Abstract
o-Tosylaminobenzaldehyde dimethylpyrimidyl hydrazone and its copper(II), nickel(II), and zinc(II) complexesare synthesized and studied. According to the X-ray diffraction data, the zinc(II) complex has the structure of a tetragonal pyramid with the N3O donor ligand environment. According to EPR and magnetochemistry data, the copper(II) complex has a similar structure of the chelate core. In the nickel(II) complex, the solvent molecule completes the coordination core to an octahedron.
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Original Russian Text © L.D. Popov, V.V. Tkachev, Yu.P. Tupolova, S.A. Borodkin, G.V. Shilov, E.A. Ugolkova, O.I. Askalepova, A.S. Burlov, V.V. Lukov, I.N. Shcherbakov, S.I. Levchenkov, V.V. Minin, 2017, published in Zhurnal Neorganicheskoi Khimii, 2017, Vol. 62, No. 7, pp. 912–919.
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Popov, L.D., Tkachev, V.V., Tupolova, Y.P. et al. Copper(II), nickel(II), and zinc(II) complexes with o-tozylaminobenzaldehyde 4,6-dimethylpyrimidyl hydrazone. Russ. J. Inorg. Chem. 62, 893–899 (2017). https://doi.org/10.1134/S003602361707018X
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DOI: https://doi.org/10.1134/S003602361707018X