Abstract
Polymer electrolytes have attracted great interest for next-generation lithium-based batteries on account of safety and high energy density. In this review, we assess recent progress on the design of poly(ethylene oxide)(PEO)-based solid polymer electrolytes in high voltage lithium batteries and identify possible side reactions between PEO-based electrolytes and existing cathodes. We provide an overview of the ways to enhance high voltage resistance of PEO-based electrolytes. Those include components blend, molecular design and interface modification. With these efforts, we want to present new insights into rational design of PEO-based electrolytes to develop solid-state lithium batteries for advanced performance.
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Acknowledgements
This work was supported by the National Natural Science Foundation of China (No.22071133), the China Postdoctoral Science Foundation(No.2021M691763), the Tsinghua-Foshan Innovation Special Fund(TFISF), China (No.2020THFS0130), and the Fund of the Tsinghua University-China Petrochemical Corporation Joint Institute for Green Chemical Engineering (No.421120).
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Hou, W., Ou, Y. & Liu, K. Progress on High Voltage PEO-based Polymer Solid Electrolytes in Lithium Batteries. Chem. Res. Chin. Univ. 38, 735–743 (2022). https://doi.org/10.1007/s40242-022-2065-2
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DOI: https://doi.org/10.1007/s40242-022-2065-2