Abstract
The title compound, bis[4-(3′-benzoyl)thiocarbamidophenyl]ether, was synthesized by the reaction of benzoylisothiocyanate with 4,4′-diaminodiphenylether in aprotic solvent. The structure was determinated by means of elemental analysis and FT-IR, 1H-NMR, 13C-NMR and MS spectroscopic techniques. The crystal structure was characterized by X-ray syngle crystal analysis: orthorhombic, sp. gr. Pnna, Z = 4. In crystal packing, there are intramolecular hydrogen bond N-H⋯O generating S(6) motif, and intermolecular hydrogen bond N-H⋯S forming R 22 (8) ring.
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References
K. R. Koch, Coord. Chem. Rev. 216–217, 473 (2001).
A. N. Mautiana, J-D. S. Miller, A. Gie, S. A. Bourneand, and K. R. Koch, Dalton Trans. 1952 (2003).
M. Schuster, Fresenius Z. Anal. Chem. 324,2, 127 (1986).
W. Antholine and F. Taketa, J. Inorg. Biochem. 16, 145 (1982).
C. Limban, A. M. Grumezescu, C. Saviuc, G. Voicu, G, Predan, R. Sakizlian, and M. C. Chifiriuc, Int. J. Mol. Sci. 13, 12584 (2012).
S. Y. Key: and S-J. Xue, Arkivoc (x) 63 (2006)
W. Hernandez, E. Spodine, J. C. Munoz, L. Beyer, U. Schroder, J. Ferreira, and M. Pavani, Bioinorg. Chem. Appl. 1, 271 (2003).
Y. Bessard and R. Crettaz, Tetrahedron 56, 4739 (2000).
G. Binzet, N. Külcü, U. Florke, and H. Arslan, J. Coord. Chem. 62, 3454 (2009)
G. Kavak, S. Özbey, G. Binzet, and N. Kulcü, Turk. J Chem. 33, 857 (2009)
R. Del Campo, J. J. Criado, and R. Georghe, J. Inorg. Biochem. 98(8), 1307 (2004).
N. Selvakumaran, S. N. Weng, E. R. T. Tiekink, and R. Karvembu, Inorg. Chim. Acta 376, 278 (2011).
W. Henderson, B. K. Nicholons, M. B. Dinger, and R. L. Bennett, Inorg. Chim. Acta 338, 210 (2002).
F. Aydin, D. Aykaç, H. Ünver, and N. O. Iskeleli, J. Chem. Crystallogr. 42, 381 (2012).
H. H. Nguyen, P.C. Thang, A. Rodenstein, R. Kirmse, and U. Abram, Inorg. Chem. 50, 590 (2011).
S. A. Bourne, O. Hallale, K. R. Koch, Growth & Design 5, 307 (2005).
S. Saeed, N. Rashid, M. Ali, and R. Hussain, Eur. J. Chem. 1(3), 200 (2010).
D. J. Che, G. Li, X. L. Yao, Q.-J. Wu, W. L. Wang, and Y. Zhu, J. Organomet. Chem. 584, 190 (1999).
G. Y. Sarkis and E. D. Faisal, J. Heterocycl. Chem. 22, 137 (1985).
K. R. Koch, O. Hallale, S. A. Bourne, J. Miller, and J. Bacsa, J. Mol. Struct. 561, 185 (2001).
L. Nie, Z. Li, J. Han, X. Zhang, R. Yang, W. X. Liu, J. W. Xie, Y. F. Zhao, and Y. B. Jiang, J. Org. Chem. 69, 6449 (2004).
A. Saeed, R. A. Khera, N. Abbas, M. Latıf, I. Sajıd, and U. Füorke, Turk J. Chem. 34, 335 (2010).
C. Reichardt, Solvent and Solvent Effects in Organic Chemistry, 2nd ed. (VCH, Weinheim, 1988)
Stoe & Cie X-AREA and X-RED32 (Stoe & Cie, Darmstadt, Germany, 2002)
G. M. Sheldrick, Acta Crystallogr. A 64, 112 (2008).
M. Sukeri, M. Yosof, and B. M. Yamin, Acta Crystallogr. E 60, o1998 (2004)
B. M. Yamin and I. N. Hassan, Acta Crystallogr. E 60, o2514 (2004)
B. M. Yamin, S. Yousuf, M. S. M. Yousf, and R. H. Jusoh, Acta Crystallogr. E 64, o833 (2008).
J. H. Hu, Z. Y. Luo, C. F. Ding, and X. L. Song, Acta Crystallogr. E 67, o376 (2011).
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Aydin, F., Aykaç, D., Burcu Arslan, N. et al. Synthesis, characterization, and crystal structure of bis[4-(3′-benzoyl)thiocarbamidophenyl]ether. Crystallogr. Rep. 59, 955–960 (2014). https://doi.org/10.1134/S1063774514070050
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DOI: https://doi.org/10.1134/S1063774514070050