Abstract
The cobalt(II) nitrate complex with α-(3,3-dimethyl-3,4-dihydroisoquinolyl-1)hydroxyiminoacetonitrile [Co(LH)(L)(NO3)] (I) has been synthesized and studied by X-ray diffraction, IR, and electronic spectroscopy. One of the ligands is in the molecular form LH, and the other is the L− anion. The two independent ligands bidentately chelately coordinate the cobalt(II) atom via nitrogen atoms. The coordination polyhedron of the cobalt atom is a distorted octahedron. The NO −3 group is bidentately chelately coordinated. The LH and L ligands are in the same E-s-cis- isomer form. Some data on the IR and electronic spectra of complex I are reported.
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Original Russian Text © V.I. Sokol, V.V. Davydov, V.S. Sergienko, E.I. Polyakova, Yu.V. Shklyaev, 2015, published in Zhurnal Neorganicheskoi Khimii, 2015, Vol. 60, No. 5, pp. 626–632.
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Sokol, V.I., Davydov, V.V., Sergienko, V.S. et al. Synthesis, structure, and physicochemical characteristics of the cobalt(II) nitrate complex with α-(3,3-dimethyl-3,4-dihydroisoquinolyl-1)hydroxyiminoacetonitrile [Co(LH)(L)(NO3)]. Russ. J. Inorg. Chem. 60, 560–565 (2015). https://doi.org/10.1134/S0036023615050174
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DOI: https://doi.org/10.1134/S0036023615050174