Abstract
Three new metal-organic complexes, [Cd4(2,3-Pdc)4 · 4H2O] (I), [Fe4(2,3-Pdc)4 · 12H2O] (II), [Ba8(2,3-Pdc)4 · 12H2O] (III) (2,3-Pdc = 2,3-pyridinedicarboxylic acid), have been synthesized and characteristic by IR spectrum, elemental analysis, single-crystal X-ray diffraction, thermogravimetric analysis. X-ray structure analysis shows that complex I is 3D structure, complex II and complex III are 1D chain structures (CIF files CCDC nos. 1002757 (I), 1002888 (II) and 1002980 (III)). 2,3-Pdc has many kinds of coordination mode, so it can form many different of coordination polymers. Complexes can be packed by the weak C-H⋯O, N-H⋯O and π-π interactions.
Article PDF
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
References
Batten, S.R. and Robson, R., Angew. Chem. Int. Ed., 1998, vol. 37, p. 1460.
Leininger, S., Olenyuk, B., and Stang, P.J., Chem. Rev., 2000, vol. 100, p. 853.
Swiegers, G.F. and Malefetse, T.J., Chem. Rev., 2000, vol. 100, p. 3483.
Moulton, B. and Zaworotko, M.J., Chem. Rev., 2001, vol. 101, p. 1629.
Holliday, B.J. and Mirkin, C.A., Angew. Chem. Int. Ed., 2001, vol. 40, p. 2022.
Eddaoudi, M., Moler, D.B., and Li, H., Chem. Res., 2001, vol. 34, p. 319.
Caulder, D.L. and Raymond, K.N., Acc. Chem. Res., 1999, vol. 32, p. 975.
Song, L.F., Jiang, C.H., Jiao, C.L., Zhang, J., et al., Cryst. Growth. Des., 2010, vol. 10, p. 5020.
Sun, D., Wang, D.F., Zhang, N., Huang, R.B., et al., Cryst. Growth. Des., 2010, vol. 10, p. 5031.
An, H.Y., Han, Z.B., and Xu, T.Q., Inorg. Chem., 2010, vol. 49, p.11403.
Zou, R.Q., Sakurai, H., and Xu, Q., Angew. Chem. Int. Ed., 2006, vol. 45, p. 2542.
Liu, Y., Kravtsov, V.C., and Eddaoudi, M., Angew. Chem. Int. Ed., 2008, vol. 47, p. 8446.
Wang, S., Zhang, L., Li, G., et al., CrystEngComm, 2008, vol. 10, p. 1662.
Liu, Y., Kravtsov, V., Walsh, R.D., et al., Chem. Commun., 2004, p. 2806.
Liu, Y., Kravtsov, V., Larsena, R., and Eddaoudi, M., Chem. Commun., 2006, p. 1488.
Nouar, F., Eckert, L., Eubank, J.F., et al., J. Am. Chem. Soc., 2009, vol. 131, p. 2864.
Woodward, J.D., Backov, R.V., Abboud, K.A., and Talham, D.R., Polyhedron, 2006, vol. 25, p. 2605.
Blessing, R.H., Acta Crystallogr., A, 1995, vol. 51, p. 33.
Sheldrick, G.M., SHELXTL-97, Program for Refining Cystal Sructure Refinement, Göttingen (Germany): Univ. of Göttingen, 1997.
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Huang, Y.F., Shi, Z.W., Liu, Y. et al. Synthesis, crystal structure, and thermal properties of three novel complexes based on 2,3-Pdc. Russ J Coord Chem 41, 325–333 (2015). https://doi.org/10.1134/S1070328415050036
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070328415050036