Abstract
To address the problems of easy leakage and high flammability of phase change materials, a series of innovative leakage-proof phase change composites (PCCs) with excellent solar thermal conversion capability and superior flame retardancy have been successfully developed. Herein, two-dimensional layered MXene nanosheets with excellent solar-thermal conversion effect were first synthesized by etching MAX phase with lithium fluoride and hydrochloric acid solutions. MXene/polyimide (PI) aerogel was then prepared by freeze-drying and thermal imidization after MXene dispersions mixed with poly (amic acid). The MXene/PI aerogels were subsequently impregnated into polyethylene glycol (PEG) by vacuum impregnation to obtain new shape-stable MXene/PI@PEG phase change composites (MPPCCs). Among them, MPPCC-4 exhibits a very high PEG loading capacity (98.1%) and high enthalpy (167.9 J/g), and a relative enthalpy efficiency of 99.8%. When compared to PEG, MPPCC-4 has outstanding flame retardant properties, including a 26.2% lower peak heat release rate and an 11.6% lower total heat release rate. In conclusion, MPPCCs show considerable potential for application in solar energy utilization systems.
Graphical abstract
MXene/polyimide hybrid aerogel supported phase change composites show excellent solar thermal energy harvesting and flame-retardant property.
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1 Introduction
The shortage of fossil fuels and greenhouse gases emissions [1, 2] are exacerbated as global issues, which can be resolved through searching for new renewable energy sources [3] and developing energy-efficient systems. Among the various renewable energy, solar energy is a ubiquitous, easily accessible, and inexhaustible source to relieve energy crisis [4]. However, the application of solar energy is always restricted by several uncontrollable factors such as mismatching in time and space and low solar-thermal conversion. Therefore, exploring suitable materials making great use of solar energy is the key thesis in current research. Phase change materials (PCMs) with huge latent heat and stable phase change points are beneficial to improving the energy utilization by storing and releasing the solar energy without any environmental limitation [5]. Pure PCMs can be simply divided as organic and inorganic compounds. Compared to inorganic PCMs, organic PCMs are less corrosive and more stable to apply without phase separation during solid–liquid process [6]. However, pure organic PCMs also exist several drawbacks, which seriously hinder their practical application such as poor solar absorption and the leakage caused by deformability [7].
To overcome these challenges as well as keep excellent energy storage performance, PCMs are always request to composite with other framework materials as PCMs composites. Among various preparation methods of PCM composites, encapsulated organic PCMs in porous materials is a common way to keep satisfactory shape stability and achieve stable thermal energy conversion [8]. These porous materials include graphite foam [9], carbon nanotube sponge [10, 11], graphene aerogel [12,13,14,15], expanded graphite [16,17,18], boron nitride aerogels [19,20,21,22], or other polymer composites [8, 23, 24]. PCMs are firmly fixed in the help of porous three-dimensional skeleton, preventing leakage via improving shape stability, which are facilitating for thermal energy storage. Unlike other common porous materials, MXene as a kind of emerging 2D materials may be also promised in PCMs composites utilization [25,26,27]. In contrast, MXene shows great strengths in enabling thermal energy storage and transport applications. Since 2011, MXene has been studied in many fields. It is reported that two enhanced absorption peaks have been detected in the visible and near-infrared regions, which are similar to metal nanoparticles [28, 29]. This result shows that light absorption of MXene would be enhance due to localized surface plasmon resonance effects. What is more, with excellent solar energy conversion performance, high thermal conductivity [30] and wide absorption spectral range [31], MXene is a suitable candidate for enhanced capability of solar thermal conversion [32,33,34]. Therefore, adding MXene in PCM-based energy storage systems will improve the utilization of solar energy.
In addition, the high flammability of organic solid–liquid PCMs (such as polyethylene glycol) is another factor severely limiting applications. Hence, it is necessary to strengthen the flame retardant performance of phase change composites (PCCs). It is understood that not only MXene have strong light absorption capacity, but it also has excellent charring capacity and physical barrier effect [35,36,37,38], which may help to improve the flame-retardant efficiency of PCCs. On the other hand, polyimide (PI) aerogels show a special three-dimensional structure, low density, and excellent flame resistance [39, 40], which is expected to be a framework material, reducing leakage and improving flame resistance of PCCs.
In this work, MXene nanosheets were obtained by etching MAX powder with lithium fluoride (LiF)-hydrochloric acid (HCl) solution. The MXene dispersion was then mixed with poly (amic acid) (PAA), followed by freeze-drying and thermal imidization to prepare MXene/PI aerogels (MPs). Finally, the MPs were vacuum-impregnated into polyethylene glycol (PEG) to obtain shape-stable MXene/PI@PEG phase change composites (MPPCCs). The solar-thermal conversion properties, thermal storage properties, thermal stability, and flame retardancy of the MPPCCs were systematically investigated. As expected, the MPPCCs have excellent shape stability and high PEG encapsulation ability (98.1%) with a relative enthalpy efficiency of 99.8%, showing strong solar-thermal conversion capability and excellent flame retardancy. Noteworthy, the peak heat release rate (pHRR) and total heat release rate (THR) of MPPCC-4 were 26.2% and 11.6% lower than pure PEG, respectively. As a result, the obtained MPPCCs have great potential in safe flame retardancy and efficient solar energy storage applications.
2 Experimental section
The manufacturing process of MPPCCs is shown in Fig. 1. First, the MAX powder was etched with LiF-HCl solution to obtain MXene nanosheets. PAA was prepared and then uniformly mixed with the MXene dispersion in a certain proportion at room temperature. After that, MPs were obtained by freeze-drying and thermal imidization. Finally, the MPPCCs were obtained by adsorbing PEG through vacuum impregnation. More detailed information on the experimental procedure and characterization can be found in the supporting information.
3 Results and discussion
3.1 Analysis of MXene
Figure 2a, b shows the morphologies of MAX (Ti3AlC2) powder and multilayered MXene (Ti3C2) powder. The Al atomic layers from the densely layered MAX phase are etched by LiF-HCl solution, and after that, the interlayer spacing becomes larger, transforming into an accordion-like loose layer structure. These phenomena are consistent with our previous research [41], indicating fluffy MXene powder with an accordion-like structure is successfully prepared. The Tyndall effect can be observed in the aqueous dispersion of MXene as shown in Fig. 2c. This indicates that MXene owns superior water dispersibility with the existing hydrophilic groups. The TEM images of single-layered MXene nanosheets are exhibited in Fig. 2d. Due to the destroyed Vander Waals force, the multilayered MXene were exfoliated as the ultra-thin MXene nanosheets. Figure 2e shows the AFM image of MXene and the corresponding height profile. The width and thickness of the MXene nanosheets are around 0.40–1.00 μm and 3.23–3.43 nm, respectively, which are consistent with those reported in the literature [42, 43]. All these results confirmed that few-layer MXene nanosheets were prepared successfully.
3.2 Morphology and structure of MXene/PI@PEG phase change composites
Figure 3a–d show SEM images of MP-5, PI aerogel and MXene aerogel. As shown in Fig. 3d, the MXene aerogel shows loose and disordered porous structure. The partially overlapping porous structures are weakly linked with the lamellar structure, so the aerogel may collapse by slight compression. At the same time, a shapeless pore structure is presented in PI aerogel (Fig. 3c). However, tight interfaces and interconnected oriented porous structures are produced after the combination of PI with MXene (Fig. 3a, b). The hydroxyl groups of MXene form strong hydrogen bonding forces with the oxygen-containing groups in the PI chains. Therefore, a stable 3D network of aerogel is formed [44]. At the same time, it can be further proved from Fig. S1 that with the increasing MXene content, the porous structure becomes more regular and denser. As shown in Fig. 3h, i, PAA solution and MXene/PAA dispersion are encased in circular boxes (radius d1), respectively. After freezing-drying, the radius of a pure PI aerogel (d2) is smaller than that of MP-4 (d4). The MP-4 is almost no change in volume after thermal imidization, while the pure PI aerogel shows severe shrinkage (d1 > d4 > d5 > d2 > d3). Therefore, these data further confirm that the MXene nanosheets are tightly wrapped and interconnected by PI chains, forming an integrated structure with outstanding size stability.
The EDS mapping image (Fig. 3g) of the MP-5 clearly shows the uniform distribution of MXene nanosheets on the PI backbone, which may completely enhance solar-thermal absorption as well as improve thermal storage ability. The SEM images of PI@PEG phase change composite (PPCC) and MPPCC-1 are shown in Fig. 3e, f. The loose porous structure of PI aerogel and MP-1 have strong capillary driving forces [36], and the interlayer spaces are easily filled by the molten PEG segments. Hence, the interlayer space is porous structure of PI aerogel and MP-1 that are filled with PEG without any gap after vacuum impregnation.
The interactions between the various components in aerogels and MPPCCs were investigated by FTIR (Fig. 4a). The FTIR spectrum of the MXene aerogel shows peaks at 3436.98 cm−1 and 1072.36 cm−1, which are –OH and C–O stretching vibrations [45]. The characteristic peaks of MP aerogel appear at 1718.26 cm−1 (C = O), 1501.95 cm−1 (C = C), 1378.85 cm−1 (C–N), and 1243.86 cm−1 (C–O) [46], indicating the existing of MXene nanosheets and PI chains. For pure PEG, its characteristic absorption peaks at 3467.38 cm−1 and 1108.87 cm−1 attribute to the stretching vibrations of –OH and C–O [47]. In addition, the spectra of PPCC and MPPCC-3 show the same characteristic peaks as PEG, and no obvious new peaks are found. These results show that there is physical adsorption between MP and PEG, including capillary effect and hydrogen bond interaction [34]. Therefore, MP can enhance the shape stability of PEG.
The crystal structure of aerogels and MPPCCs were understood using XRD, as shown in Fig. 4b. Compared with the pattern of MXene, the (002) peak intensity of MP is weaker, and the angle of 2θ changes from 6.06 to 5.66°. According to the Bragg equation, the interlayer distance increases from 14.6 to 15.6 Å. This is due to the PI molecules inserting and increasing the interlayer space of MXene nanosheets [48, 49].The curve of pure PEG shows two distinct strong peaks at 19.30° and 23.40°, corresponding to the (120) and (032) planes [6]. Notably, the characteristic peaks of PPCC and MPPCC-3 are similar to those of PEG. These results indicate that there is no change in the crystal structure of PEG in MPPCCs, confirming the porous structure of MP has no effect on the crystallinity of PEG. Therefore, the phase change properties of MPPCCs may not be influenced by the composites structure and keep same as that of pure PEG.
3.3 Phase change properties and thermal reliability of MPPCCs
The phase transition behaviors, including phase transition enthalpy and phase transition temperature, are recorded by DSC measurement. Figure 5a performs the DSC curves of pure PEG and MPPCCs between 20 and 80 °C, and the corresponding parameters are shown in Table 1. In addition, the enthalpy efficiency λ, and the relative enthalpy efficiency η are calculated by formula (1) and (2), respectively. With the little loss of latent heat, the larger values of them are, the more excellent thermal energy storage performance is.
where ΔHm–MPPCCs and ΔHm–PEG are the melting enthalpies of MPPCCs and pure PEG, respectively; the ω indicates the loading rate of PEG in MPPCCs.
From Fig. 5b, d and Table 1, it is clear that pure PEG is a good thermal storage material due to its high enthalpy (ΔHm = 171.5 J/g, ΔHf = 169.9 J/g) and suitable phase transition temperature (Tf = 40.3 °C, Tm = 61.8 °C). Compared to pure PEG, the addition of PI aerogel and MPs resulted in significant changes in the melting and freezing peak temperatures of the MPPCCs, as well as in the enthalpy values of melting 139.6 ~ 167.9 J/g and freezing (138.1 ~ 165.4 J/g). These results indicate that MXene nanosheets and PI molecules restrict the arrangement and free movement of PEG segments [34]. With the increasing MXene content in MPPCCs, the values of melting and freezing enthalpies firstly increase to a certain value, and then decrease. This shows that the more MXene introduced, the stronger the capillary effect and hydrogen bonding between MPs and PEG, which are conducive to the adsorption of PEG in large quantities. However, the dense pores of aerogels may be performed by excess addition of MXene, leading to decreasing of PEG absorption. As shown in Table 2, MPPCCs still have high relative enthalpy efficiencies compared with related phase change composites [7, 34, 50,51,52,53,54,55]. Therefore, DSC results show that the construction of MXene/PI framework can well encapsulate PEG to obtain MPPCCs with good thermal storage properties.
Excellent thermal reliability and repeatability are the important properties to ensure the long-term utilization in practical solar energy storage applications. The DSC curves of MPPCC-4 before and after 200 thermal cycles are shown in Fig. 6, and the corresponding thermal parameters are recorded in Table 3. There is no significant difference in the DSC curves after 200 thermal cycles, while the value of λ only decreases about 1.2%. This shows that MPPCC-4 has almost no loss of phase change enthalpy after 200 thermal cycles with good thermal reliability and reusability, which can meet the requirements of PCCs in practical solar energy storage applications. Figure 6d, e shows no difference in the position and shape of the peaks of MPPCC-4 before and after 200 thermal cycles as measured by FTIR and XRD spectra, indicating good chemical stability of the MPPCCs to meet practical application requirements.
The shape stability of phase change composites is another key factor for their practical application. As shown in Fig. 7, all samples are placed in a constant temperature vacuum oven at 80 °C. Obviously, pure PEG begins to leak after 30 min heating. However, all MPPCCs maintain their intact shape without any leakage. After 75 min, pure PEG is completely amorphous melting. In contrast, MPPCCs maintain their original shape macroscopically without leakage, suggesting the rigid 3D supporting framework and strong capillary force of MPs are beneficial for PEG absorption. Also, PEG can be tightly fixed via the intermolecular hydrogen bonding interaction between PEG and MPs [36, 56]. All above results confirm that aerogels constructed by PI and MXene show excellent ability to load PEG, and MPPCCs have good shape stability and reliability.
3.4 UV–vis–NIR measurement and solar-thermal conversion of MPPCCs
Figure 8a shows the UV–vis-NIR absorption intensity spectra of pure PEG and MPPCCs. Pure PEG has extremely low absorption over the entire UV–vis-NIR range, even almost zero below 1150 nm. Likewise, the absorbance of PPCC is poor tested. With the introduction of MXene nanosheets, MPPCC-4 and MPPCC-5 exhibit stronger absorbance over the entire spectral range. Furthermore, the absorption intensity of MPPCC-5 is slightly higher than that of MPPCC-4, which can be attributed to relatively higher MXene content of MPPCC-5. Theoretically, stronger light absorption means higher solar-thermal conversion capability, which is beneficial for solar energy storage.
As shown in Fig. 8b, the temperature–time curve (Fig. 8c) and digital thermal infrared imagery (Fig. 8d) of samples were recorded using a homemade infrared thermal imaging data recording device. When the light turns on, the temperature of all samples increased rapidly. When the detected temperature reaches 55 °C, the PEG in the phase change composite undergoes a “solid–liquid” phase transition, the heating rates of all samples start to slow down, and the radiant heat energy is stored in the form of latent heat. After 1390 s, the temperature of PPCC raises to 67.3 °C, while that of MPPCC-4 and MPPCC-5 raise to 78.1 °C and 80.9 °C, respectively. This indicates that the higher the content of MXene nanosheets in MPPCCs, the faster the heating rate and the higher the peak temperature, which is consistent with the UV–vis-NIR results.
When the illumination is stopped at 1390 s, the temperatures of MPPCCs all samples begin to drop rapidly to about 45 °C due to thermal diffusion between the samples and the surrounding environment, and begin to undergo a “liquid–solid” phase transition. The phase transition platform duration of MPPCC-5 during cooling is about 550 s, which is higher than that of MPPCC-4 (530 s) and PPCC (510 s). Due to the higher content of MXene nanosheets, more solar-thermal energy converts into heating latent stored in MPPCC-5 during the same illumination time. Therefore, the heat storage capacity of MPPCC-5 is better than that of MPPCC-4 and PPCC under the same light intensity and duration. Although the PEG loading rate of MPPCC-5 is 1.2% lower than MPPCC-4, there is little effect on the duration of the phase change platform. Meantime, the results of phase change platform duration are consistent with DSC. The above results indicate that the addition of MXene nanosheets is beneficial to improving the solar-thermal conversion ability of MPPCCs. Among them, MPPCC-5 exhibits outstanding solar-thermal conversion ability, following the same trend as the UV–vis-NIR absorption spectrum (Fig. 8a).
Furthermore, the durability of MPPCC-5 under higher light intensity was investigated by solar-thermal conversion cycling experiments (Fig. 9). As shown in Fig. 9a, c, comparing with the phase change platform duration keeping 690 s at the first cycle, the 16th duration of MPPCC-5 is slight shorten to 620 s. However, in Fig. 9b, d, the morphology of MPPCC-5 remains almost unchanged before and after 16 cycles. These results show that MPPCC-5 has excellent solar thermal cycling stability, which provides favorable conditions for long-term thermal storage of phase change composites.
3.5 Thermal stability of MPPCCs
The thermal stability of MXene, PI, MP-4, PEG, and MPPCCs was evaluated by thermogravimetric analysis (TGA). Figure 10 and Table 4 show the corresponding TGA and DTG results. It can be clearly observed from TGA and DTG curves that the thermal decomposition of all samples exhibits one step of mass loss. PEG undergoes a one-stage thermal degradation process corresponding to the pyrolysis of PEG molecular chains, showing a low onset thermal decomposition temperature (T5%, 378.8 °C) and a residual char (2.1%). MXene demonstrates high thermal stability with a mass loss of 12.1%. Furthermore, the PI also possesses high thermal stability, with a high maximum mass loss temperature (Tmax) of 568.4 °C and residual char of 51.6% at 800 °C. Specifically, in the case of MP-4 exhibits a Tmax of 587.2 °C and a residual char of 79.9% at 800 °C, indicating the thermal stability of PI can be improved by the addition of MXene. Therefore, the introduction of MXene can effectively hinder the decomposition of the PI matrix by the catalytic charring and barrier effect, thus resulting in improved thermal stability [36, 57].
PEG and all MPPCCs show similar thermal decomposition behavior. It is worth noting that the Tmax of the MPPCCs is slightly increased with the MXene content increases, which indicates that the thermal degradation of PEG can be inhibited by the MXene. Figure 10f shows the relationship between their final carbon residue as PPCC = 11.5% > MPPCC-1 = 7.5% > MPPCC-5 = 4.3% > MPPCC-4 = 3.3% > PEG = 2.1%. This corresponds to the trend of PEG content contained in the aerogels (Fig. 5c). With the increase of PEG loading rate in MPPCCs, the carbon residue rate decreased. However, compared with PEG, the char residue of MPPCCs was significantly increased, which is attributed to the MXene and PI can change the path of thermal degradation and promote PEG to form carbon residue [36]. The results show that the MPPCCs have sufficient thermal stability under the application conditions (61.7 °C).
3.6 Flammability performance of the MPPCCs
The flame-retardant behavior of MPPCCs was investigated using a micro-combustion calorimeter (MCC). Figure 11 shows the heat release rate (HRR) and total heat release (THR) curves of PEG, PMPCC-4, and PPCC. The corresponding data, such as peak heat release rate (pHRR), pHRR temperature, and THR, are listed in Table 5. From Fig. 11 and Table 5, it clearly shows that PEG is a flammable material with a high pHRR of 717.2 W/g and a THR of 24.2 kJ/g. By introducing MXene/PI, pHRR and THR of MPPCC-4 are reduced by 26.2% and 11.6%, respectively, compared with those of PEG. The decrease of pHRR and THR in the MXene/PI@PEG system indicates that the introduction of MXene/PI effectively decreases the heat release, thereby enhancing flame retardancy. The phenomenon is mainly due to the presence of MXene, which can contribute to improving the formation of a thermostable char, and the Ti-containing residual char can inhibit the underlying matrix from further burning [38, 58]. The SEM energy spectroscopy (EDS) results of MPPCC-4 before and after combustion (Fig. 12c1, c2) also demonstrate the protective effect of Ti-containing char during combustion. However, compared with MPPCC-4, the pHRR and THR of PPCC decreased by 16.1% and 31.8%, respectively. The reason is due to a load of PEG in PPCC being 11.7% less than in MPPCC-4 and thus weakening the heat release.
The microstructures of the residues were investigated by SEM. According to Fig. 12a1, a2, the PPCC show honeycomb-like structures, which are similar to the skeleton of PI. This indicates that almost all such PEG in PPCC is thermally decomposed and unable to form carbon residue. In contrast, a large number of fragments of char residues can be observed for MPPCC-4 residues, as shown in Fig. 12b1, b2. Such phenomenon demonstrates that the MXene can promote charring of the pyrolysis products of PEG by catalytic effect and thus improve the formation of stable graphitized char, which results in reduced heat release and reinforces the flame retardancy.
4 Conclusions
In this work, 2D layered MXene nanosheets with excellent photothermal effect were synthesized via in-situ HF method. Afterwards, MPs were freeze-dried and thermally annealed before being impregnated with PEG to create leakage-proof MPPCCs. MPPCC-4 has high PEG loading capacity (98.1%) and thermal storage density (167.9 J/g), performing excellent solar thermal conversion capacity. In addition, the coordinated effect of MXene nanosheets and PI significantly reduced the HRR and THR of MPPCCs, while the carbon yield increased, indicating that the flame retardancy of MPPCCs was significantly improved. In conclusion, MPPCCs have extremely high thermal storage density, excellent flame retardancy, and good solar-thermal conversion ability, showing a considerable potential in the field of solar energy utilization.
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Funding
This work was supported by the National Natural Science Foundation of China (Grant Nos. U20A20299 and 52003111). X. S. received support from the Research Fund Program of Yunnan Provincial Key Laboratory of Energy Saving in Phosphorus Chemical Engineering and New Phosphorus Materials (Grant No. LHG-2020–0004). Y. C. was supported by the Guangdong Special Support Program (Grant No. 2017TX04N371). J. H. received support from the Opening Project of Key Laboratory of Polymer Processing Engineering (South China University of Technology), Ministry of Education, (Grant No. KFKT2001). The authors also received financial support from Taif University Researchers Supporting Project number (TURSP-2020/158), Taif University, Taif, Saudi Arabia.
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Cao, Y., Weng, M., Mahmoud, M.H.H. et al. Flame-retardant and leakage-proof phase change composites based on MXene/polyimide aerogels toward solar thermal energy harvesting. Adv Compos Hybrid Mater 5, 1253–1267 (2022). https://doi.org/10.1007/s42114-022-00504-4
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DOI: https://doi.org/10.1007/s42114-022-00504-4