Abstract
The contents of dissolved rhodium species in the near-neutral environments have been studied for the first time and data on the interaction of Rh with organic matters of natural waters and its sorption behavior during contact with the components of geochemical barriers were obtained. The solubility method was used to analyze the behavior of rhodium hydroxide in the Rh(OH) x –H2O and Rh(OH) x –H2O–FA (fulvic acids) systems. The possible contents of inorganic species of rhodium and its compounds with humic organic ligands were determined within the pH range typical of surface waters. The solubility of rhodium shows a twoorder- of magnitude increase in the presence of humic matters (FA). The sorption interaction of the soluble rhodium species with the main components of geochemical barriers such as iron oxyhydroxides (III), (including fulvic-acid modified ones), alumosilicates, and precipitates of humic acids in contact with natural waters was studied. It was revealed that rhodium has the high affinity to all studied materials; its species are sorbed by ferrihydrite within several hours. It is suggested that rhodium is mainly transferred as colloid with suspended particulate matters of waters and then is accumulated in bottom sediments. The differences revealed in the sorption behavior of Pt(IV), Pd(II) and Rh(III) may be used to predict the distribution of the considered platinum group elements between the components of ecosystems.
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References
S. Baken, C. Sjöstedt, J. P. Gustafsson, P. Seuntjens, N. Desmet, J. De Schutter, and E. Smolders, “Characterization of hydrous ferric oxides derived from ironrich groundwaters and their contribution to the suspended sediment of streams,” Appl. Geochem. 39, 59–68 (2013).
T. M. Buslaeva, and S. A. Simanova, “State of platinum metals in solutions,” in Analytical Chemistry of Platinum Group Metals, Ed. by Yu. A. Zolotov (Editorial URSS, Moscow, 2003), pp. 23–26 (2003).
A. Cobelo-Garcia, A. Turner, and G. E. Millward, “Fractionation and reactivity of platinum group elements during estuarine mixing,” Environ. Sci. Technol. 42 (4), 1096–1101 (2008).
V. M. Dudarchik, “Binding humic acids by clay minerals,” in Humic Matters in the Biosphere (Nauka, Moscow, 1993), pp. 139–143 [in Russian].
K. H. Ek, G. M. Morrison, and S. Rauch, “Environmental routes for platinum group elements to biological materials-a review,” Sci. Total Environ. 334–335, 21–38 (2004).
O. L. Gaskova, “Semiempirical model for the description of sorption equilibria on clay mineral surfaces,” Geochem. Int. 47 (6), 611–622 (2009).
J. L. Jambor and J. E. Dutrizac, “Occurrence and constitution of natural and synthetic ferihydrite. A widespread iron oxyhydroxide,” Chem. Rev. 98, 2549–2585 (1998).
I. Ya. Koshcheeva, O. A. Tyutyunnik, D. N. Chkhetiya, L. V. Krigman, and I. V. Kubrakova, “Role of natural organic matters in transfer of platinum and palladium by organomineral colloids,” Vestn. Otd. Nauk Zemle RAN, No. 4 (2012). NZ 9001: doi 10.2205/2012NZ_ASEMPG.10.2205/2012NZ_ASEMPG
I. V. Kubrakova, A. V. Fortygin, S. G. Lobov, I. Ya. Koshcheeva, O. A. Tyutyunnik, and M. V. Mironenko, “Migration of platinum, palladium, and gold in the water systems of platinum deposits,” Geochem. Int. 49 (11), 1072–1084 (2011).
I. V. Kubrakova, I. Ya. Koshcheeva, O. A. Tyutyunnik, and A. M. Asavin, “Role of organic matter in the accumulation of platinum in oceanic ferromanganese deposits,” Geochem. Int. 48 (7), 655–663 (2010).
I. V. Kubrakova, A. V. Nikulin, I. Ya. Koshcheeva, and O. A. Tyutyunnik, “Platinum metals in environment: content, determination, and behavior in natural systems,” Khim. Interesakh Ustoich. Razvitiya 20 (6), 645–656 (2012).
I. V. Kubrakova, G. M. Varshal, Yu. V. Pogrebnyak, and T. F. Kudinova, “Species of platinum and palladium migration in natural waters,” in Chemical Analysis of Marine Sediments, Ed. by E. A. Ostroumov (Nauka, Moscow, 1988), pp. 103–119.
M. Moldovan, “Origin and fate of platinum group elements in the environment,” Anal. Bioanal. Chem. 388 (3), 537–540 (2007).
F. M. M. Morel, A. J. Milligan, and M. A. Saito, Treatise on Geochemistry, Ed. by H.D. Holland and K. K. Turekian (Elsevier, 2003), Vol. 6, pp. 113–114.
S. I. Pechenyuk, Sorption–Hydrolytic Precipitation of Platinum Metals on the Surface of Inorganic Sorbents (Nauka, Leningrad, 1991) [in Russian].
A. I. Perelman, Geochemistry (Vysshaya Shkola, Moscow, 1989) [in Russian].
D. C. Sassani and E. L. Shock, “Solubility and transport of platinum-group elements in supercritical fluids: summary and estimates of thermodynamic properties of ruthenium, rhodium, palladium and platinum solids aqueous ions, and complexes to 1000°C and 5 kbar,” Geochim. Cosmochim. Acta 62 (15), 2643–2671 (1998).
A. Turner, “Particle-water interactions of platinum group elements estuarine condition,” Mar. Chem. 103, 103–111 (2007).
J. M. Van Middlesworth and S. A. Wood, “The stability of palladium(II) hydroxide and hydroxyl-chloride complexes: an experimental solubility study at 25–85°C and 1 bar,” Geochim. Cosmochim. Acta 63, 1751–1765 (1999).
G. M. Varshal, I. Ya. Koshcheeva, T. K. Velyukhanova, D. N. Chkhetiya, O. A. Tyutyunnik, and Zh.M. Grinevskaya, “Sorption of heavy metals and isotope carriers of long-lived radionuclides on humic acids: I. Sorption of cesium(I), strontium(II), cerium(III), and Ruthenium(IV),” Geochem. Int. 34 (11), 1107–1112 (1996).
G. M. Varshal, T. K. Velyukhanova, and I. S. Sirotkina, “Fractionation, quantitative determination, and study of some main components of dissolved organic matters of natural waters,” Gidrokhim. Mater. 59, 143–151 (1973).
J. D. Whiteley and F. Murrey, “Anthropogenic platinum group elements (Pt, Pd, Rh) concentration in road dust and road side soils from Perth, Western Australia,” Sci. Total Environ. 317, 121–135 (2003).
S. A. Wood, “The interaction of dissolved Pt with fulvic acid and simple organic acids analogues in aqueous solution,” Can. Mineral. 28, 665–673 (1990).
S. A. Wood, B. W. Mountain, and P. Pan, “The aqueous geochemistry of platinum, palladium and gold: recent experimental constraints and a reevaluation of theoretical predictions,” Can. Mineral. 30, 955–982 (1992).
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Original Russian Text © I.Ya. Koshcheeva, I.V. Kubrakova, N.V. Korsakova, O.A. Tyutyunnik, 2016, published in Geokhimiya, 2016, No. 7, pp. 641–650.
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Koshcheeva, I.Y., Kubrakova, I.V., Korsakova, N.V. et al. Solubility and migration ability of rhodium in natural conditions: model experimental data. Geochem. Int. 54, 624–632 (2016). https://doi.org/10.1134/S0016702916050049
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DOI: https://doi.org/10.1134/S0016702916050049