Abstract
With the current levels of industrial development it is very difficult to prevent organic pollutants and toxic heavy metals from contaminating water. Thus purification of contaminated industrial water and its reuse is a global concern. The present study highlights application of a novel standalone technology in the form of polymers that efficiently extract a range of organic and inorganic impurities simultaneously for reuse of industrial effluent. Previous studies have focused on water soluble synthetic polymers for removal of organic contaminants, while biodegradable polymers are being used for extraction of toxic metals from water. Our earlier reports already describe a combination of synthetic and natural polymers with the ability to eliminate organic and inorganic spiked impurities from water on a lab scale. In the present work a series of novel smart composite materials have been synthesized and fully characterized. The avant-garde novelty of these materials for simultaneous removal of organic impurities such as phenols, anhydrides, textile dyes, pesticides, herbicides, antibiotics and inorganic heavy metals has been demonstrated and the novel polymers have shown a removal efficiency of more than 90% for each of the contaminants. Furthermore, the established 4-cycle reusability and an extensive reduction in levels of chemical oxygen demand suggests these materials would act as an improvement to the current methods for treating effluent water. The high reproducibility in synthesis, properties and elimination spectrum brands them as promising materials for industrial water remediation and reuse.
Similar content being viewed by others
Explore related subjects
Discover the latest articles, news and stories from top researchers in related subjects.Avoid common mistakes on your manuscript.
1 Introduction
Good quality of water is a crucial parameter for the healthcare of society. With the continuous use of water for numerous industrial procedures, a balance needs to be established between its demand and supply. Due to its polarity and hydrogen bonding it has ability to dissolve or suspend many different contaminants. The contaminants from pharmaceutical, textile, chemical, agrochemical and various other industries may represent hazards in themselves or may be able to react with other substances, resulting in serious health complications [1]. Moreover with the imposition of various laws and zero liquid discharge (ZLD) for industrial effluent by regulatory agencies, water treatment has become a mandatory aspect for better conservation [2]. With the advancement of technology, various methods have been employed for effluent management including flocculation, electrolysis, electro-dialysis, physical/biological adsorption, ion exchange, reverse osmosis and membrane separation [3]. The applicability of a specific method is exclusively dependent on the nature and the content of the effluent and yet none of these methods deliver on all the water quality parameters in their individual capacity. Hence, there is need for a unique, safe, innovative and cost-effective technology that can be readily assimilated in the current industrial setup. Our earlier reports, describe the applicability of one such technology using smart biodegradable polymers that remove hazardous organic chemicals, metal ions and dyes from spiked water under the influence of temperature on a lab scale [4, 5]. In continuation of the earlier proceedings, in this paper we present an innovative technology in the form of a novel series of temperature responsive biodegradable materials as composites that have ability to efficiently extract the dissolved metal ions and impurities present in pharmaceutical, chemical agrochemical and textile industrial effluents. The composite materials have been developed as a promising approach to encourage water reuse by industries through their direct assimilation into the current effluent treatment setup. The materials are fabricated with an aim to reduce the water stress caused by extensive use and pollution from various industrial activities which in turn is a prime factor that demands the need for efficient water reclamation.
The smart composite materials are made up of smart polymers. These polymers show a characteristic behavior with respect to the environmental conditions in which they are present. This behavior is characterized by a change in phase or change in physical properties. The triggering factor for such behavioral change in the polymer can be light, temperature, pH, magnetic field or even enzymes [6]. Of the smart polymers, temperature responsive polymers change their phase with changes in surrounding temperature. Such polymers contain hydrophilic groups, which interact strongly with water molecules. Also, there is a prevalence of hydrophobic moieties in addition to the large number of hydrophilic groups. Therefore, they experience both repulsive and attractive forces with water molecules and the delicate balance of hydrophilic and hydrophobic moieties determines their water solubility. Upon heating, these polymers precipitate due to a change in the conformation of the chains at a specific temperature called the lower critical solution temperature (LCST). When temperature rises, the solubilized polymeric chains take up a coil structure. In order to reduce their free energy, the polymers start to aggregate and reduce their contact with water molecules. At or above the LCST a complete transformation is achieved that results in efficient aggregation and precipitation of the polymer. This precipitation is attributed to the domination of the hydrophobic groups [7]. These groups enable temperature responsive polymers to have a unique property of extracting organic impurities from aqueous solutions by adsorption [8]. Despite their wide applicability, temperature responsive polymers suffer the consequences of not being environment friendly. This is in contrast to biodegradable polymers that have been reported as chelating agents and thus adsorb inorganic water soluble impurities and dyes [9] from effluent but lack the shelf life for prolonged use. Therefore, a combination of both the polymers as a graft not only extracts organic and inorganic impurities simultaneously but also imbibes biodegradability to the overall polymer [4]. Hence, the current paper demonstrates co-polymerization or grafting of a temperature responsive synthetic polymer onto a biodegradable polymer to generate novel smart composite materials for exclusive extraction of phenols, anhydrides, textile dyes, pesticides, herbicides, antibiotics and inorganic heavy metals simultaneously from water.
2 Materials and methods
The natural polymer pullulan (Mol wt. 200,000 Da.) was a gift sample from Nagase India Pvt. Ltd. (Mumbai, India). The monomer N-isopropylacrylamide (NIPAAM) was a gift sample from SLN Pharma Chem (Mumbai, India), and dimethylaminoethyl methacrylate (DMAEMA) was a gift sample from Alfa Aesar (Mumbai, India), Diethylacrylamide (DEA) and N-vinylcaprolactam (NVCL) were procured from TCI chemicals (Chennai, India). The free radical initiator ceric ammonium nitrate (CAN) was purchased from S. D. Fine Chemicals (Mumbai, India) and dialysis membrane (12,000–14,000 Da,) from Hi-media (Mumbai, India).
3 Methods
3.1 Synthesis of functionalized smart composite materials
The composite materials were synthesized as reported by Ghimici et al. [10]. with modifications. In this pullulan, 1.0 g (0.005 mmol) was dissolved in 12 ml of 0.01 M nitric acid solution in a two-necked flask equipped with a nitrogen-inlet and a rubber septum. The flask was immersed in a thermostated water bath maintained at 25 °C. The solution was purged with nitrogen for 30 min and a nitrogen atmosphere was maintained throughout the polymerization process. CAN, 0.88 g (1.6 mmol) solubilized in 4 ml 0.01 M nitric acid solution was added. The solution was stirred for 10 min to induce free radicals on the pullulan chains. This was followed by addition of 1.13 g NIPAAM (10 mmol), and the reaction was continued for 20 h at 25 °C. The reaction was terminated by addition of 1 N aqueous NaOH solution till alkaline. The reaction mixture was poured into methanol, filtered, washed and extracted again with methanol for 24 h in order to remove polymerized NIPAAM homopolymer. The product was then warmed to 50 °C to precipitate the graft polymer which was dialyzed for 4 days and then lyophilized. Table 1 gives the details of the quantities of other monomers used and the graft polymers synthesized (Fig. 1).
3.2 Determination of LCST of the material under the influence of temperature
LCST was determined by the cloud point method wherein the temperature of a 2.5% solution of material was linearly increased from 20 to 50 °C (1 °C/min). The temperature at which the solution turned turbid was noted as the LCST. The LCST was confirmed using a Mettler (Toledo) DSC 822e unit.
3.3 FT-IR
Potassium bromide (KBr) discs with the copolymers were prepared using an electrically operated Techno Search Instruments KBr press model HP-15 (Mumbai, India). IR spectra were recorded on a Jasco FTIR-5300 Fourier transform spectrophotometer with a resolution of 4 cm-1.
3.4 1H-NMR
NMR spectra of the copolymers were recorded using a Brüker Avance III 800 MHz FT-NMR spectrometer. The NMR samples were made in solution comprising 0.9 ml H2O and 0.1 ml D2O mixture.
3.5 Molecular weight determination
3.5.1 Extraction of temperature responsive polymers from the composite material [10]
To determine the amount of temperature responsive polymers grafted onto pullulan backbone, the smart composite materials were subjected to hydrolysis using 70% v/v solution of sulphuric acid at room temperature for 9 h. This resulted in separation of pNIPAAM/pDMAEMA/pDEA/pNVCL chains from the respective materials which were extracted using methanol followed by their precipitation in solution using diethyl ether to obtain the homopolymers.
The molecular weights of homopolymers were then determined from viscosity measurements using the Mark–Houwink equation given below,
[η]—Intrinsic viscosity, K & a—Specific set of constants obtained from literature and M—Molecular weight of the homopolymer.
Further, the molecular weights of the final smart composite materials were determined using the following equation [4],
GR—grafting ratio, Wg—final weight of grafted polymer, Wp—weight of pullulan, MWhomo—molecular weight of homopolymer, MWp—molecular weight of pullulan, MWg—molecular weight of graft polymer.
3.6 Surface area determination
Brunauer–Emmett–Teller (BET) surface area analysis and Barrett-Joyner-Halenda (BJH) pore size and volume analysis were performed on a Belsorp Mini II (Metrohm, India). Nitrogen adsorption and desorption by the polymer were studied. The minimum measurement of the instrument for surface area was 0.01 m2/g and range for pore size was 0.35 to 200 nm. A weighed sample of the GPA was loaded into a glass tube and, as pre-treatment, was degassed for 3 h at 110 °C and 10−2 kPa pressure. The sample was then weighed and loaded into the instrument for analysis.
3.7 Evaluation and optimization of adsorption potential
The novel smart composite materials were made with an aim to adsorb and extract various organic as well as inorganic impurities from water. Since the range of impurities is complex, it was found necessary to adapt various techniques like UV–visible spectrometry (Jasco V-630), HPLC (Jasco PU-2080 binary pump system), Inductively Coupled Plasma-Optical Emission Spectroscopy (ICP-OES) [Teledyne Leeman labs Prodigy7] and titrimetric to evaluate the proportional removal (%) of various impurities from water. Reduction in levels of Chemical Oxygen Demand (COD) was an attempt to gauge the applicability of the smart composite materials for treatment of industrial effluents. Table 2 describes the methods developed and used for specific impurities.
A fixed concentration of each impurity with absorbance in the linear range of the Beer-Lambert law was selected, and the solution was treated with the smart composite material by heating above the respective LCST. The solution was then filtered and the precipitate removed followed by measurement of absorbance for the filtrate solution. The proportional removal was calculated using Eq. (4):
where Co: impurity concentration before treatment, and Ce: impurity concentration after equilibrium treatment. The proportional impurity removal for ICP-OES was determined by comparing the reduction in concentrations of metal ions before and after treatment. All studies were carried out in triplicate.
3.7.1 COD analysis of samples [11]
The chemical oxygen demand is a direct measure of the load of dissolved organic substances and impurities present in effluents. The standard COD titration method was used for determination of dissolved organic load of the effluent samples and was calculated by the following equation,
A 500 ppm solution of potassium hydrogen phthalate (KHP) was used as the standard for calibration and standardization of the titrimetric method.
3.8 Optimization of adsorption conditions [5]
The smart composite materials are highly soluble in water and precipitate only above the LCST. Precipitation is caused by transformation of the material into hydrophobic coiled chains that are responsible for adsorption of the impurities. To determine the materials maximum adsorption ability, initially a low concentration (1 mg/ml) (0.1%) of material was added to a solution containing a known concentration of impurity. The solution temperature was gradually increased and then kept constant above the LCST of individual materials for a range of times (contact time optimization).
Similarly, proportional removal was also determined for 0.2% and 0.4% w/v concentration of materials as to determine the maximum impurity adsorption.
3.9 Adsorption isotherm determination [5]
Adsorption isotherm experiments were carried out to determine and explain the relationship between Ceq, the equilibrium concentration of the adsorbate (materials) and qe, the amount adsorbed on the surface. The Langmuir and Freundlich isotherm models were used to analyse the materials above their LCST at the optimised temperature and contact times as determined above.
3.9.1 Langmuir adsorption isotherm
The Langmuir model exhibits a linear relationship for the amount adsorbed per unit mass of adsorbent material. It is distinguished by three factors—adsorption, desorption and kinetic rates-combined with the total number of free sites available on the surface. The collective surface concentration of impurity is denoted by q. Equation (6) is the linear form of the Langmuir equation:
where qe (mg/g) is the amount of impurity adsorbed per unit mass of material (sorbent), Ce (mg/l) the final concentration of unadsorbed impurity in solution, qm (mg/g) the monolayer adsorption capacity and KL (l/mg) the Langmuir equilibrium constant. qe is expressed as,
where Ci is the initial concentration, Cf the final concentration, and V the volume of impurity solution. The volume of impurity and mass of material remains constant for a given set of analyses. A plot of Ce/qe against Ce gives the Langmuir isotherm. The Langmuir constants are obtained from the slope (qm) and intercept (KL), and the model’s characteristics can be expressed in terms of RL, a dimensionless constant for the separation factor to depict whether the adsorption is favourable or unfavourable—Eq. (8):
where Ci is initial concentration. The characteristics of RL for favourable adsorption are 0 < RL < 1, for unfavourable adsorption RL > 1, for linear adsorption RL = 1, and for irreversible adsorption RL = 0.
3.9.2 Freundlich adsorption isotherm
This isotherm is based on the assumption that the adsorbent has a heterogeneous surface with numerous adsorption sites. The linear form of the Freundlich equation is given below,
where n is the Freundlich exponent and Kf the Freundlich constant, which measures heterogeneity; the higher the Kf, the more heterogeneous the adsorbent. To determine the Freundlich isotherm, a plot of log qe against log Ce gives a slope equal to 1/n and an intercept at logKf. The slope 1/n represents a collective value of the relative magnitude of adsorption intensity for a certain sorption process.
To determine the applicability and suitability of a particular isotherm model (Langmuir or Freundlich) to the experimental data the regression coefficient (R2) is calculated from the plot of log qe versus log kf.
3.10 Reusability of smart composite materials [4]
The reusability was determined by measuring the number of times an optimised weight of material could be used to lower impurity concentration from a fresh solution to 50% of its initial value, each time. To do this the best effective concentration of material was added to a 10 ml aliquot of known impurity solution/effluent at the optimised temperature and time. After treatment, the amount of impurity remaining in solution was determined. Subsequently a fresh aliquot of impurity was treated using the same material from the previous stage and the proportional removal was calculated. The stages were repeated until the proportional removal of impurity reached 50% of actual. In each stage to evaluate reusability, the proportional desorption was also evaluated to gauge the materials uptake and thus determine their reusability. After adsorption the material was re-dissolved in distilled water and the impurity leached by desorption was calculated using Eq. (11).
4 Results and discussion
4.1 Determination of LCST
The LCST values obtained from the cloud point measurements were confirmed using a differential scanning calorimeter (DSC). Figure 2a shows the thermogram for GP-09 and Table 3 summarises the DSC events for other materials. The LCST of NIPAAM, DEA and NVCL homopolymer is 32 °C and that observed for the smart composite materials (GP-09, 10 and 11) are in the range of 34–38 °C. Also, for DMAEMA homopolymer the LCST value is 49 °C and for smart composite (GP-12) is found to be 52 °C. This shift of LCST values is due to the increase/decrease in the hydrophilic properties of the material owing to addition or change of functional groups. A similar shift in the LCST values was evident in our previous paper and was confirmed using DSC [4].
4.2 FT-IR analysis
As shown in Fig. 2b the FT-IR spectrum of GP-09 shows characteristic peak of amide at 1643 cm−1 present in the NIPAAM unit of the composite. The signal at 3300 cm−1 is due to the hydroxyl groups present in the pullulan backbone. The N–H bend at 1457 cm−1 and C–O ether stretch at 1021 cm−1 correspond to signals from NIPAAM and pullulan. Similar characteristics are observed for the other smart composites thus confirming that the graft was successful.
4.3 1H-NMR
The smart composite material GP-09 was further characterized by 1H-NMR spectroscopy (Fig. 3). The peak at δ 7.73 ppm can be attributed to the –NH resonance of the amide group from the NIPAAM unit. The peak at δ 2.02 ppm is due to the methine proton of the isopropyl group [-CH(CH3)2] and at δ 1.59 ppm for the methylene protons [–CH2–CH–CO–NHCH(CH3)2] of the NIPAAM unit. The peaks labelled as C2, C3, C4 and C5 as seen from δ 3.36 to 4.04 ppm are for the hydrogen from the pullulan backbone. The distinct peak at δ 1.16 ppm is due to the methyl groups [-CH(CH3)2] and resonance at δ 3.92 ppm represents the methine [-CH-CO-NH-] of NIPAAM moiety. The resonances at δ 5.40 and 5.41 ppm are due to the hydrogens from the 1,4 linkage of the pullulan unit. Thus, the spectrum confirms the structure of GP-09.
4.4 Molecular weight determination
The approximate molecular weight obtained for smart composite materials are given in Table 3. The grafting ratio (GR) is dependent on the amount of temperature responsive polymer grafted onto the pullulan backbone. It is observed that the graft ratio is nearly same for all the materials which can be attributed to constant weight of pullulan and also similar molecular weights of temperature responsive polymers as obtained from the extraction method. Thus, suggesting analogous grafting for all the materials and equivalent addition of the homopolymer onto pullulan backbone.
4.5 Surface area and porosity
The surface area and porosity of GP-09 were calculated from the adsorption isotherm obtained by measuring the amount of gas adsorbed across a wide range of relative pressures from 10 to 70 kPa at constant temperature (liquid nitrogen 77 K) in triplicate. The amount of gas adsorbed is correlated to the total surface area of the particles including pores in the surface. The BET specific surface of GP-09 was determined as 0.128 m2/g, while the BJH plot shows the pore specific surface as 0.122 m2/g. Although the smart composite materials have a relatively small surface area compared to conventional adsorbents, they still exhibit effective adsorbent properties due to high specificity at LCST i.e. when the positions of the hydrophilic and hydrophobic groups are reversed in their regular structural scaffold. The presence of hydrophobic groups on the surface of the smart composite materials (adsorbate) results in low/no hydrogen bonding interaction with water molecules, thereby increasing the hydrophobic surface, and the adsorption power. From the BJH plot the pore volume and pore width are 0.005 cm3/g and 3.70 nm, respectively. The pore widths of the smart composite materials are in the range 2 to 10 nm, as observed for adsorbents like zeolites. Thus it can be classified as mesoporous according to the IUPAC classification [12]. The pore width for GP-09 suggests that the area available for adsorption is the same as for standard adsorbents.
4.6 Optimization and evaluation of adsorption potential
4.6.1 Optimization of adsorption potential
The smart composite materials extract known concentrations of impurities effectively which is evident by the decrease in the absorbance with increase in the contact time. The treatment was continued until the solution reached equilibrium. It is also observed that with increase in the polymer concentration, equilibrium is attained quicker (Fig. 4). The optimum concentrations and contact times are above the LCST of the materials for a fixed impurity concentration (chlorophenol 50 ppm) as shown in Table 4.
4.6.2 Evaluation of adsorption potential under optimised conditions
The smart composite materials at concentration of 0.4% w/v under optimised contact times and temperatures were evaluated for extraction of a range of impurities and the results are presented in Tables 5 and 6 (metal ions evaluated by ICP-OES). All the smart composite materials exhibited similar extraction efficiencies for the various impurities. However, GP-09 displayed the highest impurity removal in the shortest contact time under respective optimised temperature. This adsorption and extraction of impurities including organic, inorganic dyes, agrochemical, metal ions and pharmaceuticals by the smart composite materials can be attributed to the existence of a combined action from pullulan and the temperature responsive polymer. Since each impurity was studied in isolation, it was interesting to evaluate preferential adsorption if any for a set of impurities (chlorophenol and phthalic anhydride) present together in a single solution. The results by HPLC confirmed that there is no preferential adsorption for the given set of impurities and the materials adsorb these impurities irrespective of their structural features. Also these materials are able to extract different metal ions when present together, which is an attractive feature of the materials. Moreover, the markedly reduced value of COD for the industrial effluent samples when treated with these materials indicated the simultaneous removal of impurities from industrial water.
Synthetic polymers like polyacrylamide as a flocculent have been extensively reported for COD reduction [13], but its use is limited due to environmental consequences and health hazards. Also natural polymers like chitosan, tannins, and cellulose derivatives being biodegradable and extremely good in COD reduction face challenges due to their shorter shelf life and stability [14]. Hence in the current study these polymers when combined together not only reduce the COD in a similar way as observed for their individual counterparts but also overcome the shortcomings of both the aforementioned polymers.
As discussed in the previous section, these composite materials have the potential to remove more than 90% of contaminants from wastewater at the optimum concentration of 0.4% w/v at LCST. These materials have been synthesized in a single step from individual polymers (natural and synthetic) in an economical fashion and thus can easily be mass produced. Therefore, the ease and high reproducibility of the synthetic process commends itself to easy scale-up in amounts required for commercial purposes. Also, the industrial applicability can be extended by converting these materials as nanoparticles/microspheres/nanofibers. Such fabrications will ensure that smaller quantities of the material can be used (economic viability) for wastewater treatment without compromising on the efficiency as reported by Ammar et al. [15]..
4.7 Adsorption isotherm analysis
The smart composite material GP-09 was studied using the Langmuir and Freundlich models. The models terms are calculated and R2 values are obtained for both the isotherms (Fig. 5). Table 7 shows the constants for the two isotherm models and it is clear that the Langmuir model provides a better fit than the Freundlich model, indicating monolayer adsorption on the surface of smart composite materials. Literature studies following similar Langmuir adsorption for removal of arsenic metal ions from water using a polyacrylamide hybrid has been reported by Sandip Mandal et al. [16]. The materials reported also show monolayer adsorption as seen in case of composite materials.
4.8 Reusability of smart composite materials
This study was carried out at the optimised time frame and concentration for maximum efficiency. As shown in Fig. 6, GP-09 has slightly better removal efficiency of the four smart composite materials tested when used repeatedly with fresh stock of impurity. All the materials lose more than 50% of their efficiency after 4 cycles of reuse. The reusability and efficiency of these materials is found to be almost similar to the polymers reported in our earlier communications [4, 5].
5 Conclusion
The end product/technology of the current work delivers novel smart composite materials for simultaneous removal of contaminants (90% and above) from effluent water which can be further reused for various other processes in the industry. Thus, the first and foremost outcome is a system that enables and encourages optimal water use. A significant reduction in the level of Chemical Oxygen Demand (COD) was also observed for effluent water pooled from chemical, textile, agrochemical and pharmaceutical industries. The smart composite materials have also been tested for their reusability and have proven to be useful for at least 4 cycles. Their ability to take up all impurities concurrently, coupled with the ease of handling marks them as an advanced innovation that can act as an improvement to the current technologies used in industries for reuse in wastewater treatment systems. The materials also project as proof of concept for an application that ensures complete water conservation and wastewater recovery from the industrial effluent.
References
Du B, Price AE, Scott WC, Kristofco LA, Ramirez AJ, Chambliss CK, Yelderman JC, Brooks BW (2014) Comparison of contaminants of emerging concern removal, discharge, and water quality hazards among centralized and on-site wastewater treatment system effluents receiving common wastewater influent. Sci Total Environ 466:976–984
Tong T, Elimelech M (2016) The global rise of zero liquid discharge for wastewater management: drivers, technologies, and future directions. Environ Sci Technol 50(13):6846–6855
Gunatilake S (2015) Methods of removing heavy metals from industrial wastewater. Methods 1(1):14
Paneysar JS, Barton S, Chandra S, Ambre P, Coutinho E (2016) Novel thermoresponsive assemblies of co-grafted natural and synthetic polymers for water purification. Water Sci Technol 75(5):1084–1097
Js Paneysar, Sawant S, Ip MH, Sk Bhullar, Barton S, Ambre P, Coutinho E (2019) Nanofibers for textile waste water management. Water Pract Technol 14(2):297–310
Aguilar MR, San Román J (2019) Smart polymers and their applications. Woodhead Publishing, Cambridge
Aguilar MR, Elvira C, Gallardo A, Vázquez B, Román J (2007) Smart polymers and their applications as biomaterials. Top Tissue Eng 3(6):1–27
Saitoh T, Yoshida Y, Matsudo T, Fujiwara S, Dobashi A, Iwaki K, Suzuki Y, Matsubara C (1999) Concentration of hydrophobic organic compounds by polymer-mediated extraction. Anal Chem 71(20):4506–4512
Saber-Samandari S, Gulcan HO, Saber-Samandari S, Gazi M (2014) Efficient removal of anionic and cationic dyes from an aqueous solution using pullulan-graft-polyacrylamide porous hydrogel. Water Air Soil Pollut 225(11):2177
Ghimici L, Constantin M (2011) Novel thermosensitive flocculanting agent based on pullulan. J Hazard Mater 192(3):1009–1016
Chakraborty S, Purkait M, DasGupta S, De S, Basu J (2003) Nanofiltration of textile plant effluent for color removal and reduction in COD. Sep Purif Technol 31(2):141–151
Dąbrowski A (2001) Adsorption—from theory to practice. Adv Colloid Interface Sci 93(1–3):135–224
Wong S, Teng T, Ahmad A, Zuhairi A, Najafpour G (2006) Treatment of pulp and paper mill wastewater by polyacrylamide (PAM) in polymer induced flocculation. J Hazard Mater 135(1–3):378–388
Tetteh EK, Rathilal S (2019) Application of organic coagulants in water and wastewater treatment. In: Organic polymers. IntechOpen
Ammar N, Fahmy A, Kanawy Ibrahim S, Hamzawy EMA, El-Khateeb M (2017) Wollastonite ceramic/CuO nano-composite for cadmium ions removal from waste water. Egypt J Chem 60(5):817–823
Mandal S, Sahu MK, Patel RK (2013) Adsorption studies of arsenic (III) removal from water by zirconium polyacrylamide hybrid material (ZrPACM-43). Water Resour Ind 4:51–67
Acknowledgements
The authors would like to thank (i) University Grants Commission (UGC), India [File No. 43/489 (SR)] for providing financial assistance for this Project. (ii) SLN pharmachem and Nagase India Pvt. Ltd. for the gift samples of NIPAAM and Pullulan respectively. (iii) Metrohm India Pvt. Ltd for the surface area and porosity determinations. (iv) Dr. Shardul kulkarni and Dr. Nitin Kulkarni, Lab India Pvt. Ltd. for ICP-OES analysis of the samples.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
This article is published under an open access license. Please check the 'Copyright Information' section either on this page or in the PDF for details of this license and what re-use is permitted. If your intended use exceeds what is permitted by the license or if you are unable to locate the licence and re-use information, please contact the Rights and Permissions team.
About this article
Cite this article
Paneysar, J.S., Jain, S., Ahmed, N. et al. Novel smart composite materials for industrial wastewater treatment and reuse. SN Appl. Sci. 2, 1084 (2020). https://doi.org/10.1007/s42452-020-2778-0
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s42452-020-2778-0