Abstract
Reaction of the Ag+ ions with 2,2'-(4H-1,2,4-triazole-3,4-diyl)dipyridine (L22) in the presence of NO -3 and CH3SO -3 , respectively, affords two silver(I) coordination compounds, namely {[Ag3(NO3)2(C12H9N5)2](NO3)]} n (I) and [Ag(CH3SO3)(C12H9N5)]2 (II). Both complexes have been characterized by single-crystal X-ray diffraction (CIF file CCDC nos. 1051589 (I) and 1051590 (II)). In complex I, the adjacent metal centers are interconnected via L22 ligands to afford a 1D coordination chain. Complex II shows the discrete cage-like binuclear coordination pattern with the Ag···Ag distance of 4.358(1) Å.
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Allendorf, M.D., Bauer, C.A., Bhakta, R.K., et al., Chem. Soc. Rev., 2009, vol. 38, p. 1330.
Getman, R.B., Bae, Y.S., Wilmer, C.E., et al., Chem. Rev., 2012, vol. 112, p. 703.
Moulton, B. and Zaworotko, M.J., Chem. Rev., 2001, vol. 101, p. 1629.
Khavasi, H.R. and Sadegh, B.M.M., Inorg. Chem., 2010, vol. 49, p. 5356.
Long, L.S., CrystEngComm, 2010, vol. 12, p. 1354.
Tang, M., Guo, W., Zhang, S.Z., et al., Inorg. Chem. Commun., 2011, vol. 14, p. 1217.
Chen, J., Liu, S.Y., and Li, C.P., Inorg. Chim. Acta, 2011, vol. 378, p. 206.
Chen, J., Li, C.P., Shang, J., et al., Inorg. Chem. Commun., 2012, vol. 15, p. 172.
Liu, P.W., Li, C.P., Bi, Y., et al., J. Coord. Chem., 2013, vol. 66, p. 2012.
Sun, N., Yan, Y., and Chen, J., J. Mol. Struct., 2013, vol. 1047, p. 324.
Klingele, M.H. and Brooker, S., Eur. J. Org. Chem., 2004, p. 3422.
Sheldrick, G.M., SHELXS-97, Program for the Solution of Crystal Structures, Göttingen: Univ. of Göttingen, 1997.
Sheldrick, G.M., SHELXL-97, Program for the Refinement of Crystal Structures, Göttingen: Univ. of Göttingen, 1997.
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Liu, B.L., Li, M.Z., Li, C.P. et al. Anion-directed assembly of two AgI complexes based on 2,2'-(4H-1,2,4-triazole-3,4-diyl)dipyridine. Russ J Coord Chem 41, 695–700 (2015). https://doi.org/10.1134/S1070328415100048
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DOI: https://doi.org/10.1134/S1070328415100048