Abstract
The competitive hydrogenation of сhloronitrobenzene isomers in the presence of different palladium- containing catalysts was studied. The nature of catalytic activity carriers for the Pd–P nanoparticles containing both Pd(0) clusters and palladium phosphides was determined by the method of phase trajectories. It was found that the hydrogenation of сhloronitrobenzene isomers under mild conditions occurred on the clusters of Pd(0), and the dependence of the differential selectivity of Pd–P clusters in the hydrogenation of o- and m-сhloronitrobenzene on the P/Pd ratio was related to the dispersity of the Pd(0) clusters.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
Ananikov, V.P., Khemchan, L.L., Ivanova, Yu.V., Bukhtiyarov, V.I., Sorokin, A.M., Prosvirin, I.P., Vatsadze, S.Z., Medved’ko, A.V., Nuriev, V.N., Dil’man, A.D., Levin, V.V., Koptyug, I.V., Kovtunov, K.V., Zhivonitko, V.V., Likholobov, V.A., Romanenko, A.V., Simonov, P.A., Nenaidenko, V.G., Shmatova, O.I., Muzalevskii, V.M., Nechaev, M.S., Asachenko, A.F., Morozov, O.S., Dzhevakov, P.B., Osipov, S.N., Vorob’eva, D.V., Topchii, M.A., Zotova, M.A., Ponomarenko, S.A., Borshchev, O.V., Luponosov, Yu.N., Rempel’, A.A., Valeeva, A.A., Stakheev, A.Yu., Turova, O.V., Mashkovskii, I.S., Sysolyatin, S.V., Malykhin, V.V., Bukhtiyarova, G.A., Terent’ev, A.O., and Krylov, I.B., Russ. Chem. Rev., 2014, vol. 83, no. 10, p.885.
Bukhtiyarov, V.I., Russ. Chem. Rev., 2007, vol. 76, no. 6, p.553.
Maki-Arvela, P., Hajek, I., Salmi, T., and Murzin, D.Yu., Appl. Catal., A, 2005, vol. 292, p.1.
Somordjai, G.A. and Li, Y., Top. Catal., 2010, vol. 53, p.832.
Markov, P.U., Tirova, O.V., Mashkovsky, I.S., Khudorozhkov, A.K., Bukhtiyarov, V.I., snd Stakheev, A.Yu., Mendeleev Commun., 2015, vol. 25, p.367.
Belykh, L.B., Skripov, N.I., Sterenchuk, T.P., Akimov, V.V., Tauson, V.L., and Schmidt, F.K., Russ. J. Gen. Chem., 2016, vol. 86, no. 9, p. 2022.
Belykh, L.B., Skripov, N.I., Belonogova, L.N., Umanets, V.A., and Schmidt, F.K., Kinet. Catal., 2010, vol. 51, no. 1, p.42.
Belykh, L.B., Skripov, N.I., Stepanova, T.P., and Shmidt, F.K., Kinet. Catal., 2015, vol. 56, no. 2, p.181.
Skripov, N.I., Belykh, L.B., Sterenchuk, T.P., Akimov, V.V., Tauson, V.L., and Schmidt, F.K., Kinet. Catal., 2017, vol. 58, no. 1, p.34.
Muetterties, E.L. and Sauer, J.C., J. Am. Chem. Soc., 1974, vol. 96. № 11, p. 3410.
Oyama, S.T., Gott, T., Zhao, H., and Lee, Y.-K., Catal. Today, 2009, vol. 143, p.94.
Prins, R. and Bussell, M.E., Catal. Lett., 2012, vol. 142, no. 12, p. 1413.
d’Aquino, A.I., Danforth, S.J., Clinkingbeard, T.R., Ilic, B., Pullan, L., Reynolds, M.A., Murray, B.D., and Bussell, M.E., J. Catal., 2016, vol. 335, p.,204.
Bui, P., Cecilia, J.A., Oyama, S.T., Takagaki, A., Infantes-Molina, A., Zhao, H., Li, D., Rodriguez-Castellyn, E., and Jimenez-Lopez, A., J. Catal., 2012, vol. 294, p.184.
Cecilia, J.A., Jimenez-Moralesa, I., Infantes-Molin, A., and Rodriguez-Castellon, E., J. Mol. Catal. A: Chem., 2013, vols. 368–369, p.78.
Li, D., Senevirathne, K., Aquilina, L., and Brock, S.L., Inorg. Chem., 2015, vol. 54, p. 7968.
Layan Savithra, G.H., Bowker, R.H., Carrillo, B.A., Bussell, M.E., and Brock, S.L., ACS Appl. Mater. Interfaces, 2013, vol. 5, p. 5403.
McEnaney, J.M., Crompton, J.C., Callejas, J.F., Popczun, E.J., Biacchi, A.J., Lewis, N.S., and Schaak, R.E., Chem. Mater., 2014, vol. 26, p. 4826.
Skripov, N.I., Belykh, L.B., Sterenchuk, T.P., and Schmidt, F.K., Russ. J. Appl. Chem., 2015, vol. 88, no. 8, p. 1255.
Chen, Y., Li, C., Zhou, J., Zhang, S., Rao, D., He, S., Wei, M., Evans, D.G., and Duan, X., ACS Catal., 2015, vol. 5, no. 10, p. 5756.
Zhao, M., Chem. - Asian J., 2016, vol. 11, p.461.
Belykh, L.B., Skripov, N.I., Akimov, V.V., Tauson, V.L., Stepanova, T.P., and Schmidt, F.K., Russ. J. Gen. Chem., 2013, vol. 83, no. 12, p. 2260.
Gordon, A.J. and Ford, R.A., The Chemist’s Companion, New York: Wiley, 1972.
Mattews, J.C. and Wood, L.L., US Patent 3474464, 1967.
Schmidt, A.F., Kurokhtina, A.A., and Larina, E.V., Catal. Sci. Technol., 2014, vol. 4, p. 3439.
Cano, R., Schmidt, A.F., and McGlacken, G.P., Chem. Sci., 2015, vol. 6, p. 5338.
Serna, P., Concepciyn, P., and Corma, A., J. Catal., 2009, vol. 265, p.19.
Belykh, L.B., Skripov, N.I., Stepanova, T.P., Akimov, V.V., Tauson, V.L., and Schmidt, F.K., Curr. Nanosci., 2015, vol. 11, no. 2, p.175.
Blaser, H.U., Science, 2006, vol. 313, p.312.
Corma, A., Serna, P., Concepcion, P., and Calvino, J.J., J. Am. Chem. Soc., 2008, vol. 130, p. 8748.
Tsirul’nikov, P.G., Afonasenko, T.N., Koshcheev, S.V., and Boronin, A.I., Kinet. Catal., 2007, vol. 48, no. 5, p.728.
Wu, T., Kaden, W.E., Kunkel, W.A., and Anderson, S.L., Surf. Sci., 2009, vol. 603, p. 2764.
Carenco, S., Leyva-Perez, A., Concepciyn, P., Boissiere, C., Mezailles, N., Sanchez, C., and Corma, A., Nano Today, 2012, vol. 7, p.21.
Stojewski, M., Kowalska, J., and Jurczakowski, R., J. Phys. Chem. C., 2009, vol. 113, p. 3707.
Nikolaev, S.A., Zanaveskin, L.N., Smirnov, V.V., Aver’yanov, V.A., and Zanaveskin, K.L., Usp. Khim., 2009, vol. 78, no. 3, p. 1.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © L.B. Belykh, T.P. Sterenchuk, N.I. Skripov, S.B. Sanzhieva, F.K. Shmidt, 2018, published in Kinetika i Kataliz, 2018, Vol. 59, No. 3, pp. 286–293.
Rights and permissions
About this article
Cite this article
Belykh, L.B., Sterenchuk, T.P., Skripov, N.I. et al. Differential Selectivity of Palladium–Phosphorus Catalysts in the Competitive Hydrogenation of Isomeric Chloronitrobenzenes. Kinet Catal 59, 267–274 (2018). https://doi.org/10.1134/S0023158418030035
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0023158418030035