Abstract
The synthesis, analysis, and IR spectroscopic, thermogravimetric, and X-ray diffraction study of [Cu(Тsc)2](Nds) (I), where Тsc is thiosemicarbazide NH2NHС(=S)NH2, and 1,5-Nds2– is the doubly deprotonated 1,5-naphthalenedisulfoacid anion C10H6(SO3) 2–2 , have been performed. Crystal structure units in complex I are [Cu(Тsc)2]2+ centrosymmetric complex cations and (Nds)2– anions (including those in inversion centers). The copper atom is coordinated to the vertices of a square via the two sulfur and two nitrogen atoms of the two bidentate-chelate (S,N) ligands Тsc. Crystal structure units in complex I are linked together by a branched network of weak nonlinear N–Н···О hydrogen bonds with participation of donors (all the five independent hydrogen atoms of the two NH2 groups and NH group of the [Cu(Tsc)]2+ complex cation) and acceptors (all the three independent oxygen atoms of the sulfato group of the 1,5-Nds2– anion).
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Original Russian Text © V.S. Sergienko, T.V. Koksharova, M.D. Surazhskaya, T.S. Skakun, Yu.N. Mikhailov, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 1, pp. 26–31.
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Sergienko, V.S., Koksharova, T.V., Surazhskaya, M.D. et al. Bis(Thiosemicarbazide)Copper(II) 1,5-Naphthalenedisulfonate Complex [Cu(Тsc)2](1,5-Nds): Synthesis and Crystal and Molecular Structures. Russ. J. Inorg. Chem. 63, 22–27 (2018). https://doi.org/10.1134/S0036023618010138
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DOI: https://doi.org/10.1134/S0036023618010138