Abstract
Three new metal-organic frameworks [Zn(Hibdc)2]·DMF (1), (H2NMe2)[Li2Zn3(H2O)(dmf)(Hbtc)3(btc)]·6DMF·H2O (2), and [Li2Zn2(H2O)2(bpp)(bpdc)3]·7DMF (3) are obtained in the interaction of heterometallic carboxylate complex [Li2Zn2(piv)6(py)2] with isophthalic (H2ibdc) and trimesic (H3btc) acids and in the presence of both 4,4′-biphenyldicarboxylic acid (H2bpdc) and 4,4′-bispyridylpropane (bpp). The structure of the obtained compounds is determined by the single crystal X-ray diffraction analysis. In the reactions studied the structure of the initial {Li2Zn2} fragment is not retained. A complicated fragmentation of this four-nuclear block occurs, including the formation of binuclear heterometallic dimers {LiZn}.
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Original Russian Text © 2018 A. A. Sapianik, E. E. Semenenko, D. G. Samsonenko, D. N. Dybtsev, V. P. Fedin.
Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 2, pp. 499–504, March–April, 2018.
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Sapianik, A.A., Semenenko, E.E., Samsonenko, D.G. et al. Crystal Structure of Coordination Polymers Based on A Heterometallic Carboxylate Complex. J Struct Chem 59, 487–493 (2018). https://doi.org/10.1134/S0022476618020336
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DOI: https://doi.org/10.1134/S0022476618020336