Abstract
In this work, magnetic molecularly imprinted polymers (MMIPs) were prepared by the method of co-precipitation polymerization on the surface of vinyl-modified silica magnetic particles. Here, 4-nitrophenol (4-NP) was used as a template and vinylimidazole as a functional monomer. The structural features and morphology of MMIPs were characterized by SEM, FT-IR, TEM and XRD techniques. The results showed that the structures of MMIPs have a layer of silica and MIPs on the surface of the Fe3O4 particles, and they could be rapidly separated from the solution using a magnet. MMIPs possess higher adsorption capacity and excellent selectivity towards template (4-NP) than other structural analogues. And it is found to have good imprinting effect. MMIPs were used as micro-solid phase extraction sorbent for selective separation of 4-NP in lake water sample with high recoveries (90.63–95.63%) and low relative standard deviation values (RSD ≤ 3.2%, n = 3).
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Acknowledgments: This work was supported by the national Natural Science Foundation of China (21365020, and 21565025), by the State Key Laboratory of Fine Chemicals (KF 1617) and also supported by 111 Project (D18022).
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Yigaimu, A., Muhammad, T., Yang, W. et al. Magnetic Molecularly Imprinted Polymer Particles Based Micro-Solid Phase Extraction for the Determination of 4-Nitrophenol in Lake Water. Macromol. Res. 27, 1089–1094 (2019). https://doi.org/10.1007/s13233-019-7151-z
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DOI: https://doi.org/10.1007/s13233-019-7151-z