Abstract
A new oxovanadium(V) complex [VO(BH)(EM)], where BH = N′-(2-hydroxybenzylidene)-4-trifluoromethylbenzohydrazide, EM = ethyl maltol, is synthesized and fully characterized based on the elemental analysis, FT-IR, UV-Vis, and 1H NMR spectra. The complex is also characterized by single crystal X-ray diffraction, which indicates that the V atom adopts the octahedral coordination. The hydrazone ligand behaves as a tridentate ligand, and the ethyl maltol ligand behaves as a bidentate ligand. The catalytic epoxidation property of the complex is investigated.
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Funding
This work was supported by the Collaborative Innovation Plan of Hubei Province for Key Technology of Eco-Ramie Industry.
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The authors declare that they have no conflict of interests.
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CCDC number 1824512 contains the supplementary crystallographic data for the complex. These data can be obtained free of charge via http://www.ccdc.cam.ac.uk/conts/retrieving.html, or from the Cambridge Crystallographic Data Center, 12, Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336 033; or e-mail: deposit@ccdc.cam.ac.uk.
Russian Text © The Author(s), 2019, published in Zhurnal Strukturnoi Khimii, 2019, Vol. 60, No. 8, pp. 1351–1357.
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Cui, Y.M., Wang, Y.Q., Su, X.X. et al. Synthesis, X-Ray Crystal Structure, and Catalytic Epoxidation Property of an Oxovanadium(V) Complex with Hydrazone and Ethyl Maltol Ligands. J Struct Chem 60, 1299–1305 (2019). https://doi.org/10.1134/S0022476619080092
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DOI: https://doi.org/10.1134/S0022476619080092