Abstract
Complexes Cu(II)(4′-R-terpyridine)2(ClO4)2[R=2-thienyl(1), 2-(5-bromothienyl)(2), 2-(5-methyl-thienyl)(3) and 2-(5-methoxythienyl)(4)] were synthesized, and their structures were determined by single-crystal X-ray diffraction analyses and were further characterized by high resolution mass spectrometry, infrared spectrosco-py(IR), as well as elemental analysis. Single crystal X-ray diffraction analysis shows that Cu(II) ions in the complexes are both six-coordinated with N6 coordination sphere, displaying distorted octahedral geometries. In addition, the UV-Vis absorption spectra show that the four complexes all exhibit absorption components in both UV and visible light regions. Thus, the photocatalytic activities of the four complexes in the degradation of organic dyes were investigated.
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Schubert U. S., Hofmeier H., Newkome G. R., Modern Terpyridine Chemistry, Wiley-VCH, Weinheim, 2006
Constable E. C., Chem. Soc. Rev., 2007, 36, 246
Constable E. C., Corrd. Chem. Rev., 2008, 52, 842
Wild A., Winter A., Schlütter F., Schubert U. S., Chem. Soc. Rev., 2011, 40, 1459
Juris A., Balzani V., Barigelletti F., Campagna S., Belser P., Zelewsky A. V., Coord. Chem. Rev., 1988, 84, 85
Encinas S., Flamigni L., Barigelletti F., Constable E. C., Housecroft C. E., Schofield E., Figgemeier E., Fenske D., Neuburger M., Vos J. G., Zehnder M., Chem.-Eur. J., 2002, 8, 137
Benniston A. C., Grosshenny V., Harriman A., Ziessel R., Dalton Trans., 2004, 1227
Hjelm J., Handel R. W., Hagfeldt A., Constable E. C., Housecroft C. E., Forster R. J., Inorg. Chem., 2005, 44, 1073
Hjelm J., Constable E. C., Figgemeier E., Hagfeldt A., Handel R., Housecroft C. E., Mukhtar E., Schofield E., Chem. Commun., 2002, 284
Benniston A. C., Grosshenny V., Harriman A., Ziessel R., Dalton Trans., 2004, 1227
Harriman A., Ziessel R., Chem. Commun., 1996, 1707
Constable E. C., Figgemeier E., Housecroft C. E., Kokatam S. L., Medlycott E. A., Neuburger M., Schaffner S., Zampese J. A., Dalton Trans., 2008, 6752
Harriman A., Mayeux A., Nicola A. D., Ziessel R., Phys. Chem. Chem. Phys., 2002, 4, 2229
Büschel M., Helldobler M., Daub, J., Chem. Commun., 2002, 1338
Ringenbach C., Nicola A. D., Ziessel R., J. Org. Chem., 2003, 68, 4708
Benniston A. C., Harriman A., Lawrie D. J., Mayeux A., Phys. Chem. Chem. Phys., 2004, 6, 51
Barbieri A., Ventura B., Barigelletti F., Nicola A. D., Quesada M., Ziessel R., Inorg. Chem., 2004, 43, 7359
Winter A., Egbe D. A. M., Schubert U. S., Org. Lett., 2007, 9, 2345
Meyer A., Schnakenburg G., Glaum R., Schiemann O., Inorg. Chem., 2015, 54, 8456
Elgrishi N., Chambers M. B., Artero V., Fontecave M., Phys. Chem. Chem. Phys., 2014, 16, 13635
Docherty R., Tuna F., Kilner C. A., McInnes E. J. L., Malcolm M. A., Chem. Commun., 2012, 48, 4055
Constable E. C., Decurtins S., Housecroft C. E., Keene T. D., Palivan C. G., Price J. R., Zampese J. A., Dalton Trans., 2010, 39, 2337
Gasnier A., Royal G., Terech P., Langmuir, 2009, 25, 8751
Steill J., Zhao J. F., Siu C. K., Ke Y. Y., Verkerk U. H., Oomens J., Dunbar R. C., Hopkins A. C., Siu M. K. W., Angew. Chem. Int. Ed., 2008, 47, 9666
Drew M. G. B., Foreman M. R. St. J., Geist A., Hudson M. J., Mar-ken F., Norman V., Weigl M., Polyhedron, 2006, 25, 888
Alonso C., Ballester L., Gutierrez A., Perpinan M. F., Anchez A. E., Azcondo M. T., Eur. J. Inorg. Chem., 2005, 486
Dobrawa R., Lysetska M., Ballester P., Gruene M., Wuerthner F., Macromolecules, 2005, 38, 1315
Allmann R., Henke W., Reinen D., Inorg. Chem., 1978, 17, 378
Kharat A. N., Bakhoda, A., Hajiashrafi T., J. Mol. Catal. A: Chem., 2010, 333, 94
Patel M. N., Dosi P. A., Bhatt B. S., Appl. Organometal. Chem., 2011, 25, 653
Patel M. N., Joshi H. N., Patel C. R., Appl. Organometal. Chem., 2012, 26, 641
Naseri Z., Kharat A. N., Banavand A., Bakhoda A., Foroutannejad S., Polyhedron, 2012, 33, 396
Patel M. N., Joshi H. N., Patel C. R., J. Organometal. Chem., 2012, 701, 8
Fang W. W., Liu C., Chen J. B., Lu Z. W., Li Z. M., Bao X. L., Tu T., Chem. Commun., 2015, 51, 4267
Fang W. W., Sun Z. M., Tu T., J. Phys. Chem. C, 2013, 117, 25185
Mahendiran D., Kumar R. S., Viswanathan V., Velmurugan D., Ra-himan A. K., Dalton Trans., 2016, 45, 7794
Sheldrick G. M., SHELXS 97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, 1997
Sheldrick G. M., SHELXS 97, Program for Crystal Structure Solution, University of Göttingen, Göttingen, 1997
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We wish to thank Dr. WANG Fengqin for constructive dis-cussion.
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Supported by the National Natural Science Foundation of China(No.21302138).
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Yan, X., Zhang, J. Copper(II) complexes based on 4′-R-terpyridine: Synthesis, structures, and photocatalytic properties. Chem. Res. Chin. Univ. 33, 1–6 (2017). https://doi.org/10.1007/s40242-017-6319-3
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DOI: https://doi.org/10.1007/s40242-017-6319-3