Abstract
The potentiometric titration of tin chloride SnCl2 is performed in the concentration range of 0.00009–1.1 mol/L with a solution of sodium hydroxide NaOH. According to potentiometric titration data based on modeling equilibria in the SnCl2–H2O–NaOH system, basic equations are generated for the main processes, and instability constants are calculated for the resulting hydroxo complexes and equilibrium constants of low-soluble tin(II) compounds. The data will be of interest for specialists in the field of theory of solutions.
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References
A. Yu. Betin, V. I. Bobrinev, N. N. Evtikhiev, et al., Appl. Opt. 52, 8142 (2013).
V. R. Solanki, R. J. Parmar, R. J. Pathak, and M. D. Parmar, in Proc. of the International Conference on Functional Oxides and Nanomaterials, AIP Conf. Proc. 1837, 040019–1 (2017).
M. S. Mahdi, K. Ibrahim, A. Hmood, et al., RSC Adv. 116, 114980 (2016).
D. Avellaneda, G. Delgado, M. T. S. Nair, and P. K. Nair, Thin Solid Films 515, 5771 (2007).
Z. Zainal, S. Nagalingam, A. Kassim, et al., Solar Energy Mater. Solar Cells 81, 261 (2004).
K. Zweibel, Solar Energy Mater. Solar Cells 63, 375 (2000).
N. Lindgren, M. Larsson, and S. Lindquist, Solar Energy Mater. Solar Cells 73, 377 (2002).
J. B. Johnson, H. Jones, B. S. Latham, et al., Semicond. Sci. Technol. 14, 501 (1999).
T. Jiang, G. A. Ozin, A. Verma, and R. L. Bedard, J. Mater. Chem. 8, 1649 (1998).
M. Batzill and U. Diebold, Prog. Surf. Sci. 79, 47 (2005).
S. A. Pianaro, P. R. Bueno, E. Longo, and J. A. Varela, J. Mater. Sci. Lett. 14, 692 (1995).
V. E. Bochenkov and G. B. Sergeev, Russ. Chem. Rev. 76, 1013 (2007).
A. Ammari, B. Bellal, N. Zebbar, et al., Thin Solid Films 632, 66 (2017).
S. A. Bashkirov, V. F. Gremenok, and V. A. Ivanov, Semiconductors 45, 749 (2011).
K. T. R. Reddy, N. K. Reddy, and R. W. Miles, Solar Energy Mater. Solar Cells 90, 3041 (2006).
M. Sharon and K. Basavaswaran, Solar Cells 25, 97 (1988).
M. Gunasekaran and M. Ichimura, Solar Energy Mater. Solar Cells 91, 774 (2007).
L. S. Parshina, O. D. Khramova, O. A. Novodvorsky, A. A. Lotin, I. A. Petukhov, F. N. Putilin, and K. D. Shcherbachev, Semiconductors 51, 407 (2017).
C. Cifuentes, M. Botero, E. Romero, et al., Brazil. J. Phys. 36 (3B), 1046 (2006).
M. Devika, N. K. Reddy, F. Patolsky, and K. R. Gunasekhar, J. Appl. Phys. 104, 124503 (2008).
S. A. Bashkirov, V. F. Gremenok, V. A. Ivanov, and V. V. Shevtsova, Phys. Solid State 54, 2497 (2012).
B. Stjerna, E. Olsson, and C. G. Granqvist, J. Appl. Phys. 76, 3797 (1994).
J. Park, M. Song, W. M. Jung, et al., Bull. Korean Chem. Soc. 33, 3383 (2012).
P. Sinsermsuksakul, K. Hartman, S. B. Kim, et al., Appl. Phys. Lett. 102, 053901 (2013).
V. S. Popov, V. G. Sevast’yanov, and N. T. Kuznetsov, Kompoz. Nanostrukt., No. 1, 33 (2012).
L. N. Maskaeva, E. A. Fedorova, V. F. Markov, et al., Butler. Soobshch. 37 (2), 1 (2014).
L. N. Maskaeva, S. S. Tulenin, A. A. Timina, and V. F. Markov, Butler. Soobshch. 45 (3), 72 (2016).
S. S. Tulenin, A. A. Timina, L. N. Maskaeva, and V. F. Markov, Russ. J. Appl. Chem. 90, 91 (2017).
L. P. Joshi, L. Risal, and S. P. Shrestha, J. Nepal Phys. Soc. 3, 1 (2015).
S. H. Chaki, M. D. Chaudhary, and M. P. Deshpande, J. Semicond. 37, 053001(2016).
O. D. Nnanyere, J. Nat. Sci. Res. 5, 124 (2015).
M. Safonova, E. Mellikov, V. Mikli, et al., Adv. Mater. Res. 1117, 183 (2015).
T. N. Fetisova, V. R. Mirolyubov, and S. F. Katyshev, Russ. J. Gen. Chem. 77, 1643 (2007).
V. A. Nazarenko, V. P. Antonovich, and E. M. Nevskaya, The Hydrolysis of Metal Ions in Diluted Solutions (Atomizdat, Moscow, 1979) [in Russian].
V. B. Spivakovskii, Analytical Chemistry of Tin (Nauka, Moscow, 1975) [in Russian].
R. M. Cigala, F. Crea, C. de Stefano, et al., Monatsh. Chem. 144, 761 (2013).
O. V. Reva and T. N. Vorob’eva, Russ. J. Appl. Chem. 75, 700 (2002).
F. Séby, M. Potin-Gautier, E. Giffaut, and O. F. X. Donard, Geochim. Cosmochim. Acta 65, 3041 (2001).
Yu. Yu. Lur’e, Handbook of Analytical Chemistry (Khimiya, Moscow, 1989) [in Russian].
R. A. Yusupov and S. A. Bakhteev, Russ. J. Phys Chem. A 83, 2188 (2009).
J. N. Butler, Ionic Equilibrium: A Mathematical Approach (Addison-Wesley, Reading, MA, 1964).
M. Pettine, F. J. Millero, and G. Macchi, Anal. Chem. 53, 1039 (1981).
R. M. Cigala, F. Crea, and C. de Stefano, Geochim. Cosmochim. Acta 87, 1 (2012).
T. Z. Din’, R. A. Yusupov, and S. A. Bakhteev, Vestn. Kazan. Tekhnol. Univ. 15 (15), 49 (2012).
T. Z. Din’, S. A. Bakhteev, and R. A. Yusupov, Vestn. Kazan. Tekhnol. Univ. 16 (17), 47 (2013).
T. Z. Din’, S. A. Bakhteev, and R. A. Yusupov, Vestn. Kazan. Tekhnol. Univ. 16 (4), 92 (2013).
R. A. Yusupov, S. A. Bakhteev, and S. G. Smerdova, Russ. J. Phys. Chem. A 84, 1263 (2010).
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Original Russian Text © L.N. Maskaeva, E.A. Fedorova, R.A. Yusupov, V.F. Markov, 2018, published in Zhurnal Fizicheskoi Khimii, 2018, Vol. 92, No. 5, pp. 831–837.
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Maskaeva, L.N., Fedorova, E.A., Yusupov, R.A. et al. Calculating Equilibrium Constants in the SnCl2–H2O–NaOH System According to Potentiometric Titration Data. Russ. J. Phys. Chem. 92, 1025–1031 (2018). https://doi.org/10.1134/S0036024418050230
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DOI: https://doi.org/10.1134/S0036024418050230