Abstract
This study presents the new petrology and geochemistry data for the comprehension of the origin and emplacement conditions of the Lolodorf mafic rocks whitin the Nyong Complex. The meta-mafic rocks consist of fine-grained garnet meta-mafic (FGM) and coarse-grained garnet meta-mafic (CGM) rocks presenting nearly similar mineral composition. They are made up of quartz, plagioclase, garnet orthopyroxene, clinopyroxene, amphibole, opaques, apatite and rutile. They also present recrystallization features such as quartz ribbons, corroded grain mineral, cuspate plagioclase boundary and necklace garnets in the matrix. These mineral assemblages suggest that the recrystallization took place under granulite facies condition. The meta-mafic rocks have basaltic and tholeiitic composition like the magmas (SiO2 FGM = 48.20–50.70 wt% and SiO2CGM = 46.68–50.27 wt% and MgFGM = 43.24–62.27 and MgCGM = 40.85–69.70) emplaced in the active continental margin context. The low La/Th ratio observed in the FGM and the high La/Th ratio in the CGM together with low Hf content imply that the FGM are reworked plutonic rocks that recorded both high grade partial melting and metamorphism whereas CGM recorded only metamorphism imprints. Thermobarometry results suggest that the partial melting and metamorphic peak occurred around the amphibolite-granulite facies transition. The fine-grained garnet meta-mafic rocks emplaced under pressure estimated at around 2.7–14.89 kbar with temperature interval between 672 and 952 °C while the coarse-grained garnet meta-mafics settled at around 1.5–16.09 kbar and 631–909 °C. The selected amphiboles display low water content (1.92–2.10 wt%) and plot between NNO and NNO + 2 buffers indicating that they crystallized under high oxidizing conditions. These results coupled with previous geochronological study suggest that the FGM may have occurred at the Mesoarchean and have been reworked during Eburnean whereas the CGM may have been formed at the Eburnean.
Highlights
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(1)
The rocks of the study area consists of fine-grained garnet meta-mafic (FGM) and coarse-grained garnet meta-mafic (CGM) rocks presenting partial melting and metamorphic features characterizing the amphibolite-granulite facies transition;
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(2)
Fine-grained garnet meta-mafic (FGM) have been reworked during Eburnean whereas coarse-grained garnet meta-mafic (CGM) formed at the Eburnean;
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(3)
The partial melting and metamorphic peak occurred around the amphibolite-granulite facies transition between 2.7–14.89 kbar and 672–952 °C for the FGM and around 1.5–16.09 kbar and 631–909 °C for the CGM.
Meta-mafic rocks protolith displays basaltic composition and emplaced at an active continental margin context under high oxidizing conditions.
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1 Introduction
Mafic rocks are volumetrically minor components of old Precambrian terranes that have provided important tools or contributions to the understanding of the geodynamic processes during early times [1,2,3,4]. Furthermore, the mafic rocks as well as large volume of Archean and Proterozoic continental crusts that are affected by partial melting are of much concern for modelling the evolution of recycled Archean continental crust. However, most of individual occurrences of these mafic rocks are attributed to wide-ranging geodynamic context. (1) Precambrian remnants of ophiolites or eclogites or (2) intrusive mafic layers which are often linked to a range of geodynamic context; (3) sills belonging to an oceanic crust in subduction environments; (4) remnants of arc related oceanic crust; (5) remnants of greenstone belts which have sagducted and (6) residual mantle following high degree of partial melting [5,6,7,8,9]. Particularly, controversy exists about the geodynamic context of mafic rocks generations during the Paleoproterozoic time [10, 11]. Two interpretation models have been proposed. First, there is evidence that in many Paleoproterozoic high grade belts, shortening is accommodated by the distributed thickening without real evidence for large-scale thrusting [12,13,14]. Second, the existence of Paleoproterozoic eclogites interpreted as suture zones indicated that subduction and Phanerozoic or ‘modern’ plate tectonic processes have played since that time [15, 16]. Most of geochemical finger printings in the Paleoproterozoic times are framed in the Phanerozoic tectonic [1, 2, 17]. They are the relative depletion of HFSE (Ta, Nb, Ti, Zr and Hf) on normalised trace element plots of these mafic rocks and the local observation of high pressure meta-mafics so called eclogite relics. Theses finger prints are often widely used as evidence for subduction similar, to that observed in the Phanerozoic arc magmatic area [18,19,20,21,22]. Furthermore, metasomatism and hydrothermal processes can mobilize HFSE and REE, which are typically thought to be immobile [23,24,25]. The occurrence of high-pressure rocks without thrust tectonics can be derived both by virtue homogeneous crustal thickening [3, 26, 27] and during extensional context. Despite these findings, caution is advised when using the HFSE anomaly because it can also be caused by interaction with the Sub-Continental Lithospheric Mantel (SCLM) [28] or via crustal contamination [29]. The occurrence of high-pressure rocks does not necessarily imply thrust-dominated tectonics [3]. The Cameroon Craton represents the northern edge of the Congo Craton. It consists of the Ntem complex (NC) and the Nyong complex (NyC) (Fig. 1b, c; [30,31,32,33]). The NyC records the Eburnean orogeny that occurred during the collision between the Congo and So Francisco shields (Fig. 1c; [32, 34,35,36]). The Lolodorf area which is part of the NyC appears as an islet not yet been studied. In this study, the meta-mafic rocks from Lolodorf give an opportunity to assess new petrographical, mineralogical and geochemical data to understand the origin and evolution of the meta-mafic rocks protolith.
2 Geological setting
The Eburnean orogeny in Cameroon includes the NyC [33, 38] along the NW boundary of the with NC [33, 38, 39] and Ayna series [40, 41]. However, this Eburnean orogeny has been recorded out of the NyC notably in the Adamawa-Yade domain which appears as relics within the late Neoproterozoic Panafrican fold belt [42,43,44]. Biotite-hornblende gneiss, commonly known as grey gneiss (or migmatic grey gneiss) of TTG composition, is found in the NyC lithological formations [45,46,47]. Moreover, orthopyroxene-garnet gneiss with charnockite composition, garnet-amphibole pyroxenites (metabasites interpreted as remnant eclogitic bodies) [20,21,22, 48], banded iron formation and magmatic rocks more or less metamorphosed (charnockite, augen metadiorite, metasyenite, granite and dolerite; [35, 37]). These sedimentary and plutonic rocks were remobilized during the Eburnean/Trans Amazonian orogeny due to the collision between the Congo and São Francisco Shields (Fig. 1b; [32, 34, 43]). The field observations and the geochemistry analyses support the derivation of the NyC rocks from the partial melting of the Archean crust [46, 47, 49]. The NyC is mostly characterized by flat lying foliation associated with stretching lineation variably oriented and resulting from the transposition of primary foliation by isoclinal recumbent folds during the second phase of deformation. Locally, large opening folds associated with shear zones disrupt this foliation [35, 44]. The NyC is marked by polycyclic metamorphic evolution with eclogite facies [20, 21] characterized by two deformation phases, synchronous with the emplacement of charnockite and/or migmatization process near the boundary with the NC. It is also marked by high grade granulitic assemblages characterized by polygonal fine-grained quartzo-feldspathic minerals suggesting the recrystallization process under high temperature and by the presence of corona rims illustrating a static evolution under granulite to amphibolite facies conditions [50, 51]. From eclogite phase, retrogressive phases continue down to greenschist facies conditions locally overprinted [40, 47]. Previous works on the NyC suggested that the second phase of deformation is retrograde and belongs to the Eburnean nappe formations which were transported eastward onto the NC under the amphibolitic condition [33] and dated at ca 2050 Ma [34, 40, 46]. The critical isotopic data (Sm–Nd and TDM data [46, 49]) indicate that the Nyong rocks have protolith with both an Archean age and the contribution of juvenile mantle materials. Due to the fact that the eclogitic metamorphism has been dated at ca 2.09 Ma ([20], SHRIMP U–Pb/Zr), the NyC area has been considered as one of the oldest suture zone or subducted slab so far recorded in the world [20]. The rocks of the NyC have also experienced a major late migmatitic, granulitic and tectonic events at ca 2.05 Ga ([37] by SHRIMP U–Pb/Zr) and may be therefore interpreted as a proximal area characterized by reworking and recycling of adjacent Archean cratonic crust [35].
3 Analytical techniques
3.1 Mineral chemistry
Six (06) polished thin sections of the meta-mafic rocks from the Lolodorf region were examined in detail under the polarizing microscope to identify the mineral assemblages. The observed mineral assemblages were imaged and mineral compositions measured using a JOEL JXA 8230 electron microprobe at the Advanced Facility for Microscopy and Microanalysis (AFMM) of the Indian Institute of Science in Bangalore, India. Analytical conditions used were 15 kv, with 12 nA sample current and a beam width of 3 µm. Count times for the major elements were 10 s on peaks and 5 s on each background. Natural silicate and oxide minerals were used for calibration. Data were processed with a ZAF-type correction.
3.2 Whole rock geochemistry
Geochemical analysis of 14 samples was done using Inductively Coupled Plasma-Atomic Emission (ICP-AE) for major elements and Inductively Coupled Plasma Mass Spectrometry (ICP-MS) for trace elements including REE at the ALS Mineral Global Group, Vancouver (Canada). Sample preparation, analytical conditions and limits of detection are detailed in [52]. Major oxides and CIPW Norms are listed in Table 1, while trace elements and REE compositions are presented in Table 3. The CIPW norms were obtained using Excel spreadsheet program rewritten by [53].
4 Results
4.1 Petrography
Meta-mafic rocks of the Lolodorf area occur as enclaves within charnockitic gneisses (Fig. 2). They are represented by small bodies (Fig. 3a); plugs (15 to 20 m, Fig. 3d); dykes/sills (~ 100–200 m length and 2–8 m width) and small lenses. They are melanocratic, fine to coarsed-grained and locally bear steep and flat foliations (Fig. 3a and c). At the mesoscale, they display in places, alternation of dark mafic and white felsic layers (Fig. 3a-c) or banding structures. The grain size distribution and melt segregation allow to classify into fine-grained garnet bearing meta-mafic (FGM) and coarse-grained garnet bearing meta-mafic (CGM) rocks (Fig. 3d, e).
The meta-mafics rocks display melt segregation (Fig. 3b, c) where quartz-plagioclasic phases are associated locally with garnet, amphibole and pyroxene. Locally, tiny leucosome pockets occur within the residual phase (Fig. 3).
They are mainly composed of garnet, clinopyroxene and amphibole (Fig. 3). Minor quartz and plagioclase are also observed in the hand-specimen. At the microscopic scale, the CGM display a granoblastic texture with heterogranular tendency (Fig. 4a, b) and granoporphyroblastic texture (Fig. 4c, d). They are mainly made up of garnet, clinopyroxene, amphibole, plagioclase, quartz, ilmenite, magnetite, apatite and rutile. The mineral distributions show a compositional variation from leucosome to melanosome bands or pockets (Fig. 4a, b). The leucosome is mainly composed of quartz-plagioclase aggregates, sometimes crosscut by transgranular fracture filled with quartz monocrystals (Fig. 4b, c). Clusters of fine garnet and orthopyroxene (Fig. 4c, d) are often present in the quartz-plagioclase aggregates. The melanosome phase consists of subhedral garnet phenocrystals (Fig. 4d, e and g, h), orthopyroxene, amphibole (Fig. 4e, f) and clinopyroxene, in places fractured (Fig. 4e). Ilmenite and magnetite are more abundant only within the residual phase (Figs. 2, 4a). Inclusions of garnet, quartz and plagioclase are present in the garnet and clinopyroxene cores (Fig. 4g–i). In place garnet crystals are drowned in quartzoplagioclasic matrix (Fig. 4f). Some garnets are surrounded by reactionary rim. They are also associated with amphibole (Fig. 4f) and clinopyroxenes (Fig. 4i, j). Broken garnet necklaces are also found around the plagioclase (Fig. 4e, f) and display fractures filled with quartzofeldspathic phase which seals the two entities (Fig. 4k). Clinopyroxene is surrounded by corona of green amphibole (Fig. 4f, h, i) and displays straight boundary near the plagioclase crystal faces (Fig. 4h, i). Amphiboles are represented by brown–red and green types. Brown–red amphibole consints of large crystal grain up to 2 mm long, strongly pleochroic and showing in places quartz and plagioclase inclusions. Green amphibole also appears both as lamellae exsolution and as a rim around orthopyroxene and clinopyroxene crystals (Fig. 4f–j). Plagioclase occurs as subhedral to anhedral crystal in the matrix along with quartz and garnet (Fig. 4f). The orthopyroxene-plagioclase symplectite occurs between quartz and garnet crystals (Fig. 4g, i, j).
4.2 Mineral chemistry
Garnet, clinopyroxenes, orthopyroxenes, amphiboles and plagioclases are the analyzed mineral phases in this study. Garnet contains 17–63 mol% almandine, 17–82 mol% grossular, 0–27 mol% pyrope and 0–0.05 mol% spessartine with XMg number ranging from 0 to 0.36 (Supplementary file). Clinopyroxene contains 29.57–97.02 mol% wollastonite, 0–42.20 mol% enstatite and 2.98–19.31 mol% ferrosilite. In the binary Q-J diagram, all pyroxenes plot in the quad field (Fig. 5a). Clinopyroxenes are mainly diopsidic in nature and are locally augite and wollastonite. Primary diopside and Augite are Al2O3 rich in their cores and decrease rimward from 8.69 to 1.73 for diopside and from 8.07 to 2.33 wt% for augite. They display 0.00 to 18.90 mol% jadeite with high values in the core. Orthopyroxene is clinoenstatite (Fig. 5b) with 0.85 mol% wollastonite, 52.94 mol% enstatite and 46.21 mol% ferrosilite (Supplementary file).
Amphiboles are calcic with Ca values ranging from 1.58 to 1.90 p.f.u., Na ranging from 0.19 and 0.78 p.f.u., and K values between 0.05 and 0.18 p.f.u. (Supplementary file). The primary amphiboles are Ti–rich with values ranging between 0.20 and 0.27 p.f.u., whereas the secondary amphiboles are Ti-poor (Ti = 0.03–0.18 p.f.u.). According to the classification of [54], these calcic amphiboles are represented by pargasite, magnesiohornblende and tschermakite end-members (Fig. 5c). The FGG (MO 33 and MO 47) samples are mainly composed of tschermakite and magnesiohornblende whereas the CGG (MO31 and MO 57) samples are composed of pargasite, magnesiohornblende and tschermakite (Fig. 5c).
Plagioclases contain 0.00–74.59 mol% albite, 25.17–100 mol% anorthite and 0.00–2.69 mol% orthoclase and consist of anorthite, bytownite, andesine and oligoclase end members (Fig. 5d). Anorthite contains increase rimward from oligoclase to anorthite end members.
4.3 Thermobarometry, oxygen fugacity and water content estimates
The Grt-Cpx calibration of [56] is considered as the most accurate thermometer in the amphibolite-granulite-facies transition zone [57]. Using the Cpx-Grt assemblage, the thermometer yields average temperature of 766, 710 and 805 °C (Table 1) respectively for the MO 31, MO 33 and MO 47, all belonging to the FGM. The Hbl-Pl assemblage allows using equation from [58] that is based on edenite-tremolite reaction. According to this thermometer at high pressure condition of 10 kbar, the FGM (MO 31) sample displays temperatures ranging between 692 and 759 °C; with average temperature of 736 °C (Table 1). In the FGM (MO 33) sample, temperatures are ranged between 751 and 806 °C; with an average temperature of 778 °C (Table 1). Considering low pressure condition of 5 kbar, temperatures are similar to those obtained during high pressure condition (10 kbar and in the CGM) whereas, in the FGM (MO 33), temperatures are higher in low pressure conditions than those obtained in the high pressure conditions (Table 1). As shown above, Grt-Hbl assemblage also has been used to calculate temperatures of anatectic melt. Calculation made using the calibration of [59] yielded a mean temperature estimate around 862, 784 and 828 °C in the FGM (MO 31, MO 33 and MO 47) samples respectively (Table 1). The barometer of [60] constrained in the FGM (MO 31, MO 33 and MO 47) samples yields a mean pressure estimate around 9.7, 13.4 and 9.1 kbar respectively (Table 1). Overall, the temperatures and pressures calculated above suggested P–T conditions of Cpx + Grt + Hbl + Pl range respectively between 9.1–13.4 kbar; and 710–862 °C. Such temperatures have widely varying oxygen fugacities (20.48–11.02 atm, pressures calculated after [61] in the equation of [62] (logfO2 = − 30,930/T + 14.98 + 0.142(P − 1)/T; T in °K and P in bar (Supplementary file). Amphiboles are generally used as good proxy to understand the oxidation states of their host magma [63]. When plotted on the temperature versus log f(O2) diagram, the selected amphiboles from the present study fall in the NNO and NNO + 2 buffers. The FGM crystallized between 11.69 and 15.92 atm and the CGM between 13.12 and 15.15 atm (Supplementary file, Fig. 6b). On the AlIV versus Fe/Fe + Mg diagram (Fig. 6a) (stability field after [64]), both the FGM and CGM show a high oxygen fugacity. [69] demonstrated that The AlVI content of amphiboles is sensitive to water content in the magma and then can be used for the estimation of the stability field of amphibole crystallization. Using the hygrometric formulation after [65] for the selected amphiboles, the calculation gave the value ranging from 1.92 to 2.10 wt% for the FGM and 2.02 to 2.06 wt% for the CGM (Fig. 6b, Supplementary file).
4.4 Whole rock geochemistry
4.4.1 Major elements
The major and trace element compositions of the studied granulites are reported on Table 2. The granulites display low SiO2 (48.20–50.70 wt% for the FGM and 46.68–50.27 wt% for the CGM) and P2O5 (0.05–0.26 wt% for the FGM and 0.04–0.13 wt% for the CGM) contents, high TiO2 (0.78–1.72 wt% for the FGM and 0.36–1.48 wt% for the CGM), CaO (9.17–11.81 wt% for the FGM and 9.72–13.84 wt% for the CGM), Fe2O3 (12.65–17.65 wt% for the FGM and 11.98–18.32 wt% for the CGM) and MgO (5.77–8.96 wt% for the FGM and 5.43–12.04 wt% for the CGM) contents. Al2O3 content shows a narrow range between 12.40 and 14.63 wt% for the FGM and 12.41 and 14.57 wt% for the CGM. The samples display a variable Mg number (Mg = 100 × (MgO/40.31)/[(MgO/40.31) + ((Fe2O3 × 0.8998)/71.85 × (1–0.15))]) raging from 43.24 to 62.27 of the FGM and 40.85 to 69.70 of the CGG (Table 2). The loss on ignition is low (LOI < 0.75wt%), attesting to the freshness of the collected samples. Most of sample display high Na2O/K2O and Al2O3/TiO2 ratios, 4.63–32 and 7.25–37.64 respectively. The FGM and the CGM are basaltic in composition as observed from their plots on the total alkali (Na2O + K2O) versus silica (SiO2) (TAS) diagram (Fig. 7a). Moreover, most of samples plot in the sub-alkaline basalt field on SiO2 versus Zr/TiO2 diagram of [70] (Fig. 7b), except for sample (MO71) which plots in the basanite field. The studied meta-mafic rocks plot exclusively in the tholeiitic field in the AFM ((Na2O–K2O)–FeO–MgO) ternary diagram (Fig. 8a, [68]). On the SiO2 versus K2O diagram after [69], the studied samples plot in sub-alkalic and low-k sub-alkalic domain (Fig. 8b). On the Harker diagram of major oxides versus MgO, SiO2, Al2O3, K2O and MnO do not display any correlation with MgO while, Fe2O3, TiO2, Na2O and P2O5 display a negative trend with increasing MgO while Cr2O3 and CaO contents show a positive correlation with increasing MgO (Fig. 9).
4.4.2 Trace elements
Trace and rare earth element concentrations are shown in the Table 3. The values of Cr are widely variable (23.71–360.00 ppm for the FGM and 230.00–1055.20 ppm for the CGM). Rb concentrations are generally low (0.66–14.60 ppm for the FGM and 1.40–4.70 ppm for the CGM). The Sr (67.10–232.8 ppm for the FGM and 21.80–72.00 ppm for the CGM) display a variable concentration, while Nb (1.60–11.70 ppm for the FGM and 1.10–4.60 ppm for the CGM) and Ta (0.10–0.70 ppm for the FGM and 0.10–0.35 ppm for the CGM) concentrations are low. On the bivariate plots (Fig. 10), Yb which is a relatively immobile trace element, display a strong positive correlations with Ho, Gd, Zr, and Y (R2 > 0.80), positive correlations with Nb, La, Sm, Ba (0.43 < R2 < 0.68) and no correlations with Rb (R2 = 0.004). The MgO display negative correlations with V, Zr, Nb, Y Hf and Ga (Fig. 11).
The chondrite-normalized REE spidergram [72] of the samples (Fig. 12c, d), show a nearly flat patterns with a little enrichment of the LREE compared to HREE. When plotted on the multi-element spidergram normalized to the primitive mantle [73] (Fig. 12a, b), the fine-grained garnet meta-mafic rocks exhibit relatively flat patterns with both positive and negative Ba and Sr anomalies while the coarse-grained garnet meta-mafic rocks show only Sr negative anomalies. The studied samples display Ce/Ce* ratios ranging from 0.92 to 1.37 for the FGM and 0.81–3.10 ppm for the CGM, and slightly negative Eu anomaly (Eu/Eu* = 0.59–0.97 for the FGM and 0.76–0.95 for the CGM).
5 Discussion
5.1 Petrographical evidence of anatectic melt and P–T conditions
The Lolodorf area and its surroundings display the meta-mafics rocks presenting partial melting evidences such as the presence of leucosome and melanosome at the mesoscopic scale (Fig. 3). On a microscopic scale, the presence of neosome and the residual phase (Fig. 4), significantly indicates the process of melt segregation [74]. Other evidences are the presence of quartzo-feldspathic beds hosting clinopyroxenes, orthopyroxenes and amphiboles; the dislocation of the garnet necklaces and the coalescence of the garnets in a broken chain scattered in the matrix (Fig. 4). The presence of aggregates of garnet and orthopyroxene in the neosome (Fig. 4), suggests grain migration, consistent with the presence of melt [75]. In addition, the reactive mineral aggregates in the residual phase and the quartz ribbon that cut the quartz- plagioclase aggregates in the neosome phase and the presence of the molten edges of quartz and plagioclase along the grain boundaries further support this conclusion. The mineral recrystallization features on the studied rocks are also characterized by mantle and core microstructures and the neograins around the phenocrystals. All these microstructures occur at high temperature and are symptomatic of partial melting. The comparison of the studied meta-mafics rocks with migmatitic gneiss, TTG [37] and tonalitic gray gneiss where partial melting has been described in the NyC [47, 74] helps to reinforce the claim that the partial melting event was recorded on a regional scale.
The temperature and the pressure estimated by geothermobarometry are around 672–952 °C, and 2.7–14.89 kbar for the FGM and 631–909 °C and 1.5–16.09 kbar for the CGM. The mineral assemblage of the studied meta-mafics rocks was stable at higher oxygen fugacities (LogO2 varying from − 15.67 to − 12.47 atm for the FGM and − 20.48 to − 12.67 atm for the CGM). The above-mentioned metamorphic conditions of the studied meta-mafics rocks are nearly consistent with those from other mafic rocks from the Southwest Cameroon [20, 21, 76]. It is inferred that the amphibolite-granulite transition took place during a retrograde stage possibly related to a post-peak thermal overprint and/or fluid infiltration.
5.2 Origin and evolution of the granulites’ protolith
The La/Th ratios are useful indicators of mafic or felsic source components, while Hf content generally reveals the degree of recycling. Hf (0.80–3.70 ppm) contents in the studied meta-mafics rocks are very low suggesting the presence of intracratonic basin as it is the case in the previous works in the neighbouring NC [77]. The studied meta-mafics rocks display a wide range of La/Th ratios (0.00–22.27) that can be divided into two groups: below and above of 15. The La/Th ratios below 15 suggest the input of crustal sources or the presence of the sedimentary basin while the ratios above 15 (obtained from three samples) indicate that the studied samples may probably have mantle connection. This is consistent with the high Mg# (40.85–69.70) and the low SiO2 (46.68–50.70 wt%) contents of the studied samples indicating the basaltic nature of the meta-mafics rocks protolith.
Moreover, the studied samples display high Na2O and low K2O contents [78], which is indicative of the partial melting of mafic rocks from the lower part of thickened crust [79, 80]. On the binary La/Th versus Hf diagram [81], the samples display high La/Th ratios except the MO 57 sample (Fig. 13a), defining a trend which perhaps reflects affinities with evolved “mixed felsic-basic arc” and “andesitic arc”sources. When plotted in the Th/Yb versus Nb/Yb diagram (Fig. 13b; [3]), few samples (2 samples FGM and 01 sample CGM) plot in the fields of N-MORB and E-MORB, while most of the samples are plotted above the mantle array precisely on the magmatic arc field following an oblique linear trend, indicating the influence of crustal contamination and the partial melting in their generation. These characteristics suggest a remobilization of the already crystallized mafic rocks (protolith) in the active continental margin context [82]. The trace elements ratios such as the Nb/Th and La/Nb are very useful for the discrimination of the origin of the magmas [72]. The La/Nb ratios of the samples are between 0.92 (< 1) and 2.41, (> 1.0), indicating both the participation of the crust and the mantle components in the generation of the Lolodorf mafics rocks. Such geochemical imprints are most often found in sub-alkaline, alkaline and tholeiitic formations [82]. The variable content of elements such as Ba (4.49–286.00 ppm), Sr (0.50–232.00 ppm), Zr (24.40–162.00 ppm) and Th (0.10–1.20 ppm) may indicate the fractionation of feldspars and zircon [83]. The enrichment of Rb, Ba, Th, K and La in some samples suggest the probable addition of components like sediments and fluids to the original mantle rock [84] prior to melting. In the Nb/Y versus Ba/Y (Fig. 14a) and Nb/Zr versus Th/Zr diagrams (Fig. 14b), the studied meta-mafics rocks define a trend indicating the mantle source modified by fluid phases and melt [84, 85]. In the Sm/La vs. Th/La diagram (Fig. 14c), all the studied samples are plotted in the arc magma array with few samples plotted very close to the global subducting sediment (GLOSS) [86], indicating the influence of melt during the evolution of these rocks.
These behaviors indicate the contribution of the continental crust and mantle to the generation of the studied rocks [87]. The K2O/P2O5 ratio (0.71 and 9) indicates a minimum to maximum involvement of the silicic component of the crust. In general, the studied samples display Eu/Eu* > 0.6, typical of source rocks affected by intracrustal differentiation processes [88]. Overall, a combination of these results suggests that the protolith of the studied rocks was mafic magma generated in an active continental margin (Fig. 13b). The presence of the melt segregation observed in macroscopic and microscopic scales suggests that the rocks may have been affected by high grade metamorphism associated with the migmatization or partial melting. Both the composition of the mantle source and the degree of partial melting that produced the parental magmas of the studied meta-mafic rocks can be determined using REE abundances and ratios. In the La/Sm vs. La diagram (Fig. 15a) the majority of the samples are plotted along the trend of partial melting and one sample along the fractional crystallization indicating the predominance high degree of partial melting during the generation of magma sources of these rocks. Moreover, the Sm versus Sm/Yb diagram after [89] point to the contribution of 4–68% melting of the spinel lherzolite source (Fig. 15b). Plotted on the Zr/4-2Nb–Y triangular diagram of [90] indicating the geotectonic contexts of the basalts (Fig. 15c), the studied meta-mafics of Lolodorf and its surroundings fall on the N-MORB field.
The results from the studied meta-mafics rocks from the Lolodorf area are consistent with recent studies on the NyC mafic rocks that point to a conclusion that the protolith of eclogite are basaltic in compositions, with tholeiitic nature and MORB affinities [20, 21].
5.3 Relative emplacement ages
The studied fine-grained meta-mafic rocks (FGM) display the petrographical, mineralogical and geochemical characteristics of samples that went through partial melting and metamorphism (MO31, MO33, MO36 and MO47) while the Coarse-grained meta-mafic rocks (CGM) display only metamorphic signature (MO57). The FGM displays banded patterns while the second does not. The features highlighted on the CGM are similar to those of previous studies in the NyC (dated at ca. 2.09 Ga) [20]. Then, the 2.09 Ga obtained in the NyC rocks could be assigned to the CGM [20]. The FGM (banded samples) were emplaced before the partial melting even, probably during Mesoarchean period while the CCM may have crystallized during Eburnean period [35, 46, 49].
The amphibolite-granulite facies transition observed on the Lolodorf meta-mafic rocks have been also recorded in the mafic and charnockitic rocks from the NyC in Cameroon (2.05 Ga, [20, 46]), in the migmatitic gneiss of Ivory Cost (2.05- 2.03 Ga, [93,94,95]) and in Brazil (2.10–2.07 Ga, [96]). The restricted range of ages observed in high grade metamorphic rocks (2.10–2.03 Ga, [20, 93,94,95, 97]) and within the mafic rocks (2.09 Ga, [20]) suggest that the partial melting and the metamorphism may belong to the same event developed during the Eburnean orogeny at relatively limited time span. Overall, Mesoarchean high pressure mafic rocks (FGM protoliths) may have been reworked [35, 46, 49] coeval to the emplacement of juvenile meta-mafic rocks (CGM) during Eburnean period. This assumption is supported by previous works stipulating that the NC (which is an Archean nucleus crust) has interacted with juvenile Eburnean crust as described in other orogens (Thompson belt, Canada; Terre Adélie, Antarctica; Finland; Man Rise, Ivory Cost; [3, 14, 98].
6 Conclusion
In this study, mineralogical, geochemical and petrographical results of the Lolodorf mafic rocks studied disclose the following conclusions:
The Lolodorf area is made up of fine-grained and coarse-grained garnet meta-mafic rocks presenting granoblastic to granoporphyroblastic texture. They consist of quartz, plagioclase, garnet, orthopyroxene, clinopyroxene, amphibole, opaques, apatite and rutile.
The petrological study of the selected samples indicates that partial melting and peak of metamorphism occur under conditions close to amphibolite-granulite transition. The fine-grained garnet meta-mafic rocks emplaced under pressure estimated at around 2.7–14.89 kbar with temperature interval between 672 and 952 °C while the coarse-grained garnet meta-mafic rocks settled at around 1.5–16.09 kbar and temperature between 631 and 909 °C. The studied samples crystallized under high oxidizing conditions with low water content. The Mesoarchean fine-grained meta-mafic rocks protolith may have experienced Eburnean partial melting and metamorphic processes whereas the coarse-grained garnet meta-mafic rocks would have experienced only metamorphic process during Eburnean orogeny.
The geodynamic implications of the studied meta-mafic rocks suggest that an Eburnean convergence has implemented reworking and emplacement of the juvenile magmatic crust under high pressure and high temperature (HP-HT) conditions favoring intense partial melting. These processes have implied a crustal thickening and subsequent rapid exhumation of the studied meta-mafic rocks.
Data availability
The whole-rock geochemical (major and trace element) and mineralogical data used in this manuscript are original and reported in the tables.
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The authors are grateful to Professor Sajeev Krishnan from the Indian Institute of Science, Bagalore for facilitating mineral chemistry analyses. We would like to thank anonymous reviewers, whose helpful comments and suggestions improved the quality of this manuscript.
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Messi Ottou, E.J., Ntomba, S.M., Ntieche, B. et al. Petrology of the meta-mafic rocks from the Lolodorf area, Nyong complex (Southwest Cameroon): implication for the origin and emplacement conditions. SN Appl. Sci. 4, 216 (2022). https://doi.org/10.1007/s42452-022-05089-7
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DOI: https://doi.org/10.1007/s42452-022-05089-7