Abstract
Elastic and stretchable functional fibers have drawn attentions from wide research field because of their unique advantages including high dynamic bending elasticity, stretchability and high mechanic strength. Lots of efforts have been made to find promising soft materials and improve the processing methods to fabricate the elastomer fibers with controllable fiber geometries and designable functionalities. Significant progress has been made and various interdisciplinary applications have been demonstrated based on their unique mechanical performance. A series of remarkable applications, involving biomedicine, optics, electronics, human machine interfaces etc., have been successfully achieved. Here, we summarize main processing methods to fabricate soft and stretchable functional fibers using different types of elastic materials, which are either widely used or specifically developed. We also introduce some representative applications of multifunctional elastic fibers to reveal this promising research area. All these reported applications indicate that the fast innovated interdisciplinary area is of great potential and inspire more remarkable ideas in fiber sensing, soft electronics, functional fiber integration and other related research fields.
Graphic abstract
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
Introduction
Fiber technologies originated from ancient spinning techniques have been exploited into a wide range of application fields with the fast development of the material industry and modern processing technologies [1, 2]. The accessible materials are no longer limited to natural plants and animal furs, but further extended to glasses [3], semiconductors [4], carbon materials [5], non-stretchable polymers, soft polymers and abundant functional materials [6]. Various fabrication methods have also been developed such as thermal drawing, casting, molding, extrusion, printing and so on [7, 8]. More importantly, they have enabled a wealth of functionalities beyond aesthetics and warmth. For example, optical telecommunication, optical sensing [9], neural interface [10], thermal detection, and acoustic emission have all been achieved [11,12,13]. Specifically some milestones in carbon fibers have been achieved for aerospace, civil engineering, military, and sports due to their outstanding properties in stiffness, low weight, high chemical resistance, low thermal expansion etc. [14, 15]; mass production of polymer fibers and tubes (e.g. polytetrafluoroethylene (PTFE) fibers, silicone fibers) have been realized for industry use and medical applications; and multi-material and multi-functional fibers have been demonstrated as high efficiency fiber energy storage units [16,17,18], luminescent fibers, photo detecting fibers [19], and electronic fibers [20]. Recently, polymers become more frequently used which can be processed under low temperature and they possess higher flexibility and better machinability, making them compatible with different functional materials and fiber architectures. Over the past few years, numerous non-stretchable polymer fibers (e.g., polycarbonates (PC) and polystyrene (PS)) have been demonstrated for applications in electronics [21, 22], energy conversion [23, 24], and biomedicine, etc. These various applications reveal the bright future of the fiber technology towards human–machine interface [25, 26]. Although these various fiber materials and fiber fabrication methods have benefited human life in numerous aspects, the limitations of these fibers still exist in soft and stretchable applications, such as conformal sensing, soft robotics, and textiles. Therefore, there is a rising demand for elastic and stretchable functional fibers because of their unique mechanical performance. Lots of efforts have been made to find promising soft materials and improve the processing methods to fabricate elastomer fibers with controllable fiber geometries and designable functionalities [27, 28].
Researchers have made significant progress in elastic and stretchable fibers and demonstrated various interdisciplinary applications based on their unique advantages including high dynamic bending elasticity, stretchability and high mechanic strength. Here, we summarize the main processing methods to fabricate soft and stretchable functional fibers using different types of elastic materials, which are either widely used or specifically developed. We also introduce some representative applications of multifunctional elastic fibers to reveal this promising research area and inspire more remarkable ideas in fiber sensing, soft electronics, functional fiber integration and other related research fields. The remaining challenges and potential solutions toward advanced elastic and stretchable functional fibers are discussed in the end to provide some practical insights and viewpoints.
Materials and Fabrication Methods
Different from the conventionally used non-stretchable polymer materials such as PC and PS, elastomers offer superior conformability with the soft human skin and other irregular shaped surfaces due to their excellent stretchability and softness. The elastomer materials should be chosen according to fabrication methods and applications. For example, optical transparency and refractive index of the elastomers would be the most important property for waveguide fibers; thermoset elastomer such as polydimethylsiloxane (PDMS) is not feasible for long-term heating processing like thermal extrusion and thermal injection. Table 1 summarizes some representative polymeric materials, and feasible strategies for elastic fiber fabrication together with their mechanical properties (Elongation at break/stiffness).
In general, thermoset elastomers should be shaped to fiber before crosslinking and solidity. Once the thermosets cross-linked, it would be difficult to dissolve and soften. While thermoplastic elastomers (TPEs) are easily dissolved in solvents or melted. And they could be thermally processed via various methods, including thermal injection and thermal drawing. Hydrogels are formed by a network of cross-linked polymer chains that are hydrophilic. Sometimes they are found as a colloidal gel dispersed in water. The mechanical properties of hydrogels could be modulated by modifying the polymer concentration of a hydrogel and the crosslinking concentration. And their rubber elasticity and viscoelasticity make them appealing for many biomedical applications, which have been widely investigated. The last one is biodegradable materials based on naturally derived polymers such as agarose and cellulose, and synthetic degradable polymers such as modified polylactic acid (PLA), and poly (lactic-co-glycolic) (PLGA). These biodegradable polymers could be absorbed by the human body after degrading, showing great potential in biomedical applications (Fig. 1).
Starting from thermally drawing, a traditional fiber fabrication process [61], we introduce some feasible fabrication methods for elastic and stretchable materials. Figure 2a illustrates some typical steps to make a preform before being drawn into fibers [35, 37, 52]. The main purpose is to shape the materials as designed. Some of the steps can be omitted and adjusted depending on the requirements. For example, if the raw material is SEBS pellets and we need a SEBS round rod, it can also be realized by heating the pellets and injecting them into a round tubular mold followed by cooling. When preform preparation is completed, it is then placed on the thermal drawing tower (Fig. 2b). And the clamp would draw it into thin fibers after the preform is heated to the processing temperature. Figure 2c shows some cross sections of elastic fibers fabricated via thermally drawing, indicating that customized structures can be achieved to meet different function needs.
Different from thermal drawing, 3D printing is a newly developed technology in recent years [62]. This is a three-dimensional layer-by-layer fabrication approach, allowing various materials to be precisely printed, including metals, ceramics, thermoplastic polymers and other polymers which could be cured under stimuli. As a result, 3D printing has become a versatile option to manufacture elastic fibers. Y. Tong et al. developed a 3D-printed elastomeric metal-core silicone-copper (Cu) (cladding-core) fiber, and worked as triboelectric nanogenerator (TENG) (Fig. 3a) [31]. Besides elastic fiber, 3D printing can also be used to manufacture assorted elastic subassemblies to develop a fully functional elastic system. P. Xu et al. developed optical lace (OL) for synthetic afferent neural networks [32]. They introduced a platform as OL for creating arbitrary 3D grids of soft, stretchable light guides for spatially continuous deformation sensing (Fig. 3a). This 3D sensory array provided functions similar to those of the afferent neural network in organisms. These light guide networks were distributed throughout the volume of a 3D-printed soft scaffold. Another fabrication method is a rotation-translation method for preparing the elastic conducting fiber. Z. Yang et al. developed a stretchable fiber-shaped dye-sensitized solar cell (DSSC) using this method [63,64,65]. As shown in Fig. 3b, two ends of the elastic fiber (e.g. rubber fiber) were attached to two motors. Then a continuous multi-walled carbon nanotubes (MWCNT) sheet fixed on a precisely motorized translation stage was drawn onto the elastic fiber with an angle. By adjusting the rotary speeds of the two motors and the moving speed of the translation stage, the MWCNT sheet was bundled onto the elastic fiber successfully as designed. The bounding force between the MWCNTs and the fiber surface was Van der Waals forces. Figure 3c illustrates another commonly used method to fabricate elastic fiber structures [66]. Cladding layer was coated on fiber core through dip- and spin-coating. The cladding layer was then cured by heating. Other coating methods like dry-coating was also used to fabricate the active enzyme layer-coated electrode of the stretchable biofuel cell fiber (Fig. 3d) [67].
Other elastic fiber fabrication methods are illustrated in Fig. 4. Figure 4a is a one-step co-extrusion fabrication of a stretchable fiber which was developed from basic extrusion method compatible with thermoplastic materials [29]. A. Leber et al. reported a core-cladding optical fiber via co-extrusion with polystyrene-based polymer Star Clear 1044 (refractive index (RI), 1.52) and fluorinated polymer Daikin T-530 (RI, 1.36) as core and cladding respectively. It sustained 300% tensile strains reversibly. Molding is another frequently adopted method to fabricate elastic fibers. A. Yetisen et al. reported a hydrogel optical fiber through molding with post coating steps [48]. Figure 4b shows the schematic of the core fabrication process through tube molding. Monomer solution was injected into a poly(vinyl chloride) (PVC) tube that served as a mold. Then it was crosslinked by exposing to UV light. The hydrogel fiber core was ejected from the mold by applying water pressure. As reported by Y. Zhao et al. (Fig. 4c) [67], dry spinning is a more direct way to form fiber structures in one step. The spinning solution was extruded out from a needle directly into the air. Due to the rapid evaporation of tetrahydrofuran (THF), the stream of the solution was dried to form fiber directly in the air at room temperature, and the Au nanowires (NWs)/SEBS elastic fiber was thus produced. H. Zhao et al. reported a multi-molding method achieving a stretchable optical waveguide. As illustrated in Fig. 4d, a pre-elastomer for the cladding was poured into the mold and demolded after curing [38]. Then the pre-elastomer of the core material was filled into the cladding. Finally, the pre-elastomer of the cladding was poured to enclose the core. At last, we introduce a strategy by rolling thin films to form fibers, which is not a scalable process but revealed an interesting performance in minimizing conductivity change when being stretched [68]. This strategy was reported by B. Zhang et al. as illustrated in Fig. 4e. They presented a cracking control strategy by simply rolling a facile PDMS thin film (10 μm thick) to prepare spiral structure conductive fibers. There was an encapsulation effect to confine the elongation of cracks by reducing the stress concentration in the two ends of each crack. The crack size in fiber was reduced and more conductive pathways were preserved during stretching. Thus, the fiber kept a good conductivity under stretching.
Applications
Fibers have an intrinsic advantage for distanced information delivering and transferring. So, they can be naturally utilized for implantable biomedical sensing and monitoring inside the body and tissues [69, 70]. Y. J. Heo et al. reported a long-term in vivo glucose monitoring using fluorescent hydrogel fibers. The polyethylene glycol (PEG)-bonded polyacrylamide (PAM) hydrogel fibers reduced inflammation and continuously responded to blood glucose concentration changes for up to 140 days [71]. Figure 5a–c shows the schematic and photographs to inject and remove the fluorescent hydrogel fiber, together with the continuous 140-day monitoring results. M. Choi et al. reported a step-index optical fiber made of biocompatible hydrogels to achieve a low-loss in vivo light guiding (< 0.42 dB cm−1) over the entire visible spectrum. As indicated in Fig. 5d, two hydrogel fibers (one for excitation and the other for collection) were implanted subcutaneously in an anesthetized mouse to measure the intrinsic optical absorption signal in response to oxygen/nitrogen ventilation [46]. C. Lu et al. developed a thermally drawn stretchable cyclic olefin copolymer elastomer (COCE) fiber coated with Ag nanowire (AgNW) mesh electrode layer to record spontaneous neural activity (Fig. 5e–l) [50]. Simultaneous stimulation and recording is demonstrated in transgenicmice expressing channelrhodopsin 2, where optical excitation evokes electromyographic (EMG) activity and hindlimb movement correlated to local field potentials measured in the spinal cord.
Besides in vivo applications, the elastomer materials can also be used in sensing and soft robotics. H. Zhao et al. fabricated stretchable optical waveguides as photonic strain sensors based on several elastomer materials [38]. This waveguide was prepared by pouring the pre-elastomers successively into a mold to form a core/cladding structure. And the stretchable sensor was finished by fixing a light-emitting diode (LED) and a photodetector to the two ends of the optical waveguide, respectively (Fig. 6a). The core material used in this work was a polyurethane rubber with a refractive index of 1.461 and a propagation loss of 2 dB/cm at the wavelength of 860 nm, while a highly absorptive silicone composite (1500 dB/cm at the specified wavelength) with a refractive index of 1.389 was selected as the cladding material. There are several reasons for choosing these two elastomers. Firstly, the large difference in refractive index between them ensures a large numerical aperture (0.45 at 860 nm) and acceptance angle (~ 26°), which makes it convenient for coupling the LED and the photodetector to the optical waveguide. Secondly, the large propagation loss of the core elastomer is beneficial for the sensing application: a small deformation of the waveguide will induce a relatively large change in the propagation loss, which is detectable by the low-cost photodiode and the current amplifying circuit. Thirdly, the high-absorptive and low-index cladding elastomer could serve as both cladding layer to ensure total internal reflection and protection layer to preventing the light signal influenced by ambient light. Lastly, the mechanical properties such as elastic moduli and stretchabilities of two elastomer materials are highly compliant, enabling the optical waveguide a stable performance under different deformation modes. After fabrication, the power loss of this optical waveguide was tested under elongation, bending, and local pressing, showing high linearity, repeatability, and precision to these deformation modes. To reveal its potential in soft robotics, finger actuators were constructed. As shown in Fig. 6b, the bending behavior of the figure was controlled by the internal pressure in the air channel, and three waveguides were bent to U-shape and casted inside the finger. The top waveguide experienced the largest strain when the finger bends, i.e., the top waveguide was the most sensitive to the bending motion. The middle waveguide was located in the middle plane of the figure to monitor the internal pressure. And the bottom waveguide was placed at the neural bending plane and extended to the fingertip, aiming to detect the contact force during the touching behaviors. Thus, haptic sensations, including internal pressure, bending, and external force, could be achieved by monitoring the power loss information from the three waveguides. A soft prosthetic hand was further built by mounting the fingers on a 3D printed palm mounted on a robot arm as shown in Fig. 6c. Using the robotic arm, the hand can be guided to laterally scan the surfaces of different objects and generate the topographical information. As shown in Fig. 6d, the height profile of different surfaces could be reconstructed, showing its capability of detecting surface shape and roughness. Moreover, the softness of object detection could also be achieved by monitoring the bending state (top waveguide) and contact force (bottom waveguide). Furthermore, object recognition was demonstrated by combining shape and softness detection. This soft prosthetic hand successfully recognized the ripe tomato, as shown in Fig. 6e, representing the great potential of elastomer materials in the field of soft robotics.
However, for most of the reported mechanical sensors, only one type of deformation and one point in space could be achieved by a single sensor [37]. Taking the optical waveguides introduced above as an example, a single waveguide could only detect one motion (stretching, bending, or single point pressing) at one time as the response signal is a scalar quantity (the optical power loss), in which the type of deformation type or location of pressure could not be distinguished. Although multifunctional sensing applications could be achieved by involving more sensors to form a sensing network (for example, by integrating more than ten waveguides into a prosthetic hand), the system complexity and the need of addressing all the sensors separately still greatly limits their sensing capabilities. To address these limitations, A. Leber et al. developed a soft and stretchable transmission line based on SEBS elastomer and liquid metal for detecting multimodal deformations simultaneously through interrogation by time-domain reflectometry [37]. The elastomer transmission line was fabricated by the thermal drawing technique. A SEBS preform with predesigned channels was used as shown in Fig. 6f, and the liquid metal was filled into the channels inside the preform followed by co-drawing with SEBS or injected into the microchannels in the drawn SEBS fiber to form the soft and stretchable transmission line. Owing to the good control over material and architecture achieved via the thermal drawing technique, the transmission line was uniform throughout its whole length and the configuration of the microchannels could be accurately arranged. The transmission lines with different lengths were interrogated with electrical time-domain reflectometry and the waveforms were obtained as shown in Fig. 6g. A signal with a step function was used in the measurement. The initial rise in the waveform represented the first incident of the signal and then propagation on the line. After a certain time, a full reflection was detected at the end of the open-circuit terminated line. Therefore, the length of the transmission line could be obtained by the propagation time and speed (light speed in the dielectric medium), which agreed well with the actual length (Inset of Fig. 6g. The flat signal between the first rise and full reflection indicated that the distributed resistance of the transmission line was very uniform because any change in distributed resistance could cause partial reflection, which was crucial for deformation sensing. As shown in Fig. 6h, when the transmission line was pressed, the liquid metal channels deformed accordingly, leading to an increase of distributed resistance at the pressing position. Figure 6i records the propagation signals under different pressing forces in the same position. An increased reflection was observed as the pressing force gets larger. Besides sensing the pressing force, the pressing position was also be reflected in the propagation signal. As shown in Fig. 6j, the pressing position was distinguished by the time point of the partial reflection. Finally, an electronic textile was demonstrated based on a single transmission line (Fig. 6k). Both the pressing force and position were monitored and visualized simultaneously. This demonstration reveals the application prospect of this multimodal deformation sensor in wearable devices and robotic skins.
Through functionalizing the pre-elastomer, large-area display textile was achieved recently [34]. As sketched in Fig. 6l, ionic-liquid-doped polyurethane gel was employed to form the transparent conductive weft fibers and ZnS phosphor dispersed in an insulating polymer matrix (polyurethane) was coated on conductive yarns serving as luminescent warp fibers. A display textile was thus woven with microscale electroluminescent (EL) units at the weft-warp contact points. Figure 6m shows a 6-m-long display textile consisting of approximately 5 × 105 EL units. And multicolor soft display textile was fabricated by altering the EL units (Fig. 6n, p). This weaving strategy was proven to be general by integrating fibers with other electronic functions into the same textile. This integrated textile could also be used as a wearable communication tool and interact with a handphone supported by the keyboard and Bluetooth module (Fig. 6o). It reveals great potential in various areas including Internet of Things. And the ability of this approach for fabrication and integration of different electronic functions is expected to shape the next-generation electronics.
Conclusions and Outlook
Enabled by the traditional fiber manufacturing industry, elastic and stretchable fiber has been developed in both material exploration and fabrication approach innovation. A series of remarkable applications, involving biomedicine, optics, electronics, human machine interfaces etc., have been successfully achieved. All these reported applications (implantable in vivo biomedical sensing, innervated prosthetic robotic hand, distributed probes of multimodal deformations and large-area display textiles integrated with functional system) indicate that the fast innovated interdisciplinary area is of great potential. Nevertheless, the study of the material system of elastomer fibers is still at the initial stage, and there is broad space to be explored. Towards material innovation, extensive functional materials could be designed and synthesized to meet different requirements of various fabrication methods. For example, hydrogels which could maintain a proper viscosity for thermally drawing could then be developed by studying the chemical synthesis process. Hydrophilic and hydrophobic segments could be designed to the polymer chain structure to further form a stretchable hydrophilic or hydrophobic fiber. Fibers with more functionalities could be expected through investigating the surface modification and functional structure design inside the fiber [72]. For example, recently a direct imprinting method was developed to print functional patterns on fiber surface [6]. And some metastructures could be introduced into the fiber to obtain special optical function. Thus, these special functionalities can be implemented to more application scenarios through the elastic fiber devices. And more integrated fiber systems consisting of signal sensing, information transferring, and human machine interaction could be developed to include more functions by engaging other research fields from integrated circuits, data analysis, and mechanical design [73] (e.g., triboelectric nanogenerator system based on elastic fibers [74, 75]). More inspiring elastic and stretchable fiber-based work can be expected resting at the cross-section of many disciplines ranging from soft electronics, multi-functional sensing, energy harvesting, data science, to scalable manufacturing.
References
Xiong J., Lee P. S. Progress on wearable triboelectric nanogenerators in shapes of fiber, yarn, and textile. Sci. Technol. Adv. Mater. 2019, 20, 837.
Dong K., Peng X., Wang Z. L. Fiber/fabric‐based piezoelectric and triboelectric nanogenerators for flexible/stretchable and wearable electronics and artificial intelligence. Adv. Mater. 2020, 32, 1902549.
Yan W., Richard I., Kurtuldu G., James N. D., Schiavone G., Squair J. W., Nguyen‐Dang T., Das Gupta T., Qu Y., Cao J. D , Ignatans R., Lacour S. P., Tileli V., Courtine G., Löffler J. F., Sorin F. Structured nanoscale metallic glass fibres with extreme aspect ratios. Nat. Nanotech. 2020, 15, 875.
Zhang J., Zhang T., Zhang H., Wang Z., Li C., Wang Z., Li K., Huang X., Chen M., Chen Z. Single‐crystal SnSe thermoelectric fibers via laser‐induced directional crystallization: from 1D fibers to multidimensional fabrics. Adv. Mater. 2020, 32, 2002702.
Yang Z., Ren J., Zhang Z., Chen X., Guan G., Qiu L., Zhang Y., Peng H. Recent advancement of nanostructured carbon for energy applications. Chem. Rev. 2015, 115, 5159.
Wang Z., Wu T., Wang Z., Zhang T., Chen M., Zhang J., Liu L., Qi M., Zhang Q., Yang J. Designer patterned functional fibers via direct imprinting in thermal drawing. Nat. Commun. 2020, 11, 1.
Yan W., Page A., Nguyen-Dang T., Qu Y., Sordo F., Wei L., Sorin F. Advanced multimaterial electronic and optoelectronic fibers and textiles. Adv. Mater. 2019, 31, 1802348.
Loke G., Yan W., Khudiyev T., Noel G., Fink Y. Recent progress and perspectives of thermally drawn multimaterial fiber electronics. Adv Mater. 2020, 32, 1904911.
Yan W., Qu Y., Gupta T. D., Darga A., Nguyên D. T., Page A. G., Rossi M., Ceriotti M., Sorin F. Semiconducting nanowire-based optoelectronic fibers. Adv. Mater. 2017, 29, 1700681.
Frank J. A., Antonini M.-J., Anikeeva P. Next-generation interfaces for studying neural function. Nat. Biotechnol. 2019, 37, 1013.
Qi M., Zhang N. M. Y., Li K., Tjin S. C., Wei L. Hybrid plasmonic fiber-optic Sensors. Sensors. 2020, 20, 3266.
Yan W., Dong C., Xiang Y., Jiang S., Leber A., Loke G., Xu W., Hou C., Zhou S., Chen M. Thermally drawn advanced functional fibers: new frontier of flexible electronics. Mater. Today. 2020, 35, 168.
Dong C., Page A. G., Yan W., Nguyen-Dang T., Sorin F. Microstructured multimaterial fibers for microfluidic sensing. Adv. Mater. Technol. 2019, 4, 1900417.
Sun H., You X., Jiang Y., Guan G., Fang X., Deng J., Chen P., Luo Y., Peng H. Self-healable electrically conducting wires for wearable microelectronics. Angew. Chem. Int. Ed. 2014, 53, 9526.
Yu D., Goh K., Wang H., Wei L., Jiang W., Zhang Q., Dai L., Chen Y. Scalable synthesis of hierarchically structured carbon nanotube-graphene fibres for capacitive energy storage. Nat. Nanotech. 2014, 9, 555.
Sun H., Zhang Y., Zhang J., Sun X., Peng H. Energy harvesting and storage in 1D devices. Nat. Rev. Mater. 2017, 2, 17023.
Liao M., Ye L., Zhang Y., Chen T., Peng H. The recent advance in fiber-shaped energy storage devices. Adv. Electron. Mater. 2019, 5, 1800456.
Zhou Y., Wang C.-H., Lu W., Dai L. Recent advances in fiber-shaped supercapacitors and lithium-ion batteries. Adv Mater. 2020, 32, 1902779.
Yang S., Macharia D. K., Ahmed S., Zhu B., Zhong Q., Wang H., Chen Z. Flexible and reusable non-woven fabric photodetector based on polypyrrole/crystal violate lactone for NIR light detection and writing. Adv. Fiber Mater. 2020, 2, 150.
Wei L. Advanced Fiber Sensing Technologies. Springer; 2020.
Wang L., Fu X., He J., Shi X., Chen T., Chen P., Wang B., Peng H. Application challenges in fiber and textile electronics. Adv. Mater. 2020, 32, 1901971.
Weng W., Yang J., Zhang Y., Li Y., Yang S., Zhu L., Zhu M. A route toward smart system integration: from fiber design to device construction. Adv. Mater. 2020, 32, 1902301.
Chen T., Hao R., Peng H., Dai L. High-performance, stretchable, wire-shaped supercapacitors. Angew. Chem. In.t Ed. 2015, 54, 618.
Sun H., Xie S., Li Y., Jiang Y., Sun X., Wang B., Peng H. Large-area supercapacitor textiles with novel hierarchical conducting structures. Adv. Mater. 2016, 28, 8431.
Shi Q., Sun J., Hou C., Li Y., Zhang Q., Wang H. Advanced functional fiber and smart textile. Adv. Fiber Mater. 2019, 1, 3.
Gao P., Li J., Shi Q. A hollow polyethylene fiber-based artificial muscle. Adv. Fiber Maters. 2019, 1, 214.
Li J., Sun J., Wu D., Huang W., Zhu M., Reichmanis E., Yang S. Functionalization-directed stabilization of hydrogen-bonded polymer complex fibers: elasticity and conductivity. Adv. Fiber Mater. 2019, 1, 71.
Chen J., Pakdel E., Xie W., Sun L., Xu M., Liu Q., Wang D. High-performance natural melanin/poly(vinyl alcohol-co-ethylene) nanofibers/PA6 Fiber for twisted and coiled fiber-based actuator. Adv. Fiber Mater. 2020, 2, 64.
Leber A., Cholst B., Sandt J., Vogel N., Kolle M. Stretchable thermoplastic elastomer optical fibers for sensing of extreme deformations. Adv. Funct. Mater. 2019, 29, 1802629.
Cooper C. B., Arutselvan K., Liu Y., Armstrong D., Lin Y., Khan M. R., Genzer J., Dickey M. D. Stretchable capacitive sensors of torsion, strain, and touch using double helix liquid metal fibers. Adv. Funct Mater. 2017, 27, 1605630.
Tong Y., Feng Z., Kim J., Robertson J. L., Jia X., Johnson B. N. 3D printed stretchable triboelectric nanogenerator fibers and devices. Nano Energy. 2020, 104973.
Xu P. A., Mishra A. K., Bai H., Aubin C. A., Zullo L., Shepherd R. F. Optical lace for synthetic afferent neural networks. Sci. Robot. 2019, 4, 34.
Zhang Q., Li L., Li H., Tang L., He B., Li C., Pan Z., Zhou Z., Li Q., Sun J. Wei L., Fan X., Zhang T., Yao Y. Ultra-endurance coaxial-fiber stretchable sensing systems fully powered by sunlight. Nano Energy. 2019, 60, 267.
Peng H., Shi X., Zuo Y., Zhai P., Shen J., Yang Y., Gao Z., Liao M., Wang J., Xu X. Large-area display textiles integrated with functional systems. 2020. DOI: https://doi.org/10.21203/rs.3.rs-56463/v1.
Qu Y., Nguyen‐Dang T., Page A. G., Yan W., Das Gupta T., Rotaru G. M., Rossi R. M., Favrod V. D., Bartolomei N., Sorin F. Superelastic multimaterial electronic and photonic fibers and devices via thermal drawing. Adv. Mater. 2018, 30, 1707251.
Yu L., Parker S., Xuan H., Zhang Y., Jiang S., Tousi M., Manteghi M., Wang A., Jia X. Flexible multi‐material fibers for distributed pressure and temperature sensing. Adv. Funct. Mater. 2020, 30, 1908915.
Leber A., Dong C., Chandran R., Gupta T. D., Bartolomei N., Sorin F. Soft and stretchable liquid metal transmission lines as distributed probes of multimodal deformations. Nat. Electron. 2020, 1, 11.
Zhao H., O’Brien K., Li S., Shepherd R. F. Optoelectronically innervated soft prosthetic hand via stretchable optical waveguides. Sci. Robot. 2016, 1, eaai7529.
Chang-Yen D. A., Eich R. K., Gale B. K. A monolithic PDMS waveguide system fabricated using soft-lithography techniques. J. Lightwave Technol. 2005, 23, 2088.
Kee J. S., Poenar D. P., Neuzil P., Yobas L. Design and fabrication of poly (dimethylsiloxane) single-mode rib waveguide. Opt. Express. 2009, 17, 11739.
Cai Z., Qiu W., Shao G., Wang W. A new fabrication method for all-PDMS waveguides. Sens. Actuators A: Physical. 2013, 204, 44.
Missinne J., Kalathimekkad S., Van Hoe B., Bosman E., Vanfleteren J., Van Steenberge G. Stretchable optical waveguides. Opt. Express. 2014, 22, 4168.
Guo J., Niu M., Yang C. Highly flexible and stretchable optical strain sensing for human motion detection. Optica. 2017, 4, 1285.
Guo J., Zhou B., Yang C., Dai Q., Kong L. Stretchable and temperature‐sensitive polymer optical fibers for wearable health monitoring. Adv. Funct. Mater. 2019, 29, 1902898.
Elmogi A., Bosman E., Missinne J., Van Steenberge G. Comparison of epoxy-and siloxane-based single-mode optical waveguides defined by direct-write lithography. Opt. Mater. 2016, 52, 26.
Choi M., Humar M., Kim S., Yun S. H. Step‐index optical fiber made of biocompatible hydrogels. Adv. Mater. 2015, 27, 4081.
Guo J., Liu X., Jiang N., Yetisen A. K., Yuk H., Yang C., Khademhosseini A., Zhao X., Yun S. H. Highly stretchable, strain sensing hydrogel optical fibers. Adv. Mater. 2016, 28, 10244.
Yetisen A. K., Jiang N., Fallahi A., Montelongo Y., Ruiz‐Esparza G. U., Tamayol A., Zhang Y. S., Mahmood I., Yang S. A., Kim K. S. Glucose‐sensitive hydrogel optical fibers functionalized with phenylboronic acid. Adv. Mater. 2017, 29, 1606380.
Zhu S., So J. H., Mays R., Desai S., Barnes W. R., Pourdeyhimi B., Dickey M. D. Ultrastretchable fibers with metallic conductivity using a liquid metal alloy core. Adv. Funct. Mater. 2013, 23, 2308.
Lu C., Park S., Richner T. J., Derry A., Brown I., Hou C., Rao S., Kang J., Moritz C. T., Fink Y., Anikeeva P. Flexible and stretchable nanowire-coated fibers for optoelectronic probing of spinal cord circuits. Sci. Adv. 2017, 3, e1600955.
Manocchi A. K., Domachuk P., Omenetto F. G., Yi H. Facile fabrication of gelatin‐based biopolymeric optical waveguides. Biotechnol. Bioeng. 2009, 103, 725.
Sordo F., Janecek E. R., Qu Y., Michaud V., Stellacci F., Engmann J., Wooster T. J., Sorin F. Microstructured fibers for the production of food. Adv. Mater. 2019, 31, 1807282.
Qin H., Owyeung R. E., Sonkusale S. R., Panzer M. J. Highly stretchable and nonvolatile gelatin-supported deep eutectic solvent gel electrolyte-based ionic skins for strain and pressure sensing. J. Mater. Chem. C. 2019, 7, 601.
Shan D., Zhang C., Kalaba S., Mehta N., Kim G. B., Liu Z., Yang J. Flexible biodegradable citrate-based polymeric step-index optical fiber. Biomaterials. 2017, 143, 142.
Nizamoglu S., Gather M. C., Humar M., Choi M., Kim S., Kim K. S., Hahn S. K., Scarcelli G., Randolph M., Redmond R. W. Bioabsorbable polymer optical waveguides for deep-tissue photomedicine. Nat. Commun. 2016, 7, 1.
Fu R., Luo W., Nazempour R., Tan D., Ding H., Zhang K., Yin L., Guan J., Sheng X. Implantable and biodegradable poly (l‐lactic acid) fibers for optical neural interfaces. Adv. Opt. Mater. 2018, 6, 1700941.
Parker S. T., Domachuk P., Amsden J., Bressner J., Lewis J. A., Kaplan D. L., Omenetto F. G. Biocompatible silk printed optical waveguides. Adv. Mater. 2009, 21, 2411.
Huby N., Vié V., Renault A., Beaufils S., Lefevre T., Paquet-Mercier F., Pézolet M., Bêche B. Native spider silk as a biological optical fiber. Appl. Phys. Lett. 2013, 102, 123702.
Applegate M. B., Perotto G., Kaplan D.L., Omenetto F. G. Biocompatible silk step-index optical waveguides. Biomedical. Opt. express. 2015, 6, 4221.
Chen G., Matsuhisa N., Liu Z., Qi D., Cai P., Jiang Y., Wan C., Cui Y., Leow W. R., Liu Z. Plasticizing silk protein for on‐skin stretchable electrodes. Adv. Mater. 2018, 30, 1800129.
Loke G., Yan W., Khudiyev T., Noel G., Fink Y. Recent progress and perspectives of thermally drawn multimaterial fiber electronics. Adv. Mater. 2019, 1904911.
Loke G., Yuan R., Rein M., Khudiyev T., Jain Y., Joannopoulos J., Fink Y. Structured multimaterial filaments for 3D printing of optoelectronics. Nat. Commun. 2019, 10, 4010.
Yang Z., Deng J., Sun X., Li H., Peng H. Stretchable, wearable dye‐sensitized solar cells. Adv. Mater. 2014, 26, 2643.
Yang Z., Deng J., Chen X., Ren J., Peng H. A highly stretchable, fiber-shaped supercapacitor. Angew. Chem. Int. Ed. 2013, 52, 13453.
Sun H., Fu X., Xie S., Jiang Y., Peng H. Electrochemical capacitors with high output voltages that mimic electric eels. Adv. Mater. 2016, 28, 2070.
Guo J., Zhou B., Zong R., Pan L., Li X., Yu X., Yang C., Kong L., Dai Q. Stretchable and highly sensitive optical strain sensors for human-activity monitoring and healthcare. ACS Appl. Mater. Interfaces. 2019, 11, 33589.
Sim H. J, Lee D. Y, Kim H., Choi Y.-B., Kim H.-H., Baughman R. H., Kim S. J. Stretchable fiber biofuel cell by rewrapping multiwalled carbon nanotube sheets. Nano Lett. 2018, 18, 5272.
Zhang B., Lei J., Qi D., Liu Z., Wang Y., Xiao G., Wu J., Zhang W., Huo F., Chen X. Stretchable conductive fibers based on a cracking control strategy for wearable electronics. Adv. Funct. Mater. 2018, 28, 1801683.
Wang L., Xie S., Wang Z., Liu F., Yang Y., Tang C., Wu X., Liu P., Li Y., Saiyin H., Zheng S., Sun X., Xu F., Yu H., Peng H. Functionalized helical fibre bundles of carbon nanotubes as electrochemical sensors for long-term in vivo monitoring of multiple disease biomarkers. Nat. Bio. Eng. 2020, 4, 159.
Yang X., Li L., Yang D., Nie J., Ma G. Electrospun core-Shell fibrous 2D scaffold with biocompatible poly(glycerol sebacate) and poly-l-lactic acid for wound healing. Adv. Fiber Mater. 2020, 2, 105.
Heo Y. J., Shibata H., Okitsu T., Kawanishi T., Takeuchi S. Long-term in vivo glucose monitoring using fluorescent hydrogel fibers. Proc. Natl. Acad. Sci. 2011, 108, 13399.
Xu B., Ma S., Xiang Y., Zhang J., Zhu M., Wei L., Tao G., Deng D. In-Fiber structured particles and filament arrays from the perspective of fluid instabilities. Adv. Fiber Mater. 2020, 2, 1.
Kanik M., Orguc S., Varnavides G., Kim J., Benavides T., Gonzalez D., Akintilo T., Tasan C. C., Chandrakasan A. P., Fink Y., Anikeeva P. Strain-programmable fiber-based artificial muscle. Science. 2019, 365, 145.
Feng Z., Yang S., Jia S., Zhang Y., Jiang S., Yu L., Li R., Song G., Wang A., Martin T., Zuo L., Jia X. Scalable, washable and lightweight triboelectric-energy-generating fibers by the thermal drawing process for industrial loom weaving. Nano Energy. 2020, 74, 104805.
Dong C., Leber A., Das Gupta T., Chandran R., Volpi M., Qu Y., Nguyen-Dang T., Bartolomei N., Yan W., Sorin F. High-efficiency super-elastic liquid metal based triboelectric fibers and textiles. Nat. Commun. 2020, 11, 3537.
Acknowledgements
This work was supported by the Singapore Ministry of Education Academic Research Fund Tier 2 (MOE2019-T2-2-127 and T2EP50120-0005), A*STAR under AME IRG (A2083c0062), the Singapore Ministry of Education Academic Research Fund Tier 1 (RG90/19 and RG73/19) and the Singapore National Research Foundation Competitive Research Program (NRF-CRP18-2017-02). This work was also supported by Nanyang Technological University.
Author information
Authors and Affiliations
Corresponding authors
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Rights and permissions
About this article
Cite this article
Chen, M., Wang, Z., Li, K. et al. Elastic and Stretchable Functional Fibers: A Review of Materials, Fabrication Methods, and Applications. Adv. Fiber Mater. 3, 1–13 (2021). https://doi.org/10.1007/s42765-020-00057-5
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s42765-020-00057-5