Abstract
Phenylacetates [AnO2(C6H5CH2COO)2], where An = U (I), Np (II), or Pu (III), were synthesized and studied by single crystal X-ray diffraction. Compounds I–III are isostructural and crystallize in the monoclinic system, space group C2/c, Z = 4. The main structural units in crystals of I–III are 1D chains [AnO2·(C6H5CH2COO)2] belonging to crystal-chemical group \({\rm{AB}}_2^{11}\) (\({\rm{A}} = {\rm{AnO}}_2^{2 + }\), B11 = C6H5CH2COO−). The intermolecular interactions in the structures of [AnO2L2] crystals, where L is benzoate or phenylacetate ion, were analyzed by the method of molecular Voronoi-Dirichlet polyhedra. The X-ray structural data were confirmed by analysis of the IR and electronic absorption spectra.
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Loiseau, T., Mihalcea, I., Henry, N., and Volkringer, C., Coord. Chem. Rev., 2014, vols. 266–267, pp. 69–109.
Cousson, A., Proust, J., Pages, M., et al., Acta Crystallogr., Sect. C, 1990, vol. 46, no. 6, pp. 2316–2318.
Gao, X., Wang, C., Shi, Z.-F., et al., Dalton Trans., 2015, vol. 44, no. 25, pp. 11562–11571.
Serezhkin, V.N., Medvedkov, Ya.A., Serezhkina, L.B., and Pushkin, D.V., Russ. J. Phys. Chem. A, 2015, vol. 89, no. 6, pp. 1018–1027.
Serezhkin, V.N., Vologzhanina, A.V., Serezhkina, L.B., et al., Acta Crystallogr., Sect. B, 2009, vol. 65, no. 1, pp. 45–53.
Nierlich, M., Iroulart, G., Vigner, D., et al., Acta Crystallogr., Sect. C, 1990, vol. 46, no. 6, pp. 2459–2460.
Navaza, A., Iroulart, M.G., Nierlich, M., et al., Acta Crystallogr., Sect. C, 1993, vol. 49, no. 10, pp. 1767–1770.
Wang, J.-L., Deng, Z.-Y., Duan, S.-B., and Xing, Y.-H., J. Coord. Chem., 2012, vol. 65, no. 20, pp. 3546–3555.
Bismondo, A., Casellato, U., and Graziani, R., Inorg. Chim. Acta, 1994, vol. 223, nos. 1–2, pp. 151–153.
Shchelokov, R.N., Mikhailov, Yu.N., Orlova, I.M., et al., Koord. Khim., 1985, vol. 11, no. 6, pp. 706–709.
Bismondo, A., Casellato, U., Rizzo, L., and Graziani, R., Inorg. Chim. Acta, 1992, vol. 191, no. 1, pp. 69–73.
Cambridge Structural Database System, Cambridge: Cambridge Crystallographic Data Centre, 2017.
Fedoseev, A.M., Gogolev, A.V., Shilov, V.P., et al., Radiochemistry, 2017, vol. 59, no. 6, pp. 570–578.
SAINT-Plus (Version 7.68), Madison, Wisconsin (USA): Bruker AXS, 2007.
Sheldrick, G.M., SADABS, Madison, Wisconsin (USA): Bruker AXS, 2008.
Sheldrick, G.M., Acta Crystallogr., Sect. A, 2008, vol. 64, no. 1, pp. 112–122.
Sheldrick, G.M., Acta Crystallogr., Sect. C, 2015, vol. 71, no. 1, pp. 3–8.
Serezhkin, V.N., Mikhailov, Yu.N., and Buslaev, Yu.A., Russ. J. Inorg. Chem., 1997, vol. 42, no. 12, pp. 1871–1910.
Serezhkin, V.N., Structural Chemistry of Inorganic Actinide Compounds, Krivovichev, S.V., Burns, P.C., and Tananaev, I.G., Eds., Amsterdam: Elsevier, 2007, pp. 31–65.
Serezhkin, V.N. and Serezhkina, L.B., Crystallogr. Rep., 2012, vol. 57, no. 1, pp. 33–42.
Serezhkin, V.N. and Savchenkov, A.V., Cryst. Growth Des., 2015, vol. 15, no. 6, pp. 2878–2882.
Novikov, S.A., Peresypkina, E.V., Serezhkina, L.B., et al., Russ. J. Inorg. Chem., 2014, vol. 59, no. 2, pp. 63–71.
Serezhkin, V.N., Grigoriev, M.S., Abdulmyanov, A.R., et al., Inorg. Chem., 2017, vol. 56, pp. 7151–7160.
Nyquist, R.A. and Settioneri, S.E., Appl. Spectrosc., 1990, vol. 44, no. 10, pp. 1629–1632.
Castro, J.L., Lopez Ramirez, M.R., Lopez Tocon, I., and Otero, J.C., J. Mol. Struct., 2003, vols. 651–653, pp. 602–606.
Krishnamurthy, M.V., Nagar, M.S., and Hon, N.S., J. Radioanal. Nucl. Chem., 1987, vol. 117, no. 2, pp. 91–98.
Lee, H. and Wilmshurst, J.K., Aust. J. Chem., 1969, vol. 22, no. 4, pp. 691–670.
Gruen, D.M., J. Chem. Phys., 1952, vol. 20, no. 11, pp. 1818–1821.
McGlynn, S.P. and Smith, J.K., J. Mol. Spectrosc., 1961, vol. 6, no. 2, pp. 164–187.
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Serezhkin, V.N., Grigor’ev, M.S., Fedoseev, A.M. et al. Synthesis and Structure of U(VI), Np(VI), and Pu(VI) Phenylacetates. Radiochemistry 61, 129–136 (2019). https://doi.org/10.1134/S1066362219020012
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DOI: https://doi.org/10.1134/S1066362219020012