Abstract
In the pursuit of more reliable and affordable energy storage solutions, interest in batteries powered by water-based electrolytes is surging. Today’s commercial aqueous batteries lack the energy density and cycle life required to compete in the fast-growing transportation and grid storage sectors, but this will change as new materials and cell design strategies are developed. Many of the constraints of traditional aqueous batteries have been alleviated by innovations such as selective membranes, lean-water electrolytes and new types of electrode reactions. As a result, an unprecedentedly broad range of electrode chemistries may be paired in previously impossible ways via modular cell designs to achieve performance metrics unattainable by traditional aqueous batteries. These innovations, however, change the properties for which aqueous batteries are traditionally known, and may result in compromises. This Review starts by examining the historical evolution of aqueous batteries, summarizing their essential merits and limitations. It then analyses how modern chemistries and cell designs may further strengthen the merits of aqueous batteries and address their limits while sometimes compromising prior merits, providing a holistic and critical overview of modern aqueous battery design.
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References
Zhao, Y. et al. A review on battery market trends, second-life reuse, and recycling. Sustain. Chem. 2, 167–205 (2021).
Kurzweil, P. Gaston Planté and his invention of the lead–acid battery — the genesis of the first practical rechargeable battery. J. Power Sources 195, 4424–4434 (2010).
Pavlov, D. in Lead-Acid Batteries: Science and Technology (ed. Detchko, P.) 3–28 (Elsevier, 2011).
Bullock, K. R. & Salkind, A. J. in Linden’s Handbook of Batteries 4th edn (ed. Thomas, B. R.) Ch. 17 (McGraw-Hill Education, 2011).
Nakayama, Y., Hojo, E. & Koike, T. Development of VRLA battery for hybrid bus. J. Power Sources 124, 551–558 (2003).
Moseley, P. T. High rate partial-state-of-charge operation of VRLA batteries. J. Power Sources 127, 27–32 (2004).
Shukla, A. K., Venugopalan, S. & Hariprakash, B. Nickel-based rechargeable batteries. J. Power Sources 100, 125–148 (2001).
Carcone, J. A. in Linden’s Handbook of Batteries 4th edn (ed. Thomas, B. R.) Ch. 21 (McGraw-Hill Education, 2011).
Brill, J. N. in Linden’s Handbook of Batteries 4th edn (ed. Thomas, B. R.) Ch. 24 (McGraw-Hill Education, 2011).
Chang, S., Young, K.-H., Nei, J. & Fierro, C. Reviews on the U.S. patents regarding nickel/metal hydride batteries. Batteries 2, 10 (2016).
Rand, D. A. J., Holden, L. S., May, G. J., Newnham, R. H. & Peters, K. Valve-regulated lead/acid batteries. J. Power Sources 59, 191–197 (1996).
Nelson, R. The basic chemistry of gas recombination in lead–acid batteries. JOM 53, 28–33 (2001).
Ye, Z. & Noréus, D. Oxygen and hydrogen gas recombination in NiMH cells. J. Power Sources 208, 232–236 (2012).
Allebrod, F., Chatzichristodoulou, C., Mollerup, P. L. & Mogensen, M. B. Electrical conductivity measurements of aqueous and immobilized potassium hydroxide. Int. J. Hydrog. Energy 37, 16505–16514 (2012).
Carton, A., Sobron, F., Bolado, S. & Gerboles, J. I. Density, viscosity, and electrical conductivity of aqueous solutions of lithium sulfate. J. Chem. Eng. Data 40, 987–991 (1995).
Ai, F. et al. Heteropoly acid negolytes for high-power-density aqueous redox flow batteries at low temperatures. Nat. Energy 7, 417–426 (2022).
Singh, M., Kaiser, J. & Hahn, H. Thick electrodes for high energy lithium ion batteries. J. Electrochem. Soc. 162, A1196–A1201 (2015).
Deveau, J., White, C. & Swan, L. G. Lead-acid battery response to various formation levels — part A: recommended formation levels for off-grid solar and conventional applications. Sustain. Energy Technol. Assess. 11, 1–10 (2015).
Wu, W., Shabhag, S., Chang, J., Rutt, A. & Whitacre, J. F. Relating electrolyte concentration to performance and stability for NaTi2(PO4)3/Na0.44MnO2 aqueous sodium-ion batteries. J. Electrochem. Soc. 162, A803–A808 (2015).
Singh, A., Cornilsen, B., Mullins, M. & Rogers, T. Nickel hydroxide impregnated carbon foam electrodes for rechargeable nickel batteries. US patent US20060024583A1 (2006).
Lai, Y. Q. et al. Electrochemical performance of a Pb/Pb-MnO2 composite anode in sulfuric acid solution containing Mn2+. Hydrometallurgy 115–116, 64–70 (2012).
Wessells, C., Ruffο, R., Huggins, R. A. & Cui, Y. Investigations of the electrochemical stability of aqueous electrolytes for lithium battery applications. Electrochem. Solid State Lett. 13, A59–A61 (2010).
Nakamura, K., Shiomi, M., Takahashi, K. & Tsubota, M. Failure modes of valve-regulated lead/acid batteries. J. Power Sources 59, 153–157 (1996).
He, P., Liu, J.-L., Cui, W.-J., Luo, J.-Y. & Xia, Y.-Y. Investigation on capacity fading of LiFePO4 in aqueous electrolyte. Electrochim. Acta 56, 2351–2357 (2011).
Gheytani, S., Liang, Y., Jing, Y., Xu, J. Q. & Yao, Y. Chromate conversion coated aluminium as a light-weight and corrosion-resistant current collector for aqueous lithium-ion batteries. J. Mater. Chem. A 4, 395–399 (2016).
Juda, W. & McRae, W. A. Coherent ion-exchange gels and membranes. J. Am. Chem. Soc. 72, 1044–1044 (1950).
Mauritz, K. A. & Moore, R. B. State of understanding of Nafion. Chem. Rev. 104, 4535–4586 (2004).
Thaller, L. H. Electrically rechargeable redox flow cell. US patent US3996064A (1976).
Noya, S., Uchida, M. & Yoshino, M. Double fluid cell. Patent JPH04101358A (1992).
Visco, S. J., Nimon, E. & Katz, B. The development of high energy density lithium/air and lithium/water batteries with no self-discharge. ECS Meet. Abstr. MA2006-02, 389–389 (2006).
Imanishi, N. et al. Lithium anode for lithium-air secondary batteries. J. Power Sources 185, 1392–1397 (2008).
Li, H., Wang, Y., Na, H., Liu, H. & Zhou, H. Rechargeable Ni-Li battery integrated aqueous/nonaqueous system. J. Am. Chem. Soc. 131, 15098–15099 (2009).
Hasegawa, S. et al. Study on lithium/air secondary batteries — stability of NASICON-type lithium ion conducting glass–ceramics with water. J. Power Sources 189, 371–377 (2009).
Zhang, T. et al. A novel high energy density rechargeable lithium/air battery. Chem. Commun. 46, 1661–1663 (2010).
Yang, T., Liu, X., Sang, L. & Ding, F. Control of interface of glass-ceramic electrolyte/liquid electrolyte for aqueous lithium batteries. J. Power Sources 244, 43–49 (2013).
Suo, L. et al. ‘Water-in-salt’ electrolyte enables high-voltage aqueous lithium-ion chemistries. Science 350, 938–943 (2015).
Dubouis, N. et al. The role of the hydrogen evolution reaction in the solid–electrolyte interphase formation mechanism for ‘water-in-salt’ electrolytes. Energy Environ. Sci. 11, 3491–3499 (2018).
Yang, C. et al. 4.0 V aqueous Li-ion batteries. Joule 1, 122–132 (2017).
Wang, F. et al. Hybrid aqueous/non-aqueous electrolyte for safe and high-energy Li-ion batteries. Joule 2, 927–937 (2018).
Zhang, J. et al. ‘Water-in-salt’ polymer electrolyte for Li-ion batteries. Energy Environ. Sci. 13, 2878–2887 (2020).
Cao, L. et al. Solvation structure design for aqueous Zn metal batteries. J. Am. Chem. Soc. 142, 21404–21409 (2020).
Viswanathan, V. et al. Cost and performance model for redox flow batteries. J. Power Sources 247, 1040–1051 (2014).
Yuan, Z. et al. Low-cost hydrocarbon membrane enables commercial-scale flow batteries for long-duration energy storage. Joule 6, 884–905 (2022).
Li, Z. & Lu, Y.-C. Polysulfide-based redox flow batteries with long life and low levelized cost enabled by charge-reinforced ion-selective membranes. Nat. Energy 6, 517–528 (2021).
Yamada, Y. et al. Hydrate-melt electrolytes for high-energy-density aqueous batteries. Nat. Energy 1, 16129 (2016).
Suo, L. et al. Advanced high-voltage aqueous lithium-ion battery enabled by ‘water-in-bisalt’ electrolyte. Angew. Chem. 128, 7252–7257 (2016).
Zheng, J. et al. Understanding thermodynamic and kinetic contributions in expanding the stability window of aqueous electrolytes. Chem 4, 2872–2882 (2018).
Nakamoto, K., Sakamoto, R., Ito, M., Kitajou, A. & Okada, S. Effect of concentrated electrolyte on aqueous sodium-ion battery with sodium manganese hexacyanoferrate cathode. Electrochemistry 85, 179–185 (2017).
Leonard, D. P., Wei, Z., Chen, G., Du, F. & Ji, X. Water-in-salt electrolyte for potassium-ion batteries. ACS Energy Lett. 3, 373–374 (2018).
Lukatskaya, M. R. et al. Concentrated mixed cation acetate ‘water-in-salt’ solutions as green and low-cost high voltage electrolytes for aqueous batteries. Energy Environ. Sci. 11, 2876–2883 (2018).
Zhang, C. et al. A ZnCl2 water-in-salt electrolyte for a reversible Zn metal anode. Chem. Commun. 54, 14097–14099 (2018).
Li, T., Li, M., Li, H. & Zhao, H. High-voltage and long-lasting aqueous chlorine-ion battery by virtue of ‘water-in-salt’ electrolyte. iScience 24, 101976 (2021).
He, X. et al. Fluorine-free water-in-ionomer electrolytes for sustainable lithium-ion batteries. Nat. Commun. 9, 5320 (2018).
Zhao, J. et al. ‘Water-in-deep eutectic solvent’ electrolytes enable zinc metal anodes for rechargeable aqueous batteries. Nano Energy 57, 625–634 (2019).
Xie, J., Liang, Z. & Lu, Y.-C. Molecular crowding electrolytes for high-voltage aqueous batteries. Nat. Mater. 19, 1006–1011 (2020).
Peng, M. et al. Molecular crowding agents engineered to make bioinspired electrolytes for high-voltage aqueous supercapacitors. eScience 1, 83–90 (2021).
Hao, J. et al. Boosting zinc electrode reversibility in aqueous electrolytes by using low-cost antisolvents. Angew. Chem. Int. Ed. 60, 7366–7375 (2021).
Bi, H. et al. A universal approach to aqueous energy storage via ultralow-cost electrolyte with super-concentrated sugar as hydrogen-bond-regulated solute. Adv. Mater. 32, 2000074 (2020).
Sun, Y. et al. Low-cost and long-life Zn/Prussian blue battery using a water-in-ethanol electrolyte with a normal salt concentration. Energy Storage Mater. 48, 192–204 (2022).
Jaumaux, P. et al. Non-flammable liquid and quasi-solid electrolytes toward highly-safe alkali metal-based batteries. Adv. Funct. Mater. 31, 2008644 (2021).
Bin, D., Wen, Y., Wang, Y. & Xia, Y. The development in aqueous lithium-ion batteries. J. Energy Chem. 27, 1521–1535 (2018).
Poizot, P. et al. Opportunities and challenges for organic electrodes in electrochemical energy storage. Chem. Rev. 120, 6490–6557 (2020).
Ruan, P., Liang, S., Lu, B., Fan, H. J. & Zhou, J. Design strategies for high‐energy-density aqueous zinc batteries. Angew. Chem. Int. Ed. 61, e202200598 (2022).
Liu, Z. et al. Issues and opportunities facing aqueous Mn2+/MnO2-based batteries. ChemSusChem 15, e202200348 (2022).
Sánchez-Díez, E. et al. Redox flow batteries: Status and perspective towards sustainable stationary energy storage. J. Power Sources 481, 228804 (2021).
Zhang, R. et al. Recent advances for Zn-gas batteries beyond Zn-air/oxygen battery. Chin. Chem. Lett. https://doi.org/10.1016/j.cclet.2022.1006.1023 (2022).
Li, W., Dahn, J. R. & Wainwright, D. S. Rechargeable lithium batteries with aqueous electrolytes. Science 264, 1115–1118 (1994).
Luo, J. Y., Cui, W. J., He, P. & Xia, Y. Y. Raising the cycling stability of aqueous lithium-ion batteries by eliminating oxygen in the electrolyte. Nat. Chem. 2, 760–765 (2010).
Sun, W. et al. ‘Water-in-salt’ electrolyte enabled LiMn2O4/TiS2 lithium-ion batteries. Electrochem. Commun. 82, 71–74 (2017).
Li, Z., Young, D., Xiang, K., Carter, W. C. & Chiang, Y.-M. Towards high power high energy aqueous sodium-ion batteries: the NaTi2(PO4)3/Na0.44MnO2 system. Adv. Energy Mater. 3, 290–294 (2013).
Whitacre, J. F. et al. A polyionic, large-format energy storage device using an aqueous electrolyte and thick-format composite NaTi2(PO4)3/activated carbon negative electrodes. Energy Technol. 3, 20–31 (2015).
Wessells, C. D., Peddada, S. V., McDowell, M. T., Huggins, R. A. & Cui, Y. The effect of insertion species on nanostructured open framework hexacyanoferrate battery electrodes. J. Electrochem. Soc. 159, A98–A103 (2011).
Huang, J. et al. Polyaniline-intercalated manganese dioxide nanolayers as a high-performance cathode material for an aqueous zinc-ion battery. Nat. Commun. 9, 2906 (2018).
Dong, S. et al. Ultra-fast NH4+ storage: strong H bonding between NH4+ and bi-layered V2O5. Chem 5, 1537–1551 (2019).
Zhang, H. et al. Interlayer engineering of α-MoO3 modulates selective hydronium intercalation in neutral aqueous electrolyte. Angew. Chem. Int. Ed. 60, 896–903 (2021).
Zheng, J. P., Cygan, P. J. & Jow, T. R. Hydrous ruthenium oxide as an electrode material for electrochemical capacitors. J. Electrochem. Soc. 142, 2699–2703 (1995).
Lukatskaya, M. R. et al. Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides. Nat. Energy 2, 17105 (2017).
Kundu, D., Adams, B. D., Duffort, V., Vajargah, S. H. & Nazar, L. F. A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode. Nat. Energy 1, 16119 (2016).
Chengjun, X., Baohua, L., Hongda, D. & Feiyu, K. Energetic zinc ion chemistry: the rechargeable zinc ion battery. Angew. Chem. Int. Ed. 51, 933–935 (2012).
Chen, H. et al. Reunderstanding the reaction mechanism of aqueous Zn–Mn batteries with sulfate electrolytes: role of the zinc sulfate hydroxide. Adv. Mater. 34, 2109092 (2022).
Shpigel, N. et al. New aqueous energy storage devices comprising graphite cathodes, MXene anodes and concentrated sulfuric acid solutions. Energy Storage Mater. 32, 1–10 (2020).
Huang, Z. et al. Manipulating anion intercalation enables a high-voltage aqueous dual ion battery. Nat. Commun. 12, 3106 (2021).
Jiang, H. et al. An aqueous dual-ion battery cathode of Mn3O4 via reversible insertion of nitrate. Angew. Chem. 131, 5340–5345 (2019).
Qin, H., Song, Z. P., Zhan, H. & Zhou, Y. H. Aqueous rechargeable alkali-ion batteries with polyimide anode. J. Power Sources 249, 367–372 (2014).
Yan, L., Qi, Y.-e, Dong, X., Wang, Y. & Xia, Y. Ammonium-ion batteries with a wide operating temperature window from −40 to 80 °C. eScience 1, 212–218 (2021).
Liang, Y. et al. Universal quinone electrodes for long cycle life aqueous rechargeable batteries. Nat. Mater. 16, 841–848 (2017).
Wang, F. et al. High-voltage aqueous magnesium ion batteries. ACS Cent. Sci. 3, 1121–1128 (2017).
Gheytani, S. et al. An aqueous Ca-ion battery. Adv. Sci. 4, 1700465 (2017).
Yue, X., Liu, H. & Liu, P. Polymer grafted on carbon nanotubes as a flexible cathode for aqueous zinc ion batteries. Chem. Commun. 55, 1647–1650 (2019).
Perticarari, S. et al. Dual anion–cation reversible insertion in a bipyridinium–diamide triad as the negative electrode for aqueous batteries. Adv. Energy Mater. 8, 1701988 (2018).
Patil, N. et al. Polymers bearing catechol pendants as universal hosts for aqueous rechargeable H+, Li-ion, and post-Li-ion (mono-, di-, and trivalent) batteries. ACS Appl. Energy Mater. 2, 3035–3041 (2019).
Zhang, Y., Zhao, L., Liang, Y., Wang, X. & Yao, Y. Effect of electrolyte anions on the cycle life of a polymer electrode in aqueous batteries. eScience 2, 110–115 (2022).
Novák, P., Müller, K., Santhanam, K. S. V. & Haas, O. Electrochemically active polymers for rechargeable batteries. Chem. Rev. 97, 207–282 (1997).
Kan, H. S., Hisato, W., Ryu, K., Kenichi, O. & Hiroyuki, N. An ultrahigh output rechargeable rlectrode of a hydrophilic radical polymer/nanocarbon hybrid with an exceptionally large current density beyond 1 A cm−2. Adv. Mater. 30, 1800900 (2018).
Zhang, Y., Liang, Y., Dong, H., Wang, X. & Yao, Y. Charge storage mechanism of a quinone polymer electrode for zinc-ion batteries. J. Electrochem. Soc. 167, 070558 (2020).
Bernard, P. in Encyclopedia of Electrochemical Power Sources Vol. 4 (ed. Jürgen, G.) 459–481 (Elsevier, 2009).
Salkind, A. J., Karpinski, A. P. & Serenyi, J. R. in Encyclopedia of Electrochemical Power Sources Vol. 5 (ed. Jürgen, G.) 513–523 (Elsevier, 2009).
Liu, J. et al. Sulfur-based aqueous batteries: electrochemistry and strategies. J. Am. Chem. Soc. 143, 15475–15489 (2021).
Guo, W., Tian, Z., Yang, C., Lai, Y. & Li, J. ZIF-8 derived nano-SnO2@ZnO as anode for Zn/Ni secondary batteries. Electrochem. Commun. 82, 159–162 (2017).
Shukla, A. K. & Hariprakash, B. in Encyclopedia of Electrochemical Power Sources Vol. 4 (ed. Jürgen, G.) 522–527 (Elsevier, 2009).
Cooper, A. & Moseley, P. T. Progress in overcoming the failure modes peculiar to VRLA batteries. J. Power Sources 113, 200–208 (2003).
Atlung, S. & Zachau-Christiansen, B. Degradation of the positive plate of the lead/acid battery during cycling. J. Power Sources 30, 131–141 (1990).
Hollenkamp, A. F. & Newnham, R. H. Benefits of controlling plate-group expansion: opening the door to advanced lead/acid batteries. J. Power Sources 67, 27–32 (1997).
Moseley, P. T., Nelson, R. F. & Hollenkamp, A. F. The role of carbon in valve-regulated lead–acid battery technology. J. Power Sources 157, 3–10 (2006).
Bača, P., Micka, K., Křivík, P., Tonar, K. & Tošer, P. Study of the influence of carbon on the negative lead-acid battery electrodes. J. Power Sources 196, 3988–3992 (2011).
Yang, C. et al. Unique aqueous Li-ion/sulfur chemistry with high energy density and reversibility. Proc. Natl Acad. Sci. USA 114, 6197–6202 (2017).
Kumar, M. & Nagaiah, T. C. High energy density aqueous rechargeable sodium-ion/sulfur batteries in ‘water in salt’ electrolyte. Energy Storage Mater. 49, 390–400 (2022).
Yang, C. et al. Aqueous Li-ion battery enabled by halogen conversion–intercalation chemistry in graphite. Nature 569, 245–250 (2019).
Yoo, S. J. et al. Fundamentally addressing bromine storage through reversible solid-state confinement in porous carbon electrodes: design of a high-performance dual-redox electrochemical capacitor. J. Am. Chem. Soc. 139, 9985–9993 (2017).
Zou, Y. et al. A four-electron Zn-I2 aqueous battery enabled by reversible I−/I2/I+ conversion. Nat. Commun. 12, 170 (2021).
Li, X. et al. Activating the I0/I+ redox couple in an aqueous I2–Zn battery to achieve a high voltage plateau. Energy Environ. Sci. 14, 407–413 (2021).
Kundu, D. et al. Organic cathode for aqueous Zn-ion batteries: taming a unique phase evolution toward stable electrochemical cycling. Chem. Mater. 30, 3874–3881 (2018).
Dong, H. et al. High-power Mg batteries enabled by heterogeneous enolization redox chemistry and weakly coordinating electrolytes. Nat. Energy 5, 1043–1050 (2020).
Wang, X. et al. Hydronium-ion batteries with perylenetetracarboxylic dianhydride crystals as an electrode. Angew. Chem. Int. Ed. 56, 2909–2913 (2017).
Li, Y. et al. High-energy-density quinone-based electrodes with [Al(OTF)]2+ storage mechanism for rechargeable aqueous aluminum batteries. Adv. Funct. Mater. 31, 2102063 (2021).
Nam, K. W. et al. Redox-active phenanthrenequinone triangles in aqueous rechargeable zinc batteries. J. Am. Chem. Soc. 142, 2541–2548 (2020).
Lin, Z. et al. A high capacity small molecule quinone cathode for rechargeable aqueous zinc-organic batteries. Nat. Commun. 12, 4424 (2021).
Guo, Z. et al. An environmentally friendly and flexible aqueous zinc battery using an organic cathode. Angew. Chem. Int. Ed. 57, 11737–11741 (2018).
Luo, Z. et al. High energy density aqueous zinc–benzoquinone batteries enabled by carbon cloth with multiple anchoring effects. J. Mater. Chem. A 9, 6131–6138 (2021).
Volmer, M. & Estermann, I. Über den mechanismus der molekülabscheidung an kristallen. Z. Phys. 7, 13–17 (1921).
Fischer, H. & Heiling, H. F. Morphology of the growth of isolated crystals in cathodic metal deposits. Trans. IMF 31, 90–105 (1954).
Winand, R. Electrocrystallization — theory and applications. Hydrometallurgy 29, 567–598 (1992).
Wang, R. Y., Kirk, D. W. & Zhang, G. X. Effects of deposition conditions on the morphology of zinc deposits from alkaline zincate solutions. J. Electrochem. Soc. 153, C357 (2006).
Bai, P., Li, J., Brushett, F. R. & Bazant, M. Z. Transition of lithium growth mechanisms in liquid electrolytes. Energy Environ. Sci. 9, 3221–3229 (2016).
Cai, Z. et al. Chemically resistant Cu–Zn/Zn composite anode for long cycling aqueous batteries. Energy Storage Mater. 27, 205–211 (2020).
Zhang, Y. et al. Separator effect on zinc electrodeposition behavior and its implication for zinc battery lifetime. Nano Lett. 21, 10446–10452 (2021).
Garcia, G., Ventosa, E. & Schuhmann, W. Complete prevention of dendrite formation in Zn metal anodes by means of pulsed charging protocols. ACS Appl. Mater. Inter. 9, 18691–18698 (2017).
Sun, K. E. K. et al. Suppression of dendrite formation and corrosion on zinc anode of secondary aqueous batteries. ACS Appl. Mater. Inter. 9, 9681–9687 (2017).
Sun, K. E. K., Hoang, T. K. A., Doan, T. N. L., Yu, Y. & Chen, P. Highly sustainable zinc anodes for a rechargeable hybrid aqueous battery. Chem. Eur. J. 24, 1667–1673 (2018).
Wang, F. et al. Highly reversible zinc metal anode for aqueous batteries. Nat. Mater. 17, 543–549 (2018).
Kang, L. et al. Nanoporous CaCO3 coatings enabled uniform Zn stripping/plating for long-life zinc rechargeable aqueous batteries. Adv. Energy Mater. 8, 1801090 (2018).
Zhao, Z. et al. Long-life and deeply rechargeable aqueous Zn anodes enabled by a multifunctional brightener-inspired interphase. Energy Environ. Sci. 12, 1938–1949 (2019).
Yang, Q. et al. Hydrogen-substituted graphdiyne ion tunnels directing concentration redistribution for commercial-grade dendrite-free zinc anodes. Adv. Mater. 32, 2001755 (2020).
Yuan, D. et al. Lignin@Nafion membranes forming Zn solid–electrolyte interfaces enhance the cycle life for rechargeable zinc-ion batteries. ChemSusChem 12, 4889–4900 (2019).
Trócoli, R. & La Mantia, F. An aqueous zinc-ion battery based on copper hexacyanoferrate. ChemSusChem 8, 481–485 (2015).
Parker, J. F. et al. Rechargeable nickel–3D zinc batteries: an energy-dense, safer alternative to lithium-ion. Science 356, 415–418 (2017).
Zheng, J. et al. Reversible epitaxial electrodeposition of metals in battery anodes. Science 366, 645–648 (2019).
Cui, M. et al. Quasi-isolated Au particles as heterogeneous seeds to guide uniform Zn deposition for aqueous zinc-ion batteries. ACS Appl. Energy Mater. 2, 6490–6496 (2019).
Tian, H. et al. Stable, high-performance, dendrite-free, seawater-based aqueous batteries. Nat. Commun. 12, 237 (2021).
Pletcher, D. et al. A novel flow battery — a lead-acid battery based on an electrolyte with soluble lead(ii): V. Studies of the lead negative electrode. J. Power Sources 180, 621–629 (2008).
Yang, Q. et al. Rechargeable aqueous Mn-metal battery enabled by inorganic–organic interfaces. Angew. Chem. Int. Ed. 61, e202206471 (2022).
Zhao, Q. et al. Solid electrolyte interphases for high-energy aqueous aluminum electrochemical cells. Sci. Adv. 4, eaau8131 (2018).
Hazza, A., Pletcher, D. & Wills, R. A novel flow battery: a lead acid battery based on an electrolyte with soluble lead(ii). Part I. Preliminary studies. Phys. Chem. Chem. Phys. 6, 1773–1778 (2004).
Pletcher, D. et al. A novel flow battery — A lead-acid battery based on an electrolyte with soluble lead(II): Part VI. Studies of the lead dioxide positive electrode. J. Power Sources 180, 630–634 (2008).
Verde, M. G., Carroll, K. J., Wang, Z., Sathrum, A. & Meng, Y. S. Achieving high efficiency and cyclability in inexpensive soluble lead flow batteries. Energy Environ. Sci. 6, 1573–1581 (2013).
Chen, W. et al. A manganese–hydrogen battery with potential for grid-scale energy storage. Nat. Energy 3, 428–435 (2018).
Rodrigues, S., Shukla, A. K. & Munichandraiah, N. A cyclic voltammetric study of the kinetics and mechanism of electrodeposition of manganese dioxide. J. Appl. Electrochem. 28, 1235–1241 (1998).
Xie, C. et al. A highly reversible neutral zinc/manganese battery for stationary energy storage. Energy Environ. Sci. 13, 135–143 (2020).
Chen, Y. et al. Copper activated near-full two-electron Mn4+/Mn2+ redox for mild aqueous Zn/MnO2 battery. Chem. Eng. J. 450, 137923 (2022).
Lei, J., Yao, Y., Wang, Z. & Lu, Y.-C. Towards high-areal-capacity aqueous zinc–manganese batteries: promoting MnO2 dissolution by redox mediators. Energy Environ. Sci. 14, 4418–4426 (2021).
Thaller, L. H. Electrically rechargeable redox flow cell. US patent US3996064 A (1976).
Skyllas-Kazacos, M., Rychcik, M., Robins, R. G., Fane, A. G. & Green, M. A. New all-vanadium redox flow cell. J. Electrochem. Soc. 133, 1057–1058 (1986).
Alotto, P., Guarnieri, M. & Moro, F. Redox flow batteries for the storage of renewable energy: a review. Renew. Sust. Energy Rev. 29, 325–335 (2014).
Eustace, D. J. Bromine complexation in zinc-bromine circulating batteries. J. Electrochem. Soc. 127, 528–532 (1980).
Carr, P., Symons, P. C. & Aller, D. J. Operational zinc chlorine battery based on a water store. US patent US4146680A (1979).
Cho, K. T. et al. High performance hydrogen/bromine redox flow battery for grid-sacale energy storage. J. Electrochem. Soc. 159, A1806–A1815 (2012).
Xu, Y., Wen, Y.-H., Cheng, J., Cao, G.-P. & Yang, Y.-S. A study of tiron in aqueous solutions for redox flow battery application. Electrochim. Acta 55, 715–720 (2010).
Huskinson, B. et al. A metal-free organic-inorganic aqueous flow battery. Nature 505, 195–198 (2014).
Kwabi, D. G. et al. Alkaline quinone flow battery with long lifetime at pH 12. Joule 2, 1894–1906 (2018).
Hollas, A. et al. A biomimetic high-capacity phenazine-based anolyte for aqueous organic redox flow batteries. Nat. Energy 3, 508–514 (2018).
Liu, T., Wei, X., Nie, Z., Sprenkle, V. & Wang, W. A total organic aqueous redox flow battery employing a low cost and sustainable methyl viologen anolyte and 4-HO-TEMPO catholyte. Adv. Energy Mater. 6, 1501449 (2016).
Beh, E. S. et al. A neutral pH aqueous organic–organometallic redox flow battery with extremely high capacity retention. ACS Energy Lett. 2, 639–644 (2017).
Liu, Y. et al. A long-lifetime all-organic aqueous flow battery utilizing TMAP-TEMPO radical. Chem 5, 1861–1870 (2019).
Janoschka, T. et al. An aqueous, polymer-based redox-flow battery using non-corrosive, safe, and low-cost materials. Nature 527, 78–81 (2015).
Armstrong, C. G. & Toghill, K. E. Stability of molecular radicals in organic non-aqueous redox flow batteries: a mini review. Electrochem. Commun. 91, 19–24 (2018).
Jing, Y. et al. In situ electrochemical recomposition of decomposed redox-active species in aqueous organic flow batteries. Nat. Chem. https://doi.org/10.1038/s41557-022-00967-4 (2022).
Sun, W. et al. A rechargeable zinc-air battery based on zinc peroxide chemistry. Science 371, 46–51 (2021).
Imanishi, N. & Yamamoto, O. Perspectives and challenges of rechargeable lithium–air batteries. Mater. Today Adv. 4, 100031 (2019).
Xie, J. & Wang, Y. Recent development of CO2 electrochemistry from Li–CO2 batteries to Zn–CO2 batteries. Acc. Chem. Res. 52, 1721–1729 (2019).
Cox, A. N. Allen’s Astrophysical Quantities 4th edn (Springer, 2002).
Du, C., Gao, Y., Wang, J. & Chen, W. Achieving 59% faradaic efficiency of the N2 electroreduction reaction in an aqueous Zn–N2 battery by facilely regulating the surface mass transport on metallic copper. Chem. Commun. 55, 12801–12804 (2019).
Kim, H. et al. Aqueous rechargeable Li and Na ion batteries. Chem. Rev. 114, 11788–11827 (2014).
Placke, T. et al. Perspective on performance, cost, and technical challenges for practical dual-ion batteries. Joule 2, 2528–2550 (2018).
Manthiram, A. & Li, L. Hybrid and aqueous lithium-air batteries. Adv. Energy Mater. 5, 1401302 (2015).
Turaev, D. Y. Use of ion-exchange membranes in chemical power cells. Russ. J. Appl. Chem. 78, 1615–1619 (2005).
Gu, S., Gong, K., Yan, E. Z. & Yan, Y. A multiple ion-exchange membrane design for redox flow batteries. Energy Environ. Sci. 7, 2986–2998 (2014).
Lu, Y., Goodenough, J. B. & Kim, Y. Aqueous cathode for next-generation alkali-ion batteries. J. Am. Chem. Soc. 133, 5756–5759 (2011).
Tomazic, G. & Skyllas-Kazacos, M. in Electrochemical energy storage for renewable sources and grid balancing (eds Patrick, T. M. & Jürgen, G.) 309–336 (Elsevier, 2015).
Khor, A. et al. Review of zinc-based hybrid flow batteries: from fundamentals to applications. Mater. Today Energy 8, 80–108 (2018).
Li, Z. et al. Aqueous semi-solid flow cell: demonstration and analysis. Phys. Chem. Chem. Phys. 15, 15833–15839 (2013).
Madec, L. et al. Surfactant for enhanced rheological, electrical, and electrochemical performance of suspensions for semisolid redox flow batteries and supercapacitors. ChemPlusChem 80, 396–401 (2015).
Chen, Y. et al. A stable and high-capacity redox targeting-based electrolyte for aqueous flow batteries. Joule 3, 2255–2267 (2019).
Li, Z. et al. Air-breathing aqueous sulfur flow battery for ultralow-cost long-duration electrical storage. Joule 1, 306–327 (2017).
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Liang, Y., Yao, Y. Designing modern aqueous batteries. Nat Rev Mater 8, 109–122 (2023). https://doi.org/10.1038/s41578-022-00511-3
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DOI: https://doi.org/10.1038/s41578-022-00511-3
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