Abstract
The reaction products formed in the SO2–L–H2O–O2 systems (L is n-propylamine, n-butylamine, tert-butylamine, n-heptylamine, n-octylamine, aniline) were isolated and identified as “onium” salts [n-C3H7NH3]2SO4, [n-C4H9NH3]2SO4, [t-C4H9NH3]2SO4, [n-C7H15NH3]3SO4(HSO4), [n-C8H17NH3]3SO4(HSO4), and [C6H5NH3]2SO4. The products were characterized by elemental analysis, IR and Raman spectroscopy, mass spectrometry, and thermogravimetry.
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Original Russian Text © R.E. Khoma, V.O. Gel’mbol’dt, A.A. Ennan, V.N. Baumer, I.M. Rakipov, R.M. Dlubovskii, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 5, pp. 625–630.
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Khoma, R.E., Gel’mbol’dt, V.O., Ennan, A.A. et al. Onium Sulfates and Hydrogen Sulfates: Products of Reactions of Sulfur(IV) Oxide with Aqueous Solutions of Alkylamines and Aniline. Russ. J. Inorg. Chem. 63, 655–660 (2018). https://doi.org/10.1134/S0036023618050157
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DOI: https://doi.org/10.1134/S0036023618050157