Abstract
Photochromic and luminescent properties of a novel spiropyran modified by attachment of the nitroazomethine moiety in the 5′-position have been studied by laser photolysis and spectral and luminescent methods. Intermediate products have been detected and their decay rate constants have been determined during laser photolysis in toluene and a poly(methyl methacrylate) film. In alcohol solutions reverse photochromism is observed: coloration of the solution in the dark and its discoloration under exposure to light. The reasons for the appearance of reverse photochromism and the peculiarities of luminescence in alcohol solutions are discussed in comparison with the model nitrospiropyran.
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Original Russian Text © I.R. Mardaleishvili, L.S. Kol’tsova, N.L. Zaichenko, A.I. Shienok, P.P. Levin, A.S. Tatikolov, 2015, published in Khimiya Vysokikh Energii, 2015, Vol. 49, No. 1, pp. 32–37.
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Mardaleishvili, I.R., Kol’tsova, L.S., Zaichenko, N.L. et al. Peculiarities of photochromism and luminescence of dinitrosubstituted hydroxyazomethinespiropyran. High Energy Chem 49, 30–35 (2015). https://doi.org/10.1134/S0018143915010087
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DOI: https://doi.org/10.1134/S0018143915010087