Abstract
A pyrolyzed ash containing about 50% carbon, named silicon carbon black(SiCB), was prepared by the anoxic pyrolysis of rice husk. Fourier transform infrared spectroscopy(FTIR), thermogravimetric analysis(TGA), Brunauer-Emmett-Teller(BET), transmission electron microscopy(TEM) and universal material testing machine were used to analyze the stress-strain relationship, Mullins effect and static viscoelastic properties of SiCB-filled vulcanized natural rubber(NR), and SiCB was compared with a commercially available semi-reinforcing furnace(SRF) carbon black. The results show that the vulcanized natural rubber filled with SiCB had similar reinforcing properties to those of that filled with traditional SRF, but obvious differences between them exist in stress -strain properties and stress softening resistance. We tried to discuss the related phenomena with the aid of the modified two-layer theory. And it is successfully predicted and verified that SiCB has good compression resistance and obvious stress relaxation advantages in compression stress relaxation.
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References
Fukahori Y., Journal of Applied Polymer Science, 2005, 95(1), 60
Patel M., Karera A., Prasanna P., Joural of Material Science, 1987, 22(7), 24574
Uzunova S., Uzunov I., Vassilev S., Alexandrova A., Staykov S., Angelova D., Bul. Chemical Communication, 2010, 42(2), 130
Pande A., Makarande S., International Journal of Engineering Research and Application, 2013, 3(1), 1718
Ishak Z. A. M., Bakar A. A., European Polymer Journal, 1995, 31(3), 259
Xue B., Jiang Y. S., Yang D. F., Shi X. D., Chem. J. Chinese Universities, 2011, 32(7), 1617
Haxo H., Mehta P., Rubber Chemistry and Technology, 1975, 48(2), 271
Sae-Oui P., Rakdee C., Thanmathorn P., Journal of Applied Polymer Science, 2002, 83(11), 2485
Diani J., Faylle B., Gilormini P., European Polymer Journal, 2009, 45(3), 601
Wang C. C., Zhang Y. F., Liu Q. Q., Wang Z. B., International Polymer Processing, 2017, 32(1), 11
Hu X. L., Micro- and Macro-viscohyperelastic Behavior of Carbon Black Filled Rubber, Xiangtan University, Xiangtan, 2013
Zhou Y., A Study About the Preparation and Performance of Silica Carbon Black/polymer Composite, Jilin University, Changchun, 2017
Mullins L., Rubber Chemistry and Technology, 1969, 42(2), 339
Rickaby S. R., Scott N. H., International Journal of Solids and Structures, 2013, 50(1), 111
Webber R. E., Creton C., Brown H. R., Gong J. P., Macromolecules, 2007, 40(8), 2919
Yuan X. H., Zhang Y. X., Zhang Y., Peng Z. L., Journal of Shanghai Jiaotong University, 2000, 34(11), 1516
Wang H., Zhang J. P., Ma Y. S., Wang R. G., He A. H., Chem. J. Chinese Universities, 2017, 38(11), 2095
Sperling L. H., Introduction to Physical Polymer Science, 4th Ed., Wiley-Interscience Press, New York, 2006, 427
Bhowmick A. K., Current Topics in Elastomer Research, CRC Press, Boca Raton, 2008, 518
Tobolsky A. V., Prettyman L. B., Dillon J. H., Journal of Applied Polymer Science, 1994, 15(4), 380
Menon A. R. R., Journal of Applied Polymer Science, 1997, 65(11), 2183
Zhou D. P., Technology on Adhesion & Sealing, 1997, 18(2), 1
Wu G. W., Hsiue G. H., Yang J. S., Materials Chemistry and Physics, 1994, 39(1), 29
Mostafa A., Abouel-Kasem A., Bayoumi M. R., Materials & Design, 2009, 30(7), 2721
Acknowledgements
The authers thanked to PAN Chao and LYU Qiaochu( Changchun University of Technology) for their help in the early stage of the experiment.
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Supported by the International Cooperation Science and Technology Development Program of the Science and Technology Department of Jilin Province, China(No.20170414025GH).
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Qian, M., Sui, J., Wang, X. et al. Mechanical Properties of Silicon Carbon Black Filled Natural Rubber Elastomer. Chem. Res. Chin. Univ. 35, 139–145 (2019). https://doi.org/10.1007/s40242-019-8289-0
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DOI: https://doi.org/10.1007/s40242-019-8289-0