Abstract
Methods of analysis of reusable metal-containing material (RMR) are considered in the review: X-ray fluorescence, atomic absorption spectrophotometry, and atomic emission and mass spectrometry with inductively coupled plasma. Peculiarities of the applied methods are shown, and a method of analysis with consideration of the specificity of RMR should be developed for every object. In the most cases, the methods of sample processing harmonized with the applied method of analysis and sample content.
Article PDF
Similar content being viewed by others
Avoid common mistakes on your manuscript.
References
Karpov, Yu.A., Savostin, A.P., and Sal’nikov, V.D., Analiticheskii kontrol’ v metallurgicheskom proizvodstve: uchebnoe posobie (Analytical Control in Metallurgical Industry: Manual), Moscow: Akademkniga, 2006.
Losev, N.F. and Smagunova, A.N., Osnovy rentgenospektral’nogo fluorestsentnogo analiza (Principles of X-Ray Fluorescence Analysis), Moscow: Khimiya, 1982.
Aisueva, T.S., Analysis of Pd, Pt, Re in catalysts by xray fluorescence, VII Vserossiiskoi konferentsiya po rentgenospektral’nomu analizu, Tezisy dokladov (VII All-Russ. Conf. on X-Ray Fluorescence Analysis, Abstracts of Papers), Novosibirsk, 2011, p.82.
Shabanova, L.N., Obrazovskii, E.G., Akulova, G.I., and Sryvtseva, T.B., Sampling and determination of precious metals in industrial products and wastes, VII Konferentsiya “Analitika Sibiri i Dal’nego Vostoka–2004,” Tezisy dokladov (VII Conf. “Analytics of Siberia and the Far East–2004,” Abstracts of Papers), Novosibirsk, 2004, p.96.
Shestakov, V.A., Arkhipov, N.A., Makarov, D.F., and Kukushkin, Yu.N., The X-ray analysis of the slurry and platinum concentrates for precious metals, Zh. Analit. Khim., 1974, vol. 29, no. 12, pp. 2176–2180.
Antonova, Yu.V. and Karpov, Yu.A., The use of x-ray fluorescence analysis for the certification of secondary raw materials containing precious metals, VII Vserossiiskoi konferentsiya po rentgenospektral’nomu analizu, Tezisy dokladov (VII All-Russ. Conf. on X-Ray Fluorescence Analysis, Abstracts of Papers), Novosibirsk, 2011, p.83.
Metodika rentgenospektral’nogo opredeleniya zolota i serebra vo vtorichnom syr’e dragotsennykh (blagorodnykh) metallov (Methods of X-Ray Analysis of Gold and Silver in the Secondary Raw Materials of Precious (Noble) Metals), Moscow: Giredmet, 2005.
Obrazovskii, E.G., Akulova, G.I., and Sryvtseva, T.B., An integrated approach to the analysis of catalysts containing precious metals and their products, VII Konferentsiya “Analitika Sibiri i Dal’nego Vostoka–2004,” Tezisy dokladov (VII Conf. “Analytics of Siberia and the Far East–2004,” Abstracts of Papers), Novosibirsk, 2004, p.97.
Shestakov, V.A., Malofeeva, G.I., Petrukhin, O.M., et al., Sorption-XRF analysis of heavy metals using polymer thioester, Zh. Anal. Khim., 1983, vol. 38, no. 12, pp. 2131–2136.
Oskolok, K.V. and Monogarova, O.V., Optimal analytical abilities of hybrid sorption-XRF methods for analysis of heavy metals in the water, VII Vseross. konferentsiya po rentgenospektral’nomu analizu, Tezisy dokladov (VII All-Russian Conf. on X-Ray Analysis, Abstracts of Papers), Novosibirsk, 2011, p.171.
Ganeev, A.A., Atomno-absorbtsionnyi analiz: uchebnoe posobie (Atomic Absorption Analysis: Manual), Moscow: Lan’, 2011.
Pupyshev, A.A., Atomno-absorbtsionnyi spektral’nyi analiz (Atomic Absorption Spectral Analysis), Moscow: Tekhnosfera, 2009.
Britske, M.E., Atomno-absorbtsionnyi spektrokhimicheskii analiz (Atomic Absorption Spectrochemical Analysis), Moscow: Khimiya, 1982.
Nikolaev, G.N. and Nemets, A.M., Atomno-absorbtsionnaya spektroskopiya v issledovanii ispareniya metallov (Atomic Absorption Spectroscopy in the Study of Metal Evaporation), Moscow: Metallurgiya, 1982.
Zolotov, Yu.A., Osnovy analiticheskoi khimii. Prakticheskoe rukovodstvo (Fundamentals of Analytical Chemistry: A Practical Guide), Moscow: Vysshaya Shkola, 1999.
Analiticheskaya khimiya metallov platinovoi gruppy (Analytical Chemistry of Platinum Group Metals), Zolotov, Yu.A., Varshal, G.M., and Ivanov, V.M., Eds., Moscow: KomKniga, 2005, 2nd ed.
Dal’nova, O.A., Atomic absorption spectroscopy of secondary and technogenic raw materials for platinum metals, Extended Abstract of Cand. Sci. (Tech.) Dissertation, Moscow, 2009.
Dal’nova, O.A., Shiryaeva, O.A., Karpov, Yu.A., Alekseeva, T.Yu., Shiryaev, A.A., Kulikauskas, V.S., and Filatova, D.G., Direct atomic-absorption determination of platinum, palladium, and rhodium in dead ceramic-based autocatalysts, Inorg. Mater., 2010, vol. 46, no. 15, pp. 1599–1604.
Metodika atomno-absorbtsionnogo opredeleniya serebra, zolota, palladiya i platiny vo vtorichnom syr’e dragotsennykh (blagorodnykh) metallov (Atomic Absorption Analysis of Ag, Au, Pd, and Pt in the Secondary Raw Materials of Precious (Noble) Metals), Moscow: Giredmet, 2005, no. 1-05.
Puig, A.I. and Alvarado, J.I., Evaluation of four sample treatments for determination of platinum in automotive catalytic converters by graphite furnace atomic absorption spectrometry, Spectrochim. Acta, Part B, 2006, vol. 61, pp. 1050–1053.
Dal’nova, O.A., Shiryaeva, O.A., Karpov, Yu.A., Alekseeva, T.Yu., Shiryaev, A.A., and Filatova, D.G., Sorption-atomic-absorption determination of platinum, palladium, and rhodium in dead autocatalysts, Inorg. Mater., 2010, vol. 46, no. 15, pp. 1613–1617.
Metodika sorbtsionno-atomno-absorbtsionnogo opredeleniya palladiya, platiny, rodiya, iridiya i zolota vo vtorichnom syr’e dragotsennykh (blagorodnykh) metallov (Sorption Atomic Absorption Analysis of Pd, Pt, Rh, Ir and Au in the Secondary Raw Materials of Precious (Noble) Metals), Moscow: Giredmet, 2005.
Kulikova L.D., Shiryaeva O.A, and Karpov, Yu.A. Atomic absorption analysis of platinum, palladium, and rhodium in automotive catalysts, Latv. Kim. Zh., 2003, no. 2, pp. 154–158.
Stafilov, T., Determination of trace elements in minerals by electrothermal atomic absorption spectrometry, Spectrochim. Acta, Part B, 2000, vol. 55, no. 7, pp. 893–906.
Aktuganova, K.V., Sources of errors in the electrothermal atomic absorption analysis of platinum metals in the secondary and technogenic materials, Extended Abstract of Cand. Sci. (Tech.) Dissertation, Moscow: Moscow State Inst. Steel Alloys, 2006.
Dal’nova, O.A., Dmitrieva, A.V., Ivannikova, N.V., Shiryaeva, O.A., and Karpov, Yu.A., Determination of toxic elements (Hg, As, Se) by atomic absorption spectrometry with electrothermal atomization, S”ezd analitikov Rossii i Shkola molodykh uchenykh “Analiticheskaya khimiya—novye metody i vozmozhnosti,” Tezisy dokladov (Congr. of Analysts of Russia and School of Young Scientists “Analytical Chemistry: New Methods and Opportunities,” Abstracts of Papers), Moscow, 2010, p.94.
Nazarenko, I.I., Kislova, I.V., Kashina, L.I., et al., Atomic absorption analysis of mercury in the waters after sorption concentration on polymer thioester, Zh. Anal. Khim., 1986, vol. 29, no. 8, pp. 1385–1389.
Castillo, J.R., Lopez-Molinero, A., and Sucunza, T., Determination of As, Sb, and Bi in high-purity copper by electrothermal atomic absorption spectrometry, Microchim. Acta, 1986, vol. 35, no. 4, pp. 330–332.
Savel’eva, A.N. and Agapova, T.E., Determination of arsenic in the copper sulfate electrolyte and electrolytic copper by electrothermal atomic absorption spectrometry, Zavod. Lab., 1990, vol. 56, no. 4, pp. 40–42.
Mullen, J.D., Determination of arsenic in high-purity copper by flameless atomic-absorption spectrophotometry, Talanta, 1977, vol. 24, no. 10, pp. 657–658.
Malyutina, T.M., Alekseeva, T.Yu., D’yachkova, A.V., Kudryavtseva, G.S., Berliner, L.D., and Karpov, Yu.A., Determination of platinum and palladium in dead catalysts using inductively coupled plasma atomic emission spectrometry after sample digestion by high-temperature fusion, Inorg. Mater., 2010, vol. 46, no. 14, pp. 1479–1482.
Dyachkova, A.V., Malutina, T.M., Alekseeva, T.Yu., and Karpov, Yu.A., Chemical preparation of samples of dead automobile catalyzers for subsequent determination of platinum, palladium, and rhodium using atomic emission spectrometry with inductively coupled plasma, Inorg. Mater., 2012, vol. 48, no. 14, pp. 1272–1278.
Baranovskaya, V.B., Mar’ina, G.E., Orlov, V.V., and Karpov, Yu.A., Features of the analytical control of spent automotive catalysts containing precious metals, Mater. III mezhdunarodnoi nauchno-prakticheskoi konferentsii “Materialy v avtomobilestroenii (Proc. III Int. Sci.-Pract. Conf. “The Materials in the Automotive Industry”), Tolyatti, 2008, part 1, p.39.
Metodika atomno-emissionnogo s induktivno svyazannoi plazmoi opredeleniya platiny v otrabotannykh platinosoderzhashchikh katalizatorakh i produktakh ikh pererabotki (Inductively Coupled Plasma Atomic Emission Spectrometry of Platinum in the Platinum-Containing Catalyst Wastes and By-Products), Moscow: Giredmet, 2011.
OST (State Standard) 153-39.2-032-2003: Spent Monometallic and Polymetallic Al–Pt Catalysts and Catalyst Production Wastes, Moscow: Minist. Energetiki Ross. Fed., 2003.
TU 64-5-103–89. Katalizator palladievyi otrabotannyi (Palladium Catalyst Waste), Moscow: Minist. Med. Prom. SSSR, 1989.
Otrabotannye avtomobil’nye katalizatory. Opredelenie platiny, palladiya i rodiya atomno-emissionnym metodom s induktivno svyazannoi plazmoi s ispol’zovaniem analiticheskikh avtoklavov (Exhausted Automotive Catalysts. Determination of Pd, Pt and Rh by Inductively Coupled Plasma Atomic Emission Spectrometry Using of Autoclaves), Moscow: Giredmet, 2010.
Metodika atomno-emissionnogo s induktivno svyazannoi plazmoi opredeleniya zolota, palladiya, platiny i rodiya vo vtorichnom syr’e dragotsennykh (blagorodnykh) metallov (Inductively Coupled Plasma Atomic Emission Spectrometry of Au, Pd, Pt, and Rh in the Secondary Raw Materials of Precious (Noble) Metals), Moscow: Giredmet, 2011.
Metodika atomno-emissionnogo s induktivno svyazannoi plazmoi opredeleniya serebra vo vtorichnom syr’e dragotsennykh (blagorodnykh) metallov (Inductively Coupled Plasma Atomic Emission Spectrometry of Ag in the Secondary Raw Materials of Precious (Noble) Metals), Moscow: Giredmet, 2011.
Dal’nova, O.A., Zhernokleeva, K.V., Petrov, A.M., Baranovskaya, V.B., and Karpov, Yu.A., Sorptionatom-emission determination of platinum, palladium, rhodium, iridium and ruthenium in secondary and man-made raw materials, Mater. II mezhdunarodnogo simpoziuma po sorbtsii i ekstraktsii ISSE-2009 (Proc. II Int. Symp. on Sorption and Extraction ISSE-2009), Vladivostok, 2009, p.142.
Kubrakova, I.V., Myasoedova, G.V., Shumskaya, T.V., Kudinova, T.F., Zakharchenko, E.A., and Mokhodoeva, O.B., Determination of trace noble metals in natural samples using hyphenated methods, J. Anal. Chem., 2005, vol. 60, no. 5, pp. 475–479.
Metodika atomno-emissionnogo s induktivno svyazannoi plazmoi opredeleniya palladiya, platiny i rodiya v shlamakh proizvodstva azotnoi kisloty (Inductively Coupled Plasma Atomic Emission Spectrometry of Pd, Pt and Rh in the Production of Nitric Acid Sludge), Moscow: Giredmet, 2006, no. 11-06.
Filichkina, V.A., Alekseeva, T.Yu., Chemleva, T.A., Karpov, Yu.A., and Miskar’yants, V.G., Elaboration of the technique of atomic emission detection with inductively coupled plasma of platinum metals in chamotte waste with autoclave sample preparation and design of the experiments, Inorg. Mater., 2012, vol. 48, no. 14, pp. 1261–1265.
Metodika atomno-emissionnogo s induktivno-svyazannoi plazmoi opredeleniya palladiya v otrabotannykh palladiisoderzhashchikh katalizatorakh i produktakh ikh pererabotki (Inductively Coupled Plasma Atomic Emission Spectrometry of Palladium in the Palladium-Containing Catalyst Waste and By-Products), Moscow: Giredmet, 2011.
Golubova, E.A. and Loseva, M.P., Use of a plasma atomic emission spectrometer SPECTRO CIROS for the analysis of materials containing platinum metals, Anal. Kontrol, 2003, vol. 7, no. 2, pp. 182–183.
Doidge, P.S., Determination of Trace Impurities in High-Purity Copper by Sequential ICP-OES with Axial Viewing, Santa Clara, CA: Agilent Technol., 2010.
Pohl, P. and Zyrnicki, W., Study of chemical and spectral interferences in the simultaneous determination of As, Bi, Sb, Se and Sn by hydride generation inductively coupled plasma atomic emission spectrometry, Anal. Chim. Acta, 2002, vol. 468, pp. 71–79.
Savkina, V.N., Dolganyuk, I.M., Peikhvasser, N.N., et al., Use of atomic-emission analysis with inductively coupled plasma to control the impurity elements in the products of OEMK metallurgical production, Anal. Kontrol, 2004, vol. 8, no. 1, pp. 51–55.
Glinskaya, I.V., Gorbunov, V.B., Podgorodetskiy, G.S., and Teselkina, A.E., Monitoring the processing of red mud, Steel Transl., 2013, vol. 43, no. 9, pp. 552–556.
Khil’ko, A.A., Simonyan, L.M., Glinskaya, I.V., and Teselkina, A.E., Determining the composition of electrosmelting dust, Steel Transl., 2014, vol. 44, no. 1, pp. 1–5.
Chan, G.C.-Y. and Hieftje, G.M., Investigation of plasma-related matrix effects in inductively coupled plasma-atomic emission spectrometry caused by matrices with low second ionization potentials identification of the secondary factor, Spectrochim. Acta, Part B, 2006, vol. 61, pp. 642–659.
Price, W.J., Analytical Atomic Absorption Spectrometry, London: Heyden, 1972.
Thomas, R., Practical Guide to ICP-MS (Practical Spectroscopy), New York: Marcel Dekker, 2004.
Rusanov, A.K., Osnovy kolichestvennogo spektral’nogo analiza rud i mineralov (Fundamentals of Quantitative Spectral Analysis of Ores and Minerals), Moscow: Nedra, 1978.
Duan, T., Kang, J., Chen, H., and Zeng, X., Determination of ultra-trace concentrations of elements in high purity tellurium by inductively coupled plasma mass spectrometry after Fe(OH)3 coprecipitation, Spectrochim. Acta, Part B, 2003, vol. 58, p. 1679.
Baranovskaya, V.B., Shiryaeva, O.A., Filatova, D.G., Dal’nova, O.A., and Karandashev, V.K., Analysis of possible use of sorbents for the determination of platinum metals by inductively coupled plasma-mass spectrometry, Mater. XVIII Mendeleevskogo s”ezda po obshchei i prikladnoi khimii (Proc. XVIII Mendeleev Congr. on the General and Applied Chemistry), Moscow, 2007, p. 19.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © M.S. Doronina, Yu.A. Karpov, V.B. Baranovskaya, 2016, published in Zavodskaya Laboratoriya, Diagnostika Materialov, 2016, Vol. 82, No. 4, pp. 5–12.
Rights and permissions
About this article
Cite this article
Doronina, M.S., Karpov, Y.A. & Baranovskaya, V.B. Combined Methods of Analysis of Metal-Containing Raw Material (Review). Inorg Mater 53, 1411–1417 (2017). https://doi.org/10.1134/S0020168517140047
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168517140047