Abstract
In the present study, Fe3O4@MCM-41-(SO3−)[ZrO2] magnetic nano-particles (MNPs) as a new, effective and selective solid phase is reported for the preconcentration of lead ions by using of dispersive solid-liquid micro extraction (DSLME) as a rapid method. The Fe3O4@MCM-41 nanocomposite with charged sulfonate groups can be synthesized by the formation of sulfonic functionalized organic-inorganic MCM-41 mesoporous structure on the surface of magnetite nanoparticles. The encapsulated ZrO2 nanoparticles into network of Fe3O4@MCM-41─SO3H MNPs fabricated by covalently bound with implanted of charged sulfonate groups (-SO3−). The structure and morphology of the prepared sorbent were characterized by FT-IR, XRD, VSM, BET and TEM techniques in order to show that they comprised of both magnetite silica mesoporous structures with incorporated sulfonate groups and encapsulated ZrO2 nanoparticles. The synthesized solid phase was utilized for the preconcentration of lead ions prior to determination by atomic absorption spectrophotometry. The calibration graph was obtained under the optimized conditions with linear dynamic range of 1.0–300 μg L−1 and correlation coefficient (r2) of 0.998. The detection limits of this method was 0.03 ng mL−1. The obtained results showed that, the method can be successfully applied to the selective extraction and determination of the lead ionsin different samples of water.
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References
Zhang Q, Du Q, Hua M, Jiao T, Gao F, Pan B (2013) Sorption enhancement of Lead ions from water by surface charged polystyrene-supported Nano-zirconium oxide composites. Environ Sci Technol 47:6536–6544
Shariati S, Golshekan M (2014) Optimization of cloud point extraction of copper with neocuproine from aqueous solutions using Taguchi fractional factorial design. J Anal Chem 69:248–254
Li Z, Barnes JC, Bosoy A, Stoddart JF, Zink JI (2012) Mesoporous silica nanoparticles in biomedical applications. Chem Soc Rev 41:2590–2605
Golshekan M, Shariati S (2012) Nano magnetic solid phase extraction for Preconcentration of Lead ions in environmental samples by a newly synthesized reagent. Acta Chim Slov 60:358–367
Cao CY, Qu J, Yan WS, Zhu JF, Wu ZY, Song WG (2012) Low-cost synthesis of flowerlike α-Fe2O3 nanostructures for heavy metal ion removal: adsorption property and mechanism. Langmuir. 28:4573–4579
Ali MA, Dzombak DA (1996) Effects of simple organic acids on sorption of Cu2+ and Ca2+ on goethite. Geochim Cosmochim Acta 60:291–304
Leupin OX, Hug SJ, Badruzzaman ABM (2005) Arsenic removal from Bangladesh tube well water with filter columns containing zerovalent iron filings and sand. Environ Sci Technol 39:8032–8037
Trivedi P, Axe L, Tyson TA (2001) XAS studies of Ni and Zn sorbed to hydrous manganese oxide. Environ Sci Technol 35:4515–4521
Xiao H, Ai Z, Zhang L (2009) Nonaqueous sol−gel synthesized hierarchical CeO2 nanocrystal microspheres as novel adsorbents for wastewater treatment. J Phys Chem C 113:16625–16630
Karthikeyan KG, Elliott HA, Cannon FS (1997) Adsorption and coprecipitation of copper with the hydrous oxides of iron and aluminum. Environ Sci Technol 31:2721–2725
Hua M, Zhang S, Pan B, Zhang W, Lv L, Zhang Q (2012) Heavy metal removal from water/wastewater by nanosized metal oxides: a review. J Hazard Mater 211:317–331
Chen X, Lam KF, Zhang Q, Pan B, Arruebo M, Yeung KL (2009) Synthesis of highly selective magnetic mesoporous adsorbent. J Phys Chem C 113:9804–9813
Chen X, Lam KF, Yeung KL (2001) Selective removal of chromium from different aqueous systems using magnetic MCM-41 nanosorbents. Chem Eng J 172:728–734
Liua H, Guoa W, Li Y, He S, He C (2018) Photocatalytic degradation of sixteen organic dyes by TiO2/WO3-coated magnetic nanoparticles under simulated visible light and solar light. J Environ Chem Eng 1:59–67
Zheng X, Fu W, Peng H, Wen J (2018) Preparation and characterization of CuxZn1-xS nanodisks for the efficient visible light photocatalytic activity. J Environ Chem Eng 1:9–18
Kongarapu RJ, Mahamallik P, Pal A (2017) Surfactant modification of chitosan hydrogel beads for Ni@NiO core-shell nanoparticles formation and its catalysis to 4-nitrophenol reduction. J Environ Chem Eng 2:1321–1329
Li Z, Ai J, Ge M (2017) A facile approach assembled magnetic CoFe2O4/AgBr composite for dye degradation under visible light. J Environ Chem Eng 2:1394–1403
Toshima N, Shiraishi Y, Teranishi T, Miyake M, Tominaga T, Watanabe H, Brijoux W, Bonnemann H, Schmid G (2001) Ligand-stabilized metal nanoclusters as homogeneous and heterogeneous catalysts in the liquid phase. Appl Organomet Chem 15:178–196
Moiseev II, Stromnova TA, Vargafik MN, Orlova ST, Chernysheva TV, Stolarov IP (1999) Giant cluster catalysis: possible intermediacy of nitrene and carbene species. Catal Today 51:595–602
Behrens S, Spittel G (2005) A new palladium nanoparticle catalyst on mesoporous silica prepared from a molecular cluster precursor. Dalton Trans 5:868–873
Lu AH, Salabas EL, Sch€uth F (2007) Magnetic nanoparticles: synthesis, protection, functionalization, and application. Angew Chem Int Ed 46:1222–1244
Pankhurst QA, Connolly J, Jones SK, Dobson J (2003) Applications of magnetic nanoparticles in biomedicine. J Phys D Appl Phys 36:167–181
Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EWJ (1992) A new family of mesoporous molecular sieves prepared with liquid crystal templates. J Am Chem Soc 114:10834–10843
Corma A (1997) From microporous to mesoporous molecular sieve materials and their use in catalysis. Chem Rev 97:2373–2420
Mbaraka IK, Shanks BH (2005) Design of Multifunctionalized Mesoporous Silicas for esterification of fatty acid. J Catal 229:365–373
Kim Y, Lee B, Yi J (2003) Removal of copper ions from acid mine drainage wastewater using ion exchange technique: factorial design AnalysisSep. Sci Technol 38:2533–2548
Azizi P, Golshekan M, Shariati S, Rahchamani J (2015) Solid phase extraction of Cu2+, Ni2+, and Co2+ ions by a new magnetic nano-composite: excellent reactivity combined with facile extraction and determination. Environ Monit Assess 187:1–11
Golshekan M, Shariati S, Saadatjoo N (2014) The synthesis of aminonaphtols and β-amino carbonyls in the presence magnetic recyclable Fe3O4@MCM-48─NaHSO4 nano catalyst. RSC Adv 4:16589–16596
Saadatjoo N, Golshekan M, Shariati S, Kefayati H, Azizi P (2013) Organic/inorganic MCM-41 magnetite nanocomposite as a solid acid catalyst for synthesis of benzo[α]xanthenone derivatives. J Mol Catal A Chem 377:173–179
Saadatjoo N, Golshekan M, Shariati S, Azizi P, Nemati F (2017) Ultrasound-assisted synthesis of b-amino ketones via a Mannich reaction catalyzed by Fe3O4 magnetite nanoparticles as an efficient, recyclable and heterogeneous catalyst. Arab J Chem 10:735–741
Acknowledgements
The authors acknowledge the University of Guilan, Research Council and Iran National Science Foundation for supporting (Project Number: 94027265) this work.
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Golshekan, M., Shirini, F. Fe3O4@MCM-41-(SO3−)[ZrO2] Magnetic Mesoporous Nanocomposite: Dispersive Solid-Liquid Micro Extraction of Pb2+ Ions. Silicon 12, 747–757 (2020). https://doi.org/10.1007/s12633-019-00143-3
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DOI: https://doi.org/10.1007/s12633-019-00143-3