Abstract
To determine the template effect of hydrophobically associating copolymers(HACPs) on the morphology of nano/micro structures, six HACPs were synthesized and used as templates to biomimetically synthesize cuprous oxide(Cu2O), an important semiconductor. This experiment showed a clear relationship between the associating state of the HACP molecules and the morphology of the Cu2O particles. Cu2O hollow spheres were preferentially prepared when the HACP molecules were in an intramolecular associating state. Furthermore, a Cu2O hexapod was easily ob-tained when the HACP molecules were in an intermolecular associating state. The morphologies of the Cu2O crystals prepared in the presence of the HACPs also confirmed this result.
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Supported by the National Natural Science Foundation of China(No.51102219) and the Fundamental Research Funds for the Central Universities of China(Nos.201113024, 41404010204).
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Dong, L., Liu, H., Li, Y. et al. Template effect of hydrophobically associating polymers on the construction of cuprous oxide micro structure. Chem. Res. Chin. Univ. 34, 138–144 (2018). https://doi.org/10.1007/s40242-018-7173-7
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DOI: https://doi.org/10.1007/s40242-018-7173-7