Abstract
New supramolecular synthon induced complex [Zn(Hor)(Hiso)·3H2O]·H2O (1) is obtained in a selfassembly reaction of zinc nitrate with orotic (H3Or, 1,2,3,6-tetrahydro-2,6-dioxo-4-pyrimidinecarboxylic) acid and isonicotinamide. The isonicotinamide molecule is hydrolyzed in-situ into isonicotinic (Hiso, pyridine-4-carboxylic) acid. A detailed structural analysis and the role of hydrogen bonding synthons in deciding the overall structural diversity is discussed. The {…H–N–C=O…}2 and {…H–O–C=O…}2 dimers play an important role in the metal-organic architecture of 1. Complex 1 is insoluble in almost all organic solvents as well as in water. The complete decomposition of the compound is achieved above 445°C.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
G. R. Desiraju, Crystal Engineering: The Design of Organic Solid, Amsterdam: Elsevier (1989)
G. R. Desiraju, J. J. Vittal, and A. Ramanan, Crystal Engineering: A Text Book, IISc Press and World Scientific, Bangalore (2011).
G. R. Desiraju, J. Am. Chem. Soc., 135, 9952 (2013)
G. R. Desiraju, Angew. Chem., Int. Ed. Engl., 34, 2311 (1995).
L. J. Prins, D. N. Reinhoudt, and P. Timmerman, Angew. Chem., Int. Ed., 40, 2382 (2011)
G. R. Desiraju, in: Stimulating Concepts in Chemistry, F. Vögtle, J. F. Stoddart, and M. Shibasaki (eds.), Wiley-VCH, Weinheim (2000), p. 293.
E. Constable, Chem. Soc. Rev., 36, 246 (2007).
K. A. Siddiqui, J. Coord. Chem., 66, 2039 (2013)
K. A. Siddiqui, G. K. Mehrotra, S. S. Narvi, and R. J. Butcher, Inorg. Chem. Commun., 14, 814 (2011).
K. A. Siddiqui, G. K. Mehrotra, and R. L. LaDuca, Polyhedron, 28, 4077 (2009)
K. A. Siddiqui, J. Coord. Chem., 65, 4168 (2012).
Q.-Y. Huang, Y. Yang, and X.-R. Meng, Acta Crystallogr., C71, 701 (2015)
L. Tei, A. J. Devillonova, F. A. A. Garav, and V. Lippolis, Chem. Commun., 2582 (2001)
T. Shiga, T. Nakanishi, M. Obba, and H. Okawa, Polyhedron, 24, 2732 (2005)
K. A. Siddiqui, G. K. Mehrotra, J. Mrozinski, and R. J. Butcher, J. Mol. Struct., 964, 18 (2010).
D. D. Genchev, Dokl. Bolg. Akad. Nauk, 23, 435 (1970)
J. D. Rawn, Biochemistry, Neil Patterson Publishers, Burlington, North Carolina (1989)
N. Lalioti, C. P. Raptopoulou, A. Terzis, A. Panagiotopoulos, S. P. Perlepes, and E. Manessi-Zoupa, J. Chem. Soc. Dalton Trans., 1327 (1998).
M. Sabat, D. Zglinska, and B. Jezowska-Trzebiatowska, Acta Crystallogr., B36, 1187 (1980)
A. Karipides and B. Thomas, Acta Crystallogr., C42, 1705 (1986)
P. Castan, E. Colacio-Rodriguez, A. L. Beauchamp, S. Cros, and S. Wimmer, J. Inorg. Biochem., 38, 225 (1990)
O. Kumberger, J. Riede, and H. Schmidbaur, Z. Naturforsch., Teil B, 48, 961 (1993).
I. Mutikainen, Inorg. Chim. Acta, 136, 155 (1987)
I. Mutikainen, R. Hamalatainen, M. Klinga, O. Orama, and U. Turpeinen, Acta Crystallogr., C52, 2480 (1996)
G. Maistralis, A. Koutsodimou, and N. Katsaros, Transition Met. Chem., 25, 166 (2000)
R. Wysokinski, B. Morzyk-Ocipea, T. Glowiak, and D. Michalska, J. Mol. Struct., 606, 241 (2002)
H. Icbudak, H. Olmez, O. Z. Yesilel, F. Arslan, P. Naumov, G. Jovanovski, A. R. Ibrahim, A. Usman, H.-K. Fun, S. Chantrapromma, and S. W. Ng, J. Mol. Struct., 657, 255 (2003).
G. M. Sheldrick, SADABS, Program for Empirical Adsorption Correction of Area Detector Data, University of Gottingen, Germany (1997).
G. M. Sheldrick, Acta Crystallogr. Sect. A, 46, 467 (1990).
G. M. Sheldrick, SHELXL-97, Programme for the Refinement of Crystal Structure, University of Gottingen, Germany (1997).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © 2018 K. A. Siddiqui, P. Lama.
The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 59, No. 1, pp. 170–175, January–February, 2018.
Rights and permissions
About this article
Cite this article
Siddiqui, K.A., Lama, P. First Orotic Acid and Isonicotinic Acid Based Zn Complex: Hydrothermal Synthesis, Crystal Structure, and Thermogravimetric Analysis. J Struct Chem 59, 166–171 (2018). https://doi.org/10.1134/S0022476618010250
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476618010250