Abstract
Solid polymer electrolyte films were prepared by adding Al2O3 particles to poly(vinylpyrrolidone)-MgCl2 ∙ 6H2O salt using solution cast technique. Various analytical techniques have been applied to characterize the prepared polymer films such as XRD, SEM, UV–Vis spectroscopy and AC conductivity. The structural analysis of pure poly(vinylpyrrolidone) complexed with MgCl2 ∙ 6H2O salt showed orthorhombic lattice structure indicating its semi-crystalline nature. SEM analysis reveals the heterogeneous phase of nanocomposite polymer electrolyte systems. The conductivity of Al2O3 doped poly(vinylpyrrolidone) based solid polymer electrolyte was found to be 1.22 × 10–6 S/cm at room temperature for 85: 15 weight composition. Electrochemical cell has been fabricated with the configuration Mg+/(PVP + MgCl2 ∙ 6H2O + Al2O3)/(I2 + C + electrolyte) and its discharge characteristics were studied for a constant load of 100 kΩ. Various cell parameters such as open-circuit voltage, short circuit current, energy density and power density were calculated for the prepared samples.
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25 September 2019
This erratum corrects the Figure 2 of the published paper.
References
M. Jaipal Reddy, J. Siva Kumar, U. V. Subba Rao, and P. P. Chu, Solid State Ionics 177, 253 (2006)
K. Naresh Kumar, T. Sreekanth, M. Jaipal Reddy, and U. V. Subba Rao, J. Power Sources 101, 130 (2001).
K. Murata, Electrochem. Acta 40, 2177 (1995).
X. F. Yang, G. C. Wang, R. Y. Wang, and X. W. Li, Electrochim. Acta 55, 5414 (2010).
R. A. Irgashev, A. A. Karmatsky, S. A. Kozyukhin, V. K. Ivanov, A. Sadovnikov, V. V. Kozik, V. A. Grinberg, V. V. Emets, G. L. Rusinov, and V. N. Charushin, Synth. Met. 199, 152 (2015).
D. E. Fenton, J. M. Parker, and P. V. Wright, Polymer 14, 589 (1973).
P. V. Wright, Brit. Polym. J. 7, 319 (1975).
M. S. Whittingham, W. Wippner, and H. Schulz, Solid State Ionics 28, 1 (1988).
M. B. Armand, Solid State Ionics 9–10, 745 (1983).
S. Li, M. M. Lin, M. S. Toprak, D. K. Kim, and M. Muhammed, Nano Rev. 1, 5214 (2010).
K. I. Winey and R. A. Vaia, MRS Bull. 32, 314 (2007).
C. P. Collier, R. J. Saykally, J. J. Shiang, S. E. Henrichs, and J. R. Heath, Science 277, 1978 (1997).
W. A. Lopes and H. M. Jaeger, Nature 414, 735 (2001).
T. A. Taton, C. A. Mirkin, and R. L. Letsinger, Science 289, 1757 (2000).
M. Forsyth, D. R. Mac Farlene, A. Best, J. Adebahr, P. Jacobsson, and A. J. Hill, Solid State Ionics 147, 203 (2002).
Y.-Y. Yu, W.-C. Chien, and T.-W. Tsai, Polym. Test. 29, 33 (2010).
J. Xi, X. Qiu, S. Zheng, and X. Tang, Polymer 46, 5702 (2005).
The Primary Battery, Ed. by N. C. Cahoon and G. W. Heise (J. Wiley and Sons, New York, 1976), p. 149.
T. D. Gregory, R. J. Hoffmann, ans R. C. Winterton, J. Electrochem. Soc. 137, 775 (1990).
E. M. Abdelrazeka, H. M. Ragabb, and. M. Abdelaziza, Plast.-Polym. Technol. Sci. 2, 1 (2013).
J. E. Weston and B.C.H. Steele, Solid State Ionics 7, 75 (1982).
J. Cho and M. Liu, Electrochim. Acta 42, 1481 (1997).
X. Cheng, K. W. Putz, C. D. Wood, and L. C. Brinson, Macromol. Rapid Commun. 36, 391 (2015).
T. Lan and J. M. Torkelson, Polymer 55, 1249 (2014).
J. Choi, M. J. A. Hore, N. Clarke, K. I. Winey, and R. J. Composto, Macromolecules 47, 2404 (2014)
H. Althues, J. Henle, and S. Kaskel, Chem. Soc. Rev. 36, 1454 (2007).
R. M. Hodge, G. H. Edward, and G. P. Simon, Polymer 37, 1371 (1996).
S. A. M. Noor, A. Ahmad, I. A. Talib, and M. Y. A. Rehman, Ionics 16, 161 (2010).
D. S. Davis and T. S. Shalliday, Phys. Rev. 1020, 118 (1960).
R. M. Khafagy, J. Alloys Compd. 509, 9849 (2011).
J. Arias-Pardilla, H. J. Salavagione, C. Barbero, E. Morallón, and J. L. Vázquez, Eur. Polym. J. 42, 1521 (2006).
D. K. Pradhan, R. N. P. Choudhary, and B. K. Samantaray, Int. J. Electrochem. Sci. 3, 597 (2008).
P. W. Davis and T. S. Shilliday, Phys. Rev. 118, 1020 (1960).
G. K. M. Thutupalli and S. G. Tomlin, J. Phys. D: Appl. Phys. 9, 1639 (1976).
C. Venkata Subba Rao, M. Ravi, V. Raja, P. Balji Bhargav, A. K. Sharma, and V. V. R. Narasimha Rao, Iran Polym. J. 21, 531 (2012).
M. Abdelaziz and M. M. Ghannam, Phys. B (Amsterdam, Neth.) 405, 958 (2010).
R. Bhaskaran, S. Selvasekarapandian, N. Kuwata, J. Kawamura, and T. Hattori, Mater. Chem. Phys. 98, 5 (2006).
K. Pandey, M. M. Wivedi, I. M. L. Das, and M. A. Singh, J. Electroceram. 25, 99 (2010).
G. Gondivaraj, N. Baskaran, K. Shahi, and P. Monoravi, Solid State Ionics 76, 47 (1995).
P. Balaya and P. S. Goyal, J. Non.-Cryst. Solids 351, 1573 (2005).
S. R. Majid and A. K. Arof, Phys. B (Amsterdam, Neth.) 390, 215 (2007).
A. Molak, E. Ksepko, I. Gruszka, A. Ratuszna, M. Paluch, and Z. Ujma, Solid State Ionics 176, 1439 (2005).
E. El Shafee, Carbohydr. Polym. 31, 93 (1996).
A. R. Polu and R. Kumar, Int. J. Polym. Mater. 62, 76 (2012).
J. Ravi, M. Pavani, Y. Kumar, K. K. Bhvani, A. K. Sharma, and V. V. R. N. Rao, Mater. Chem. Phys. 130, 442 (2011).
S. K. Shahenoor Basha, G. Sunita Sundari, and K. Vijay Kumar, Int. J. Chem. Technol. 9, 165 (2016).
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Shahenoor Basha, S.K., Sunita Sundari, G., Vijay Kumar, K. et al. Optical and dielectric properties of PVP based composite polymer electrolyte films. Polym. Sci. Ser. A 59, 554–565 (2017). https://doi.org/10.1134/S0965545X17040095
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DOI: https://doi.org/10.1134/S0965545X17040095