Abstract
Formation of zinc sulfide nanoparticles was detected during interaction of bulk samples with hydrogen sulfide at supercritical parameters. Synthesis proceeds with liberation of H2 by the reaction nZn + nH2S = (ZnS) n + nH2. It has been found by the X-ray diffraction method, scanning electron microscopy, and mass spectrometry that the addition of water stimulates coupled reactions of nanoparticle synthesis nZn + nH2O = (ZnO) n + nH2 and (ZnO) n + nH2S = (ZnS) n + nH2O and brings about an increase in the synthesis rate and morphological changes of (ZnS) n nanoparticles.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
S. C. Tjong, Nanocrystalline Materials: Their Synthesis-Structure-Property Relationships and Applications (Elsevier, Amsterdam, 2006).
X. Fang, T. Zhai, U. K. Gautam, L. Li, L. Wu, Y. Bando, and D. Golberg, Prog. Mater. Sci. 56, 175 (2011).
E. W. Lemmon, M. O. McLinden, and D. G. Freid, http://webbook.nist.gov/chemistry/fluid/.
A. A. Vostrikov, O. N. Fedyaeva, A. V. Shishkin, and M. Ya. Sokol, J. Supercrit. Fluids 48, 154 (2009).
R. A. Lidin, L. L. Andreeva, and V. A. Molochko, Constants of Inorganic Materials (Drofa, Moscow, 2006) [in Russian].
A. A. Vostrikov, O. N. Fedyaeva, A. V. Shishkin, and M. Ya. Sokol, J. Supercrit. Fluids 48, 161 (2009).
T. M. Seward and E. U. Frank, Ber. Bunsenges. Phys. Chem. 85, 2 (1981).
A. A. Vostrikov, O. N. Fedyaeva, A. V. Shishkin, and M. Ya. Sokol, Tech. Phys. Lett. 36(9), 779 (2010).
A. A. Vostrikov, O. N. Fedyaeva, A. V. Shishkin, M. Ya. Sokol, and V. A. Zaikovskii, Tech. Phys. Lett. 38(10), 955 (2012).
A. A. Vostrikov and D. Yu. Dubov, J. Exp. Theor. Phys. 98(2), 197 (2004).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.A. Vostrikov, O.N. Fedyaeva, M.Ya. Sokol, A.V. Shatrova, 2014, published in Pis’ma v Zhurnal Tekhnicheskoi Fiziki, 2014, Vol. 40, No. 23, pp. 41–48.
Rights and permissions
About this article
Cite this article
Vostrikov, A.A., Fedyaeva, O.N., Sokol, M.Y. et al. Synthesis of zinc sulfide nanoparticles during zinc oxidization by H2S and H2S/H2O supercritical fluids. Tech. Phys. Lett. 40, 1057–1060 (2014). https://doi.org/10.1134/S1063785014120141
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1063785014120141