Abstract
Analytical expressions for the dynamic specific conductance coefficient σ(ω) and the dynamic electroelasticity modulus ∊(ω) are obtained by solving kinetic equations using specific expressions for the potential energy Φab(r) of the interaction between structural units of the solution and the equilibrium radial distribution function gab(r). Friction coefficients βa and βb are calculated numerically; relaxation times τa, τb, τab along with ∊(ω) and σ(ω) values are determined for aqueous solutions of LiCl, NaCl, KCl, and CsCl as functions of the concentration c, density ρ, and temperature T in a wide frequency range ω. The obtained theoretical data are presented in the form of tables and graphs and are compared with experimental results show a satisfactory agreement between them.
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Odinaev, S., Akdodov, D.M. & Idibegzoda, K.I. Frequency Dispersion of the Specific Conductance Coefficient in Aqueous Electrolyte Solutions. J Struct Chem 60, 434–442 (2019). https://doi.org/10.1134/S0022476619030119
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DOI: https://doi.org/10.1134/S0022476619030119