Abstract
The reactions of copper(II) nitrate with 3-oxapentane-1,5-diamine (Oda) were investigated under different molar ratio. In the case of a 1: 1 molar ratio of copper(II) nitrate and Oda, the mononuclear complex [Cu(Oda)(NO3)2] (I) was obtained. In contrast, the treatment of copper(II) nitrate with twice Oda afforded inorganic polymer {[Cu(μ-Oda)(Oda)] · (NO3)2} n (II). The molecular structures of the two new complexes were determined from the elemental analyses, IR spectra and single-crystal X-ray diffraction (CIF files CCDC nos. 828193 (I) and 828018 (II)). Two Cu(II) complexes were both five-coordinated and forming a distorted square-base pyramidal geometry. Two complexes are stabilized by the intermolecular hydrogenbond.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
Solomons, T.W. and Fryhle, C.B., J. Org. Chem., 2009, p. 911.
Zhang, L.J., Li, X.Q., Zhou, Y.S., and Wang, X., J. Mol. Struct., 2009, vol. 928, p. 59.
Kabir, A., Hossain, M., and Kumar, G.S., J. Chem. Thermodyn., 2013, vol. 57, p. 445.
Wang, J.Y. and Casero, R.A., Polyamine Cell Signaling Physiology, Pharmacology, and Cancer Research, New Jersey: Humana Press Inc., 2006.
Obuseng, V., Nareetsile, F., and Kwaambwa, H.M., Anal. Chim. Acta, 2012, vol. 730, p. 87.
Li, N. and Bai, R., Ind. Eng. Chem. Res., 2005, vol. 44, p. 6692.
Liu, C., Bai, R., and Hong, L., Thin Solid Films, 2006, vol. 303, p. 99.
Guo, J., Zhang, L.L., Ma, H.Q., et al., Inorg. Chem. Commun., 2013, vol. 28, p. 75.
Lodeiro, C. and Pina, F., Coord. Chem. Rev., 2009, vol. 253, p. 1353.
Shul’pin, G.B., Stoeckli-Evans, H., Mandelli, D., et al., J. Mol. Catal., A, 2004, vol. 219, p. 255.
Tao, S.M., Xia, S., Rong, L.C., et al., Res. Chem. Intermed., 2012, vol. 38, p. 2065.
Ndinguri, M.W., Fronczek, F.R., Marzilli, P.A., et al., Inorg. Chim. Acta, 2010, vol. 363, p. 1796.
Shen, W., Chen, S.Y., Shi, S.K., et al., Carbohydr. Polym., 2009, vol. 75, p. 110.
Katayev, E.A., Pantos, G.D., Lynch, V.M., et al., Russ. Chem. Bull., 2005, vol. 54, p. 165.
Gade, L.H., J. Organomet. Chem., 2002, vol. 661, p. 85.
Junk, P.C. and Steed, J.W., Inorg. Chim. Acta, 2007, vol. 360, p. 1661.
Shoukry, A.A., J. Solution Chem., 2011, vol. 40, p. 1796.
Yang, X.T., Wu, H., Ma, S.J., et al., Transition Met. Chem., 2011, vol. 36, p. 403.
Pan, G.L., Bai, Y.C., Wang, H., et al., Z. Naturforsch., B: J. Chem. Sci., 2013, vol. 68, p. 57.
SMART SAINT and SADABS, Madison: Bruker AXS, Inc., 2000.
Sheldrick, G.M., SHELXTL, Madison Siemens Analytical X-ray Instruments, Inc., 1996.
Youngme, S., Phatchimkun, J., Sukangpanya, U., et al., Polyhedron, 2007, vol. 26, p. 871.
Matovic’, Z.D., Meetsma, A., Miletic’, V.D., et al., Inorg. Chim. Acta, 2007, vol. 360, p. 2420.
Qiu, J.H., Liao, Z.R., Meng, X.G., et al., Polyhedron, 2005, vol. 24, p. 1617.
Zhang, B., Kou, H.Z., He, Y., et al., Acta Crystallogr., Sect C: Cryst. Struct. Commun., 2004, vol. 60, p. m341.
Mal, D., Tuchagues, J.P., Chakraborty, S., et al., Inorg. Chim. Acta, 2006, vol. 359, p. 4431.
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Wu, H.L., Wang, C.P., Zhang, H. et al. Synthesis and structural characterization of two new copper(II) complexes with 3-oxapentane-1,5-diamine using different molar ratio. Russ J Coord Chem 42, 170–177 (2016). https://doi.org/10.1134/S1070328416030106
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070328416030106