Abstract
Kagome metals are an exciting playground for the explorations of novel phenomena at the intersection of topology, electron correlations and magnetism. The family of FeSn-based kagome magnets in particular attracted a lot of attention for simplicity of the layered crystal structure and tunable topological electronic band structure. Despite a significant progress in understanding their bulk properties, surface electronic and magnetic structures are yet to be fully explored in many of these systems. In this work, we focus on a prototypical kagome metal FeSn. Using a combination of spin-averaged and spin-polarized scanning tunneling microscopy, we provide the first atomic-scale visualization of the layered antiferromagnetic structure at the surface of FeSn. In contrast to the field-tunable electronic structure of cousin material Fe3Sn2 that is a ferromagnet, we find that electronic density-of-states of FeSn is robust to the application of external magnetic field. Interestingly, despite the field insensitive electronic band structure, FeSn exhibits bound states tied to specific impurities with large effective moments that strongly couple to the magnetic field. Our experiments provide microscopic insights necessary for theoretical modeling of FeSn and serve as a spring board for spin-polarized measurements of topological magnets in general.
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Introduction
Quantum materials composed of atoms arranged on a lattice of corner-sharing triangles (kagome lattice) are a versatile platform to explore electronic phenomena at the intersection of band topology and electronic correlations1,2,3,4,5,6,7,8,9. While the initial excitement behind these systems stemmed from the possibility of realizing spin liquid phases1,10, recent experiments revealed a range of other novel electronic phases that can emerge on a kagome lattice in the presence of spin–orbit coupling, non-trivial Berry curvature and/or magnetism. These for example include topological flat bands11,12, Chern magnet phase13, Weyl semimetal phase and Fermi arcs14,15, and various density waves16,17,18,19,20,21.
In the pursuit of exotic electronic phenomena, the family of FexSny kagome magnets has been of particular interest22,23,24,25,26,27,28,29,30,31. Materials in this family are characterized by the prototypical electronic band structure associated with the kagome lattice, consisting of Dirac cones at the Brillouin zone boundary and a dispersionless flat band24,25,27,28,30. These systems exhibit a layered crystal structure composed of different sequences of Fe3Sn kagome layers and honeycomb Sn layers stacked along the c-axis. This stacking order directly influences the type of emergent magnetic ordering in the bulk22,32,33. For example, Fe3Sn2, composed of Fe3Sn–Fe3Sn–Sn building blocks is ferromagnetic24,25,30,31. On the other hand FeSn, composed of alternating Fe3Sn layers and Sn layers is a layered antiferromagnet: Fe spins within each layer align ferromagnetically, but couple antiferromagnetically between adjacent layers34 (Fig. 1a, h). Despite the well-known magnetic structures in the bulk, magnetic ordering at the surface of Fe-based kagome metals and its tunability with external perturbations is yet to be fully investigated. Experimentally establishing this would be essential for several reasons. First, given the broken crystal symmetry at the surface, the magnetic structure may be different than that in the bulk. Dichotomy between surface and bulk magnetism has indeed been hypothesized to occur in other magnetic topological systems35. Second, surface magnetization can lead to the transition from massless to massive Dirac fermions25, the latter of which in principle carrying a non-trivial Chern number. As such, direct measurement of magnetic properties at the surface is highly desirable for a complete understanding of these materials. However, such measurements have been challenging to achieve in many of the kagome magnets to-date. In this work, we use spin-polarized scanning tunneling microscopy and spectroscopy to visualize the layered antiferromagnetic structure at the surface of prototypical kagome metal FeSn.
Results
Kagome metal FeSn is a bulk antiferromagnet (Neel temperature TN ≈ 370 K32) characterized by the P6/mmm group symmetry and a hexagonal lattice (a = 5.298 Å and c = 4.448 Å)36. Its crystal structure consists of alternating honeycomb Sn layers and Fe3Sn kagome layers (Fig. 1a, b). We cleave bulk single crystals of FeSn in ultra-high vacuum (UHV) and immediately insert them into the STM head where they are imaged at 4.5 K (Methods). STM topographs reveal both possible surface terminations: honeycomb Sn and kagome Fe3Sn (Fig. 1c, d). While both of them exhibit a similar hexagonal structure with an in-plane lattice constant of a ≈ 5.3 Å (Fig. 1c,d), they are characterized by distinct spectroscopic signatures: one with a spectral peak near − 50 meV (Fig. 1e) and the other where the peak is absent (Fig. 1f). We identify each termination based on the following. First in Fig. 1c, we can clearly discern atoms arranged on a honeycomb lattice, which is consistent with individual atoms in the complete Sn layer (inset in Fig. 1c) and qualitatively similar to the STM topographs of single layer stanene37. Second, partial overlayers of Sn on top of the kagome layer, such as the one seen in Fig. 1g,i, have also been reported to occur on isostructural CoSn38, thus pointing again towards the taller termination indeed being the Sn layer.
We first explore the Sn surface termination, which we have predominantly observed in our measurements. We focus on a region encompassing two Sn terraces across a single unit cell step (Fig. 2a, b). Using a conventional (spin-averaged) STM tip, we find that both terraces show identical dI/dV spectra (Fig. 2c, d). To evaluate if the electronic band structure changes with applied magnetic field B, as it often does in magnetic materials25,39, we repeat the dI/dV measurement as a function of out-of-plane magnetic field. We find no difference between zero-field dI/dV spectra and those acquired in ± 4 T magnetic field (minus sign denotes the reversal of the magnetic field applied antiparallel to the c-axis) (Fig. 2e). To rule out the unlikely scenario that the cleaving process affects the FeSn surface properties, we demonstrate the same absence of magnetic field tunability of dI/dV spectra in home-grown FeSn thin films synthesized by molecular beam epitaxy (Supplementary Fig. 1).
Magnetic ordering in FeSn lifts the degeneracy of the electronic bands, leading to spin majority and minority bands that can be observed on both surface terminations40. Due to the antiferromagnetic coupling between adjacent layers stacked along the c-axis (Fig. 1h), spin majority and minority bands should in principle “switch” between adjacent layers. However, as shown in Fig. 2, conventional STM cannot resolve the difference in the density of states between inequivalent terraces. To explore the spin texture in more detail, we use spin-polarized STM (Methods), a valuable tool for real-space spin-resolved imaging of various antiferromagnets, such as Fe-based metals including superconductors41,42,43,44, Ir-based oxides45,46 and elemental Cr47,48 and Mn49. We again locate a region with several consecutive steps, each between adjacent Sn layers, and acquire a dI/dV line profile across the steps (Fig. 3a, b). For the ease of discussion, we label each terrace with consecutive integers, starting with 1 on the lowest terrace. We find that the average dI/dV spectra acquired on terraces denoted by even numbers are all identical, but markedly different from the spectra acquired on odd terraces (Fig. 3c). In particular, the spectral peak at negative energy exhibits a pronounced spectral weight shift between the two types of terraces. This trend is present across all steps imaged, and can be visualized as the systematic variation in differential conductance at negative energies (Fig. 3d, g). Since dI/dV spectra acquired using a spin-averaged tip show no difference between consecutive steps, the difference observed here can be understood as a consequence of spin-polarized tunneling. In principle, for a fixed tip-sample distance, the tunneling current will depend on the overlap between the spin direction of the tip and that of the sample50. In our experiment, as the spin orientation of the tip remains the same across all terraces, the sample spin direction has to be different between adjacent terraces (Fig. 3f), which is reflected in the measured dI/dV spectrum. Systematic variation of dI/dV spectra is consistent with the expected layered antiferromagnetic structure, where neighboring terraces offset by a full unit cell step height should have spins polarized in opposite directions in the ab-plane (Fig. 1h). This interpretation is further confirmed by the magnetic field dependence, where the difference between the two types of terraces is reversed as the spin of the tip is “flipped” by external field (Fig. 3e). We note that similarly to previous SP-STM experiments41,45,46, the spin-polarized STM tip likely has both in-plane and out-of-plane spin components, and the out-of-plane magnetic field used in our experiments serves to flip the spin polarization of the STM tip. The sample spins that lie in-plane34 are largely unaffected by the relatively small magnetic fields used in our work as the saturation field of FeSn is estimated to be enormous, about 300 T40. Our SP-STM measurements establish the existence of layered antiferromagnetism at the surface of FeSn, consistent with the bulk antiferromagnetic order.
To demonstrate that this behavior is not confined to a single surface termination, we show dI/dV spectra acquired on top of the occasionally observed Fe3Sn kagome surface terraces (Fig. 4). dI/dV spectra acquired using a spin-polarized STM tip across the consecutive Fe3Sn steps show pronounced spectral differences between them across the entire energy range imaged (Fig. 4d). This is in contrast to the Sn termination, where the difference in spin-polarized integrated density of states primarily occurs on the negative side, but dI/dV spectra at positive energies appear nearly indistinguishable (Fig. 4c).
It is interesting to note that the surface of cleaved single crystals of FeSn also shows several types of impurities with distinct spatial signatures (Fig. 5a): two-fold symmetric (labeled A, B and C), C3-symmetric (labeled D) or C6-symmetric (labeled E). Based on the intra-unit cell position with respect to the Sn surface atoms, we can identify impurities A, B and C to occur at the Fe site, while D and E occur at the Sn site (Fig. 5b). The Fe-site location of A, B and C defects would naturally explain the C2-symmetric signature due to the two-fold symmetry of the atomic arrangement around this particular Fe site that is shared between two neighboring triangles (Fig. 5b). We note that this two-fold electronic signature is not indicative of a nematic phase, seen in cousin kagome system Fe3Sn225, since the spatial signature rotates by multiple of 120° for different impurities (see different orientation of A, B and C in Fig. 5a), but simply a consequence of the crystal structure. In addition to the two-fold electronic signal, impurity A shows bound states located in close proximity to zero energy (Fig. 5c,d,g). These can be modulated by the application of external magnetic field across the Fermi level for a moderate range of field values used in our experiment (Fig. 5e, f). Interestingly, the bound states evolve in different directions as the direction of the magnetic field is reversed, indicating a fixed local moment irrespective of the field direction (Fig. 5e, f). Field-tunable impurity states have previously been reported at defect sites in kagome magnet Co3Sn2S251,52. In contrast to the bound states in Co3Sn2S2 however, field-tunable bound states observed in FeSn are in close proximity to the Fermi level.
Discussion
Our SP-STM experiments reveal staggered modulations of dI/dV spectra across consecutive surface terraces, consistent with a robust layered antiferromagnetic structure of FeSn that persists at the surface. We note that it is difficult to conclusively identify the spectral features in dI/dV spectra in relation to particular electronic bands given the complexity of the band structure27, and this is beyond the scope of the current paper. Given that theoretical calculations indicate the presence of several van Hove singularities in the vicinity of the Fermi level27, it is conceivable that the peak in dI/dV around − 50 meV in Fig. 2 can be attributed to a van Hove singularity, but further work will be necessary to elucidate this. We deem that the origin of this spectral peak is unlikely to arise due to a flat band, as the flat band is located more than 200 meV below the Fermi level27. We can also rule out impurity bound states as dI/dV spectra are spatially extremely homogeneous (Fig. 2c). We further mention that although the kagome plane is located below the Sn layer, termination-dependent band structure calculations and ARPES measurements27 indicate that some Fe bands should still be detectable on the Sn termination. We find that electronic band structure is largely insensitive to the application of moderate out-of-plane magnetic field, in contrast to the ferromagnetic cousin Fe3Sn2 where the electronic band structure rapidly evolves with field as the magnetic moments rotate out-of-plane25. Field insensitivity of the band structure observed here is also different from another kagome antiferromagnet YMn6Sn6, where magnetic field leads to a continuous filed-induced band renormalization53 attributed to a combination of spin canting and orbital magnetization. This could suggest that these effects are negligible in FeSn. Despite insensitivity of the band structure to magnetic field, we reveal that certain Fe-site impurities harbor bound states tunable by magnetic field, shifting to higher energy regardless of the direction of magnetic field. The demonstrated ability to shift the energy of these bounds states away and across the Fermi level could potentially be harnessed in transport measurements if a sufficient density of impurities is induced during the growth process.
Methods
Bulk single crystals of FeSn are grown using the self-flux method. The high-purity Fe (piece) and Sn (shot) were put into corundum crucibles and sealed into quartz tubes with a ratio of Fe:Sn = 2:98. The tube was heated to 1273 K and held there for 12 h, then cooled to 823 K at a rate of 3 K/h. The flux was removed by centrifugation, and shiny crystals with typical size about 2 × 2 × 5 mm3 can be obtained.
FeSn single crystals are cleaved in UHV in about 10–10 Torr pressure and immediately inserted into the STM head. For spin-averaged measurements, we use a chemically-etched W tip, annealed in vacuum to remove the oxide layer from the surface. To create spin-polarized tips, we start with the same etched W wire, but train it on the FeSn sample surface by fast scanning and bias pulsing. The tip can ultimately become spin-polarized, likely by picking up one or more magnetic atoms from the sample surface. In order to demonstrate that the tip is actually spin-polarized, we test the tip on the cleaved surface of FeTe single crystal after the completion of measurements on FeSn (Supplementary Fig. 2). If the tip is spin-polarized, it will show stripe-like signature of antiferromagnetic ordering in FeTe, as for example reported in Refs.41. As shown in Fig. S2, our spin-polarized tip shows the desired stripe modulation related to the underlying antiferromagnetism in FeTe. The tips we create in this manner are “ferromagnetic”: the polarization can be flipped by external magnetic field. We test this by the dependence of STM topographs in external magnetic field applied perpendicular to the sample surface. For example, STM topographs acquired with such a tip show almost no difference in 0 and − 1 T magnetic field (tip has same polarization in both fields), but exhibit a stripe “shift” between 1 T and 0 T (tip polarization direction is “flipped”), demonstrating that the W tip is indeed spin-polarized (Supplementary Fig. 2).
Data availability
The datasets generated and/or analyzed during the current study are available in the Zenodo repository, https://doi.org/10.5281/zenodo.6456564. All other data that support the findings of this study are available from the corresponding author upon reasonable request.
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Acknowledgements
I.Z. gratefully acknowledges the support from DOE Early Career Award DE-SC0020130 for spin-polarized STM measurements. Z.W. acknowledges the support of U.S. Department of Energy, Basic Energy Sciences Grant No. DE-FG02-99ER45747 and the Cottrell SEED Award No. 27856 from Research Corporation for Science Advancement. H.C.L. was supported by the National Key R&D Program of China (Grant No. 2018YFE0202600), the Beijing Natural Science Foundation (Grant No. Z200005), and the Beijing National Laboratory for Condensed Matter Physics.
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STM experiments and data analysis were performed by H.L. and H.Z. Q.W. and Q.Y. synthesized and characterized FeSn bulk single crystals under the supervision of H.C.L. Z.R. and S.S. synthesized FeSn thin films. Z.W. provided theoretical input on the interpretation of data. H.L. and I.Z. wrote the paper, with the input from all authors. I.Z. supervised the project.
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Li, H., Zhao, H., Yin, Q. et al. Spin-polarized imaging of the antiferromagnetic structure and field-tunable bound states in kagome magnet FeSn. Sci Rep 12, 14525 (2022). https://doi.org/10.1038/s41598-022-18678-8
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DOI: https://doi.org/10.1038/s41598-022-18678-8
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