Abstract
X-ray photoelectron spectroscopy is used as a probe to demonstrate the interaction between cellulose and 1-butyl-3-methylimidazolium chloride. The fitting models of C 1s spectra for the ionic liquid, cellulose and cellulose containing solutions are developed. The measured binding energy of C2 1s component is used to indicate the ionic liquid-cellulose interaction. In the case of the cellulose containing solution, due to the weaker charge-transfer effect between hydrophilic groups of cellulose and the imidazolium cation, the C2 atom is in a more electropositive environment and thus exhibits higher binding energy.
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Men, S., Liu, Y. & Jin, Y. Probing the Cellulose-Ionic Liquids Interaction by X-ray Photoelectron Spectroscopy. Polym. Sci. Ser. A 60, 298–302 (2018). https://doi.org/10.1134/S0965545X18030124
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DOI: https://doi.org/10.1134/S0965545X18030124