Abstract
In this paper, a novel flexible Schiff base chemosensor N-(2-hydroxy-3-methoxybenzylidene)-2-(benz-amido)benzohydrazide (L) has been designed, synthesised and characterised by 1H-NMR, IR spectroscopy, ESI-MS spectrometry and single crystal XRD analysis. A significant fluorescence enhancement of L was observed only in the presence of Ni2+ ions with a detection limit of 3.64 uM whereas Cu2+ induced fluorescence quenching, although both the metals showed colorimetric responses in methanol-Tris-HCl buffer (10 mM, pH 7.2) solution (1:1, v/v). The single crystal structure of L-Cu2+ has also been determined. No major interference by the other effective background cations (Fe3+,Fe2+,Co2+,Zn2+,Cd2+, Hg2+,Pb2+,Cr3+,Ag+,Al3+ and Mn2+) was observed even at a higher concentration of analytes. The experimental results were further supported by DFT studies. The chemosensor L can be applied to the formation of binary logical devices, recovery of contaminated water samples and living intracellular media.
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Acknowledgements
G. K. P. would like to thank the Department of Science and Technology (SR/FST/CSI-264/2014), Government of India, New Delhi for financial support. One of the authors A. K. M. thanks the CSIR, and KR thanks DST, Government of India (No. PDF/ 2017/001365) for financial support in the form of research fellowships.
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Manna, A.K., Rout, K., Chowdhury, S. et al. A dual-mode highly selective and sensitive Schiff base chemosensor for fluorescent colorimetric detection of Ni2+ and colorimetric detection of Cu2+. Photochem Photobiol Sci 18, 1512–1525 (2019). https://doi.org/10.1039/c9pp00114j
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DOI: https://doi.org/10.1039/c9pp00114j