., Yamamoto, Y., et al., Eur. J. Inorg. Chem., 2012, vol. 2012, p. 2769.
Liu, P. and Wong, E.L., -M., Yuen, A.W.-H., et al., Org. Lett., 2008, vol. 10, p. 3275.
Ma, Z., Wei, L., Alegria, E.C., et al., Dalton Trans., 2014, vol. 43, p. 4048.
Bomben, P.G., Robson, K.C.D., Koivisto, B.D., et al., Coord. Chem. Rev., 2012, vol. 256, p. 1438.
Yin, J.-F., Velayudham, M., Bhattacharya, D., et al., Coord. Chem. Rev., 2012, vol. 256, p. 3008.
Senechal, K., Toupet, L., Ledoux, I., et al., Chem. Commun., 2004, p. 2180.
Granifo, J., Gavino, R., Freire, E., et al., Acta Crystallogr., Sect. C: Cryst. Struct. Commun., 2013, vol. 69, p. 822.
Constable, E.C., Housecroft, C.E., Murray, N.S., et al., Polyhedron, 2013, vol. 54, p. 110.
Kumar, A., Chinta, J.P., Ajay, A.K., et al., Dalton Trans., 2011, vol. 40, p. 10865.
Gai, Y.-L., Jiang, F.-L., Chen, L., et al., Dalton Trans., 2013, vol. 42, p. 9954.
Zhang, N., Yang, J., Hu, R.-X., et al., Z. Anorg. Allg. Chem., 2013, vol. 639, p. 197.
Kon, H. and Nagata, T., Dalton Trans., 2013, vol. 42, p. 5697.
Yuan, F., Xie, J., Hu, H.-M., et al., CrystEngComm, 2013, vol. 15, p. 1460.
Zhou, H., Zhou, F., Wu, P., et al., Dyes Pigments, 2011, vol. 91, p. 237.
Beves, J.E., Constable, E.C., Housecroft, C.E., et al., Polyhedron, 2008, vol. 27, p. 2395.
Constable, E.C., Figgemeier, E., Housecroft, C.E., et al., Dalton Trans., 2008, p. 6752.
Kharat, A.N., Bakhoda, A., and Zamanian, S., Polyhedron, 2011, vol. 30, p. 1134.
Kharat, A., Bakhoda, A., and Tamaddoni Jahromi, B., Polyhedron, 2011, vol. 30, p. 2768.
Kharat, A.N., Bakhoda, A., Bruno, G., et al., Polyhedron, 2012, vol. 45, p. 9.
Naseri, Z., Nemati Kharat, A., Banavand, A., et al., Polyhedron, 2012, vol. 33, p. 396.
Kharat, A.N., Bakhoda, A., and Hajiashrafi, T., J. Mol. Catal., A, 2010, vol. 333, p. 94.
Tan, J., Li, R., Li, D., et al., Dalton Trans., 2015, vol. 44, p. 1473.
Zhou, H.-P., Gan, X.-P., Li, X.-L., et al., Cryst. Growth Des., 2010, vol. 10, p. 1767.
Xu, D., Yang, M., Wang, Y., et al., J. Coord. Chem., 2013, vol. 66, p. 2992.
Wang, P., Luo, L., Okamura, T.-A., et al., Polyhedron, 2012, vol. 44, p. 18.
Zhou, F.-X., Zheng, Z., Zhou, H.-P., et al., CrystEngComm, 2012, vol. 14, p. 5613.
Wang, P., Li, Z., Lv, G.-C., et al., Inorg. Chem. Commun., 2012, vol. 18, p. 87.
Zhou, H., Wang, J., Zhou, F., et al., Dyes Pigments, 2012, vol. 95, p. 723.
Uma, V., Kanthimathi, M., Weyhermuller, T., et al., J. Inorg. Biochem., 2005, vol. 99, p. 2299.
Indumathy, R., Kanthimathi, M., Weyhermuller, T., et al., Polyhedron, 2008, vol. 27, p. 3443.
Sathyaraj, G., Weyhermuller, T., and Nair, B.U., Eur. J. Med. Chem., 2010, vol. 45, p. 284.
Manikandamathavan, V.M., Parameswari, R.P., Weyhermuller, T., et al., Eur. J. Med. Chem., 2011, vol. 46, p. 4537.
Rajalakshmi, S., Weyhermuller, T., Freddy, A.J., et al., Eur. J. Med. Chem., 2011, vol. 46, p. 608.
Fang, W., Liu, C., Chen, J., et al., Chem. Commun. (Camb.), 2015, vol. 51, p. 4267.
Chen, M.-S., Hua, W.-J., Song, Y., et al., Inorg. Chim. Acta, 2012, vol. 387, p. 137.
Hu, F.-L., Mi, Y., Gu, Y.-Q., et al., CrystEngComm, 2013, vol. 15, p. 9553.
Yang, L.-Z., Fang, R., Dou, W., et al., CrystEngComm, 2015, vol. 17, p. 3117.
Wang, C.X., Li, L., Yu, W.T., et al., Acta Crystallogr., Sect. E: Struct. Rep. Online, 2006, vol. 62, p. o246.
Wang, J. and Hanan, G.S., Synlett, 2005, vol. 2005, p. 1251.
Sheldrick, G., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p. 112.
McMurtrie, J. and Dance, I., CrystEngComm, 2009, vol. 11, p. 1141.
McMurtrie, J. and Dance, I., CrystEngComm, 2010, vol. 12, p. 3207.
Zibaseresht, R. and Hartshorn, R.M., Dalton, Trans., 2005, vol. 35, p. 3898.
Stafford, V.S., Suntharalingam, K., Shivalingam, A., et al., Dalton Trans., 2015, vol. 44, p. 3686.
Huang, W. and Qian, H., J. Mol. Struct., 2008, vol. 874, p. 64.
Ma, Z., Cao, Y., Li, Q., et al., J. Inorg. Biochem., 2010, vol. 104, p. 704.
Walesa-Chorab, M., Stefankiewicz, A.R., Ciesielski, D., et al., Polyhedron, 2011, vol. 30, p. 730.
Suntharalingam, K., White, A.J.P., and Vilar, R., Inorg. Chem., 2010, vol. 49, p. 8371.
Kubota, E., Lee, Y.H., Fuyuhiro, A., et al., Polyhedron, 2013, vol. 52, p. 435.
Lee, Y.H., Fuyuhiro, A., Harrowfield, J.M., et al., Eur. J. Inorg. Chem., 2013, vol. 2013, p. 5862.
Fu, W.-W., Zhang, F.-X., Kuang, D.-Z., et al., J. Coord. Chem., 2015, vol. 68, p. 1177.
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Fu, W.W., Huang, Q., Liu, S.T. et al. Syntheses, Crystal Structures, and Luminescence Properties of Co(II), Ni(II) and Zn(II) Complexes with 4′-(4-(Imidazol-1-Yl)phenyl)-2,2′:6′,2″-Terpyridine. Russ J Coord Chem 43, 670–678 (2017). https://doi.org/10.1134/S1070328417100037
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DOI: https://doi.org/10.1134/S1070328417100037