Abstract
Kinetic and thermodynamic parameters of the donor–acceptor self-organization in the system (5,10,15,20-tetraphenyl-21H,23H-porphyrinato)cobalt(II) (CoTPP)–1-methyl-2-(pyridin-4′-yl)-3,4-fullero[60]pyrrolidine (PyC60)–toluene yielding the 1: 2 complex (PyC60)2CoTPP are presented. The chemical structure of the supramolecular triad was elucidated by UV-vis, IR, and (1H, 13C) NMR spectroscopy. The photoelectrochemical characteristics of the Ti|TiO2 electrode modified by the triad and its precursors were determined and the redox behavior of the latter was studied by cyclic voltammetry in dichloromethane.
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Russian Text © The Author(s), 2019, published in Zhurnal Neorganicheskoi Khimii, 2019, Vol. 64, No. 5, pp. 490–499.
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Bichan, N.G., Ovchenkova, E.N., Mozgova, V.A. et al. Formation Reaction, Spectroscopy, and Photoelectrochemistry of the Donor–Acceptor Complex (5,10,15,20-Tetraphenyl-21,23H-porphinato)cobalt(II) with Pyridyl-Substituted Fullero[60]pyrrolidine. Russ. J. Inorg. Chem. 64, 605–614 (2019). https://doi.org/10.1134/S0036023619050024
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DOI: https://doi.org/10.1134/S0036023619050024